Analysis of influence mechanism of CO2-water coupling fracturing sandstone.

The existence of hard rock layers has a serious impact on coal seam mining, in order to explore the acidification and crushing mechanism of hard sandstone rock layers, this paper adopts the self-developed CO2-water-rock coupling test device to carry out the testing of mechanical properties and internal structural characteristics of rock samples before and after the coupling action of the three sandstones, and analyzes the influencing factors of sandstone CO2 coupling crushing. The study shows that: the lower the temperature of CO2-water-rock coupling, the higher the pore pressure, the higher the volume fraction of CO2 in the coupling fracturing fluid, and the longer the coupling time, the greater the decrease in the mechanical strength of the rock samples, and the more complicated the splitting damage pattern is, and the CO2-water-rock coupling makes the pore and fracture volume fraction and fractal dimension of three kinds of sandstone samples increase to varying degrees, whereas the volume fraction of minerals and the fractal dimension decrease, and the CO2-water-rock coupling results in a decrease in the volume fraction of minerals and fractal dimension, and a decrease in the volume fraction of minerals and fractal dimension. The pore volume fraction and fractal dimension of the three sandstone samples increased to different degrees, while the mineral volume fraction and fractal dimension decreased, and the pore volume fraction and fractal dimension of the three sandstone samples decreased. The damage pattern of sandstone samples after coupling is affected by both chemical and mechanical damages. When using coupling fracturing fluid with 8 % CO2, the degree of mineral dissolution and dissolution is the largest, and the dissolution effect is larger than the precipitation effect, which has the most significant effect on the morphology type and connectivity of microscopic pore cracks, and the study in this paper has certain theoretical and practical value for the chemical softening of sandstone.

Study on the fractional creep model of roadway filling paste under the coupling effect of pore water pressure and stress.

Filling paste in deep roadways is significantly affected by groundwater, especially high pore water pressure, which increases the complexity and variability of the filling paste's mechanical properties. To explore the creep characteristics and long-term stability of filling paste under varying pore water pressure, the MTS815.03 test system is used to conduct creep tests under different pore water pressures and stress. Then the creep deformation of the filling paste under the complex pressure field of static pore water pressures is analyzed. Finally, through the one-to-one correspondence between the numerical simulation of the creep model and the characteristic points of the creep curve, a method for determining the creep parameters under the complex pressure field of static pore water pressures is proposed. Results show that the creep test curves of filling paste under different pore water pressures and stress are in good agreement with the model curves. This shows that the creep constitutive model in this research can better reflect the whole process of creep deformation of filling paste. The result also verifies the rationality of the proposed method to determine creep model parameters. The newly proposed creep model can effectively compensate for the traditional Nishihara model, which is inability to reflect the acceleration of creep and can more accurately describe the creep characteristics of the primary and steady-state creep stages.

Impact of vermicompost addition on water availability of differently textured soils.

Vermicompost is an organic material that is abundant in humic acids and nutrients. It is obtained through the bio-oxidation and stabilization processes carried out by earthworms. It has been proven to bring several benefits to different soil properties, including bulk density, soil structure, and plant available water capacity (PAWC). This investigation was conducted to fill the knowledge gap in some critical factors related to vermicompost application, specifically the short-term influence of a single vermicompost application with increasing doses on soil wettability and physical quality of differently textured soils. Water repellency of vermicompost and soil/vermicompost mixtures was investigated at different moisture contents by the water drop penetration time test, whereas physical quality was assessed by 35 soil indicators related to bulk density, soil water retention curve, and pore size distribution function. Despite vermicompost showed from strong to severe hydrophobicity at moisture content lower than the field capacity, amended soils were at the most slightly water repellent thus indicating that, under field conditions, the hydrophobicity attributable to soil amendment with vermicompost could be considered negligible. Soil physical quality was effectively affected by vermicompost addiction with different outcomes depending on soil texture. Indicators linked to PAWC generally increased at increasing the vermicompost rate in the coarse soils whereas no significant effect was observed for intermediate and fine soils. For example, plant available water capacity of coarse-textured soils increased from an average initial value of 0.056 cm3 cm-3 to an optimal value of 0.15 cm3 cm-3 when a vermicompost addition dose of about one-third by volume (34 %) was applied. In the finest soil, drainable porosity significantly increased from an initial value of 0.09 cm3 cm-3 to 0.23 cm3 cm-3 when the maximum vermicompost dose (43 %) was applied thus indicating that amendment could be effective in enhancing water and air circulation.

Pore Formation by Amyloid-like Peptides: Effects of the Nonpolar-Polar Sequence Pattern.

One of the mechanisms accounting for the toxicity of amyloid peptides in diseases like Alzheimer's and Parkinson's is the formation of pores on the plasma membrane of neurons. Here, we perform unbiased all-atom simulations of the full membrane damaging pathway, which includes adsorption, aggregation, and perforation of the lipid bilayer accounting for pore-like structures. Simulations are performed using four peptides made with the same amino acids. Differences in the nonpolar-polar sequence pattern of these peptides prompt them to adsorb into the membrane with the extended conformations oriented either parallel [peptide labeled F1, Ac-(FKFE)2-NH2], perpendicular (F4, Ac-FFFFKKEE-NH2), or with an intermediate orientation (F2, Ac-FFKKFFEE-NH2, and F3, Ac-FFFKFEKE-NH2) in regard to the membrane surface. At the water-lipid interface, only F1 fully self-assembles into ß-sheets, and F2 peptides partially fold into an α-helical structure. The ß-sheets of F1 emerge as electrostatic interactions attract neighboring peptides to intermediate distances where nonpolar side chains can interact within the dry core of the bilayer. This complex interplay between electrostatic and nonpolar interactions is not observed for the other peptides. Although ß-sheets of F1 peptides are mostly parallel to the membrane, some of their edges penetrate deep inside the bilayer, dragging water molecules with them. This precedes pore formation, which starts with the flow of two water layers through the membrane that expand into a stable cylindrical pore delimited by polar faces of ß-sheets spanning both leaflets of the bilayer.

The Hidden Role of the Dielectric Effect in Nanofiltration: A Novel Perspective to Unravel New Ion Separation Mechanisms.

Nanofiltration (NF) membranes play a critical role in separation processes, necessitating an in-depth understanding of their selective mechanisms. Existing NF models predominantly include steric and Donnan mechanisms as primary mechanisms. However, these models often fail in elucidating the NF selectivity between ions of similar dimensions and the same valence. To address this gap, an innovative methodology was proposed to unravel new selective mechanisms by quantifying the nominal dielectric effect isolated from steric and Donnan exclusion through fitted pore dielectric constants by regression analysis. We demonstrated that the nominal dielectric effect encompassed unidentified selective mechanisms of significant relevance by establishing the correlation between the fitted pore dielectric constants and these hindrance factors. Our findings revealed that dehydration-induced ion-membrane interaction, rather than ion dehydration, played a pivotal role in ion partitioning within NF membranes. This interaction was closely linked to the nondeformable fraction of hydrated ions. Further delineation of the dielectric effect showed that favorable interactions between ions and membrane functional groups contributed to entropy-driven selectivity, which is a key factor in explaining ion selectivity differences between ions sharing the same size and valence. This study deepens our understanding of NF selectivity and sheds light on the design of highly selective membranes for water and wastewater treatment.

Degradative solvent-catalyze extraction of sewage sludge.

It is necessary for the further development of sludge degradative solvent extraction (DSE) to significantly increase the bio-oil yield and adjust its composition. In this study, the effects of MCM-41, HZSM-5, and SSZ-13 on the physical properties, yield, and composition of bio-oil were compared. Results show that all three catalysts effectively promote the conversion of volatiles in the residue to the heavy component (heavy-s). The addition of MCM-41 improved the yieldof both the light component (light-s) and heavy-s. Their yields increased from 8.11% and 20.47% to 14.39% and 29.18%, respectively. Its all-silicon structure and weak acidity have no significant effect on the composition of the bio-oil. HZSM-5 addition increases the light-s yield to 25.58%. Its MFI structure and proper acidity are beneficial to the formation of aromatic hydrocarbons and olefins, while effectively reducing oxygenates. SSZ-13 increases the heavy-s yield to 27.89%, and promoted the formation of nitrogen-containing compounds significantly.

Cytoplasmic nucleoporin assemblage: the cellular artwork in physiology and disease.

Nucleoporins, essential proteins building the nuclear pore, are pivotal for ensuring nucleocytoplasmic transport. While traditionally confined to the nuclear envelope, emerging evidence indicates their presence in various cytoplasmic structures, suggesting potential non-transport-related roles. This review consolidates findings on cytoplasmic nucleoporin assemblies across different states, including normal physiological conditions, stress, and pathology, exploring their structural organization, formation dynamics, and functional implications. We summarize the current knowledge and the latest concepts on the regulation of nucleoporin homeostasis, aiming to enhance our understanding of their unexpected roles in physiological and pathological processes.

Characterisation of hydraulic properties of commercial gas diffusion layers: Toray, SGL, MGL, woven carbon cloth.

This study utilises computational fluid dynamics simulations with the OpenFOAM computational framework to investigate and compare the in-plane and through-plane permeability properties of four different gas diffusion layers (GDLs). Also the through-plane water and air relative permeability values and water saturations at different rates were simulated. Permeability analysis enhances our understanding of fluid flow, ways to decrease pressure loss in the GDL, and methods to enhance oxygen concentration at the catalyst layer interface through convection. The analysis reveals that the investigated GDL materials have spatial heterogeneity of porosity and permeability, especially in the Sigracet SGL 25 BA GDL. However, the porosity and permeability of the Toray TGP-H 060 and AvCarb 370 MGL GDLs exhibit less variations. The two-phase flow studies on GDL saturation show that at the same water injection flowrate, the AvCarb 370 MGL GDL has the largest remaining water saturation, with Sigracet SGL 25 BA GDL being the less saturated GDL among the four investigated GDLs. The compression from the ribs significantly affected the in-plane permeabilities of both Toray TGP-H 060 and especially impacted Sigracet SGL 25 BA GDL. This impact was expected as the pore size distribution varied significantly in the areas under the ribs versus the channel.

Force-electric characteristics of model rock-filled concrete under uniaxial compression with different curing ages and rock-filled ratios.

By analyzing the force-electric properties of rock-filled concrete under uniaxial compression, the precursor information and characteristics of deformation and failure of rock-filled concrete can be mastered, and the reliability and safety of rock-filled concrete structures at an early age can be ensured. This study investigated four variations of model rock-filled concrete, each with a distinct rock-filled ratio. Using the two-electrode alternating current test method, we analyzed the electrical resistivity properties of rock-filled concrete under uniaxial compression at various curing ages (1 d, 3 d, 7 d, 14 d, and 28 d). Additionally, the microscopic pore structure was examined using low-field nuclear magnetic resonance technology. The results showed that with increasing curing age or rock-filled ratio, the compressive strength and electrical resistivity of rock-filled concrete showed a nonlinear growth trend. In contrast, the porosity showed a nonlinear decrease, with the internal pore structure gradually becoming more refined. A mathematical model was established to describe the electrical resistivity of rock-filled concrete at various curing ages and rock-filled ratios. During uniaxial compression, the electrical resistivity of rock-filled concrete followed a pattern of rapid decline, slow decline, stable, and slow increase with strain. These phases corresponded to the development of internal pores and cracks and changes in the crack resistance performance of the rockfill skeleton in the concrete. Moreover, a mathematical equation was formulated to elucidate the relationship among the damage variable, the rock-filled ratio, and the electrical resistivity of model rock-filled concrete, thereby enabling the prediction of the extent of damage to the model rock-filled concrete under stress conditions.

Nanoporous Carbon Materials as Solid Contacts for Microneedle Ion-Selective Sensors.

Continuous sensing of biomarkers, such as potassium ions or pH, in wearable patches requires miniaturization of ion-selective sensor electrodes. Such miniaturization can be achieved by using nanostructured carbon materials as solid contacts in microneedle-based ion-selective and reference electrodes. Here we compare three carbon materials as solid contacts: colloid-imprinted mesoporous (CIM) carbon microparticles with ∼24-28 nm mesopores, mesoporous carbon nanospheres with 3-9 nm mesopores, and Super P carbon black nanoparticles without internal porosity but with textural mesoporosity in particle aggregates. We compare the effects of carbon architecture and composition on specific capacitance of the material, on the ability to incorporate ion-selective membrane components in the pores, and on sensor performance. Functioning K+ and H+ ion-selective electrodes and reference electrodes were obtained with gold-coated stainless-steel microneedles using all three types of carbon. The sensors gave near-Nernstian responses in clinically relevant concentration ranges, were free of potentially detrimental water layers, and showed no response to O2. They all exhibited sufficiently low long-term potential drift values to permit calibration-free, continuous operation for close to 1 day. In spite of the different specific capacitances and pore architecture of the three types of carbon, no significant difference in potential stability for K+ ion sensing was observed between electrodes that used each material. In the observed drift values, factors other than the carbon solid contact are likely to play a role, too. However, for pH sensing, electrodes with CIM as a carbon solid contact, which had the highest specific capacitance and best access to the pores, exhibited better long-term stability than electrodes with the other carbon materials.

Self-Assembling and Pore-Forming Peptoids as Antimicrobial Biomaterials.

Bacterial infections have been a serious threat to mankind throughout history. Natural antimicrobial peptides (AMPs) and their membrane disruption mechanism have generated immense interest in the design and development of synthetic mimetics that could overcome the intrinsic drawbacks of AMPs, such as their susceptibility to proteolytic degradation and low bioavailability. Herein, by exploiting the self-assembly and pore-forming capabilities of sequence-defined peptoids, we discovered a family of low-molecular weight peptoid antibiotics that exhibit excellent broad-spectrum activity and high selectivity toward a panel of clinically significant Gram-positive and Gram-negative bacterial strains, including vancomycin-resistant Enterococcus faecalis (VREF), methicillin-resistant Staphylococcus aureus (MRSA), methicillin-resistant Staphylococcus epidermidis (MRSE), Escherichia coli, Pseudomonas aeruginosa, and Klebsiella pneumoniae. Tuning the peptoid side chain chemistry and structure enabled us to tune the efficacy of antimicrobial activity. Mechanistic studies using transmission electron microscopy (TEM), bacterial membrane depolarization and lysis, and time-kill kinetics assays along with molecular dynamics simulations reveal that these peptoids kill both Gram-positive and Gram-negative bacteria through a membrane disruption mechanism. These robust and biocompatible peptoid-based antibiotics can provide a valuable tool for combating emerging drug resistance.

Ultrastable Carboxyl-Functionalized Pore-Space-Partitioned Metal-Organic Frameworks for Gas Separation.

Isoreticular chemistry, which enables property optimization by changing compositions without changing topology, is a powerful synthetic strategy. One of the biggest challenges facing isoreticular chemistry is to extend it to ligands with strongly coordinating substituent groups such as unbound -COOH, because competitive interactions between such groups and metal ions can derail isoreticular chemistry. It is even more challenging to have an isoreticular series of carboxyl-functionalized MOFs capable of encompassing chemically disparate metal ions. Here, with the simultaneous introduction of carboxyl functionalization and pore space partition, a family of carboxyl-functionalized materials is developed in diverse compositions from homometallic Cr3+ and Ni2+ to heterometallic Co2+/V3+, Ni2+/V3+, Co2+/In3+, Co2+/Ni2+. Cr-MOFs remain highly crystalline in boiling water. Unprecedentedly, one Cr-MOF can withstand the treatment cycle with 10m NaOH and 12m HCl, allowing reversible inter-conversion between unbound -COOH acid form and -COO- base form. These materials exhibit excellent sorption properties such as high uptake capacity for CO2 (100.2 cm3 g-1) and hydrocarbon gases (e.g., 142.1 cm3 g-1 for C2H2, 110.5 cm3 g-1 for C2H4) at 1 bar and 298K, high benzene/cyclohexane selectivity (up to ≈40), and promising separation performance for gas mixtures such as C2H2/CO2 and C2H2/C2H4.

Effects of pore characteristics on CO2 adsorption performance of coal slime with different metamorphic degrees.

With the rapid development of Carbon Capture, Utilization and Storage (CCUS) technology, it is necessary to explore the feasibility of coal slime as a porous carbon material for CO2 capture. In this paper, scanning electron microscopy (SEM) was used to observe the morphological characteristics of coal slime samples with different metamorphic degrees, and the pore structure of coal slime was explored by low temperature N2 adsorption and low-pressure CO2 adsorption experiments. The pore distribution characteristics were analyzed, and the adsorption law of different metamorphic degrees were summarized through CO2 isothermal adsorption experiments. The results showed that: The specific surface area (SSA) and pore volume (PV) of the mesopores of the coal slime exhibited a U-shaped distribution with coal rank, and are much smaller than that of its micropores. Micropores less than 2 nm are the main adsorption space of coal slime, its PV accounted for 59%, 60%, 71%, and SSA accounted for 92%, 93%, 95%, obviously, which are dominant at all stages. The linear correlation fitting coefficients R2 between the limiting adsorbed amount a of CO2 and the micropores PV and the SSA were up to 0.830 and 0.887, respectively. The coal slime has good adsorption performance for CO2. Based on the Langmuir model to fit the limit adsorption amount, a-value can reach 41.774 cm3 g-1, 32.072 cm3 g-1, 38.457 cm3 g-1 at 303 K with the increase of Rmax. Studying the impact of coal slime on CO2 adsorption performance provides a theoretical basis for the subsequent preparation of energy storage materials and is of great significance for the safe, efficient and economic capture and sequestration of CO2, to alleviate the serious situation of the environment and realizing the dual-carbon goal.

Constructing Hierarchical Zeolites with Highly Complete Framework via Controlled Desilication.

Desilication in alkaline medium has been widely used in construction of hierarchical zeolites for industrially relevant catalytic processes. The built of hierarchy in zeolites, especially with low aluminum stability or high Si/Al ratio, often suffers from uncontrolled destruction of zeolitic framework, accompanied by a significant loss of microporous domains and intrinsic acidity after desilication. Here, we report a novel and simple methodology for preparation of hierarchical zeolites with highly complete framework and minimum sacrifice of microporosity and acidity. The pre-impregnated amines in zeolite micropores act as inner pore-directing agents (iPDAs), largely protecting the zeolitic framework and moderating the silicon extraction during the alkaline treatment. The resulting hierarchical zeolites exhibit high crystallinity, tunable hierarchy, stable framework, and well-preserved acidity, endowing them with significantly improved mass transport properties and enhanced activities in catalytic conversion of methanol or furfural.

Scalable, Controlled Bimodal Pore-Structured Polymer Coating for Efficient Passive Daytime Radiative Cooling.

Outdoor thermal irritation poses a serious threat to public health, with the frequent occurrence of increasingly intense heat waves. With the global goal of carbon peaking and carbon neutrality, there is an urgent need for a strategy that is efficient and can provide localized outdoor cooling without an intensive energy input. This paper demonstrated a rapidly formable polyurethane-based coating with controlled bimodal spherical micropores. Nano-Al2O3 particles (300 nm) embedded in the polymer were used for targeted enhancement of reflectance at 0.38-0.5 wavelengths. The enhanced film reflected 93% solar irradiance and selectively transmitted 95% thermal radiation (8-13 µm), enabling rapid cooling and the creation of a comfortable thermal microclimate to avoid overheating of 6-11 °C during daytime conditions. The ultrawide material compatibility and excellent adaptive mechanical strength of polyurethane-based coatings are expected to benefit the sustainable development of society in a wide range of fields, from health to economics.

Mechanism and treatment of intracerebral hemorrhage focus on mitochondrial permeability transition pore.

Intracerebral hemorrhage (ICH) is the second most common subtype of stroke, characterized by high mortality and a poor prognosis. Despite various treatment methods, there has been limited improvement in the prognosis of ICH over the past decades. Therefore, it is imperative to identify a feasible treatment strategy for ICH. Mitochondria are organelles present in most eukaryotic cells and serve as the primary sites for aerobic respiration and energy production. Under unfavorable cellular conditions, mitochondria can induce changes in permeability through the opening of the mitochondrial permeability transition pore (mPTP), ultimately leading to mitochondrial dysfunction and contributing to various diseases. Recent studies have demonstrated that mPTP plays a role in the pathological processes associated with several neurodegenerative diseases including Parkinson's disease, Alzheimer's disease, Huntington's disease, ischemic stroke and ischemia-reperfusion injury, among others. However, there is limited research on mPTP involvement specifically in ICH. Therefore, this study comprehensively examines the pathological processes associated with mPTP in terms of oxidative stress, apoptosis, necrosis, autophagy, ferroptosis, and other related mechanisms to elucidate the potential mechanism underlying mPTP involvement in ICH. This research aims to provide novel insights for the treatment of secondary injury after ICH.

Regulating the Porosity and Bipolarity of Polyimide-Based Covalent Organic Framework for Advanced Aqueous Dual-Ion Symmetric Batteries.

The all-organic aqueous dual-ion batteries (ADIBs) have attracted increasing attention due to the low cost and high safety. However, the solubility and unstable activity of organic electrodes restrict the synergistic storage of anions and cations in the symmetric ADIBs. Herein, a novel polyimide-based covalent organic framework (labeled as NTPI-COF) is constructed, featured with the boosted structure stability and electronic conductivity. Through regulating the porosity and bipolarity integrally, the NTPI-COF possesses hierarchical porous structure (mesopore and micropore) and abundant bipolar active centers (C═O and C─N), which exhibits rapid dual-ion transport and storage effects. As a result, the NTPI-COF as the electrodes for ADIBs deliver a high reversible capacity of 109.7 mA h g-1 for Na+ storage and that of 74.8 mA h g-1 for Cl- storage at 1 A g-1, respectively, and with a capacity retention of 93.2% over 10 000 cycles at 10 A g-1. Additionally, the all-organic ADIBs with symmetric NTPI-COF electrodes achieve an impressive energy density of up to 148 W h kg-1 and a high power density of 2600 W kg-1. Coupling the bipolarity and porosity of the all-organic electrodes applied in ADIBs will further advance the development of low-cost and large-scale energy storage.

Study on microstructure evolution and oxidation kinetics in Coal-Oil Symbiosis.

Differences in the spontaneous combustion mechanism characteristics of Coal-Oil Symbiosis (COS) significantly affect coal mines' safety management and ecological environment maintenance. Accordingly, this study aims to investigate COS's macroscopic and microstructural characteristics with different oil mass percentage using simultaneous thermal analysis, low-temperature N2 adsorption, scanning electron microscopy (SEM), and in-situ Fourier transform infrared spectroscopy (FTIR). The results showed that with the increase of oil mass percentage, the COS displayed the weakening of oxygen absorption and the advance of some characteristic temperatures, and 11.5 °C advanced the maximum weight loss temperature on average. For the 25 % oil sample, the ignition temperature was 9.5 °C lower than that of the raw coal. Additionally, the apparent activation energy of the high oil mass percentage sample was significantly reduced in the pyrolysis and combustion stages, and when the oil mass percentage was 25 %, the activation energies of the two stages decreased by 89 % and 60.65 %, respectively. Compared to raw coal, COS exhibits fewer macropores and surface pores covered by oil, which limits oxygen adsorption. Moreover, COS with higher oil mass percentage had an increase in hydroxyl and aliphatic hydrocarbon groups, and the CH3 + CH2 content of COS increased by 69.2 % on average, providing more active groups, thereby promoting spontaneous combustion. This study provides an important reference and theoretical support for further understanding the structural evolution and oxidation kinetic behavior of COS, contributing to disaster prevention and ecological environmental protection in coal-oil coexistence mining areas.

Customizing Pore Structure and Lithiophilic Sites Dual-Gradient Free-Standing 3D Lithium-Based Anode to Enable Excellent Lithium Metal Batteries.

Developing 3D hosts is one of the most promising strategies for putting forward the practical application of lithium(Li)-based anodes. However, the concentration polarization and uniform electric field of the traditional 3D hosts result in undesirable "top growth" of Li, reduced space utilization, and obnoxious dendrites. Herein, a novel dual-gradient 3D host (GDPL-3DH) simultaneously possessing gradient-distributed pore structure and lithiophilic sites is constructed by an electrospinning route. Under the synergistic effect of the gradient-distributed pore and lithiophilic sites, the GDPL-3DH exhibits the gradient-increased electrical conductivity from top to bottom. Also, Li is preferentially and uniformly deposited at the bottom of the GDPL-3DH with a typical "bottom-top" mode confirmed by the optical and SEM images, without Li dendrites. Consequently, an ultra-long lifespan of 5250 h of a symmetrical cell at 2 mA cm-2 with a fixed capacity of 2 mAh cm-2 is achieved. Also, the full cells based on the LiFePO4, S/C, and LiNi0.8Co0.1Mn0.1O2 cathodes all exhibit excellent performances. Specifically, the LiFePO4-based cell maintains a high capacity of 136.8 mAh g-1 after 700 cycles at 1 C (1 C = 170 mA g-1) with 94.7% capacity retention. The novel dual-gradient strategy broadens the perspective of regulating the mechanism of lithium deposition.

Fabrication and characterization of ceramic tubular composite membranes using slag waste materials for oily wastewater treatment.

In this study, low-cost tubular ceramic membranes were fabricated by using waste slag and natural raw materials in order to decrease the manufacturing carbon footprints. The effects of incorporation of phosphorus slag (PS) and blast furnace slag (BFS) in the mullite-zeolite membrane body were investigated. The structural characteristics of the fabricated membranes were evaluated using X-ray diffraction (XRD), field emission-scanning electron microscopy (FESEM), atomic force microscopy (AFM), contact angle, porosity and average pore size analyses. Thermal and mechanical stability were studied by thermogravimetric analysis (TGA) and three-point bending test, respectively. The oily wastewater treatment tests revealed that an increase in the slag percentage from 0 to 30% leads to enhancing the permeate flux from 99 l m-2 h-1 to 349 l m-2 h-1 for PS-based tubular membrane and to 244 l m-2 h-1 for BFS-based tubular membrane under 1 bar applied. The chemical oxygen demand (COD) removal percentage of all membranes was reported almost 99% for oily wastewater feed with a COD concentration of 612 mg l-1. In addition, the investigation of membrane fouling mechanisms was carried out using Hermia models indicating that the best correlation with the experimental data is observed for the complete pore blocking model. This study presents experimental foundations aimed at enhancing the performance of affordable slag-based membranes, thus fostering their applicability in engineering contexts.