SPGAN Optimized by Piranha Foraging Optimization for Thyroid Nodule Classification in Ultrasound Images.

In this research work, Semantic-Preserved Generative Adversarial Network optimized by Piranha Foraging Optimization for Thyroid Nodule Classification in Ultrasound Images (SPGAN-PFO-TNC-UI) is proposed. Initially, ultrasound images are gathered from the DDTI dataset. Then the input image is sent to the pre-processing step. During pre-processing stage, the Multi-Window Savitzky-Golay Filter (MWSGF) is employed to reduce the noise and improve the quality of the ultrasound (US) images. The pre-processed output is supplied to the Generalized Intuitionistic Fuzzy C-Means Clustering (GIFCMC). Here, the ultrasound image's Region of Interest (ROI) is segmented. The segmentation output is supplied to the Fully Numerical Laplace Transform (FNLT) to extract the features, such as geometric features like solidity, orientation, roundness, main axis length, minor axis length, bounding box, convex area, and morphological features, like area, perimeter, aspect ratio, and AP ratio. The Semantic-Preserved Generative Adversarial Network (SPGAN) separates the image as benign or malignant nodules. Generally, SPGAN does not express any optimization adaptation methodologies for determining the best parameters to ensure the accurate classification of thyroid nodules. Therefore, the Piranha Foraging Optimization (PFO) algorithm is proposed to improve the SPGAN classifier and accurately identify the thyroid nodules. The metrics, like F-score, accuracy, error rate, precision, sensitivity, specificity, ROC, computing time is examined. The proposed SPGAN-PFO-TNC-UI method attains 30.54%, 21.30%, 27.40%, and 18.92% higher precision and 26.97%, 20.41%, 15.09%, and 18.27% lower error rate compared with existing techniques, like Thyroid detection and classification using DNN with Hybrid Meta-Heuristic and LSTM (TD-DL-HMH-LSTM), Quantum-Inspired convolutional neural networks for optimized thyroid nodule categorization (QCNN-OTNC), Thyroid nodules classification under Follow the Regularized Leader Optimization based Deep Neural Networks (CTN-FRL-DNN), Automatic classification of ultrasound thyroids images using vision transformers and generative adversarial networks (ACUTI-VT-GAN) respectively.

Encoder signal-based optimized Savitzky-Golay and adaptive spectrum editing for feature extraction of rolling element bearing under low-speed and variable-speed conditions.

Feature extraction of rolling element bearings (REB) under variable-speed conditions is always one of the hot and difficult points in the field of fault diagnosis. Based on the encoder signal with the advantages of low noise, and direct correlation with machine dynamics, an optimized Savitzky-Golay and adaptive spectrum editing are proposed for REB feature extraction under low-speed and variable-speed conditions. Firstly, the estimated features of the instantaneous angular speed (IAS) and interference components are studied. Secondly, based on the proposed multipoint mean ratio indicator and parametric decomposition structure, an adaptive SG filter is proposed to remove the speed trend component. Thirdly, an adaptive spectrum editing scheme with no transition band and low computational cost advantages is proposed to detect REB fault based on the combination of the cyclic dislocation scheme, the Gaussian function and the Pearson theory. Simulation and experiments are used to verify the effectiveness of the proposed scheme.

Mapping and analyzing the spatiotemporal dynamics of forest aboveground biomass in the ChangZhuTan urban agglomeration using a time series of Landsat images and meteorological data from 2010 to 2020.

In the context of global warming, there is a substantial demand for accurate and cost-effective assessment and comprehensive understanding of forest above-ground biomass (AGB) dynamics. The timeliness and low cost of optical remote sensing data enable the mapping of large-scale forest AGB dynamics. However, mapping forest AGB with optical remote sensing data presents challenges primarily due to data uncertainty and the complex nature of the forest environment. Previous studies have demonstrated the potential of meteorological data in enhancing forest AGB mapping. To accurately capture the dynamics of forest AGB, we initially acquired Landsat datasets, digital elevation model (DEM), and meteorological datasets (temperature, humidity, and precipitation) from 2010 to 2020 in Changsha-Zhuzhou-Xiangtan urban agglomeration (CZT) located in Hunan Province, China. Spectral variables (SVs), including spectral bands and vegetation indices, were extracted from Landsat images, while meteorological variables (MVs) were derived from the monthly meteorological data using the Savitzky-Golay (S-G) filtering algorithm. Additionally, terrain variables (TVs) were also extracted from the DEM data. Three modelling models, multiple linear regression (MLR), K nearest neighbor (KNN) and random forest (RF), were developed for mapping the dynamics of forest AGB in CZT. The result revealed that MVs have the potential to improve forest AGB mapping. Integration of MVs into the models resulted in a significant reduction in root mean square error (RMSE) ranging from 32.85 % to 19.25 % compared to utilizing only SVs. However, minimal improvement was observed with the inclusion of TVs due to negligible topographic relief within the study area. An upward trend of forest AGB in CZT was observed during this period, which can be attributed to the effective implementation of government environmental protection policies. It is confirmed that the meteorological data has significant contribution to forest AGB mapping, thereby endorsing advancements in forest resource monitoring and management programs.

Sugar detection in adulterated honey using hyper-spectral imaging with stacking generalization method.

This paper develops a new hybrid, automated, and non-invasive approach by combining hyper-spectral imaging, Savitzky-Golay (SG) Filter, Principal Components Analysis (PCA), Machine Learning (ML) classifiers/regressors, and stacking generalization methods to detect sugar in honey. First, the 32 different sugar concentration levels in honey were predicted using various ML regressors. Second, the six ranges of sugar were classified using various classifiers. Third, the 11 types of honey and 100% sugar were classified using classifiers. The stacking model (STM) obtained R2: 0.999, RMSE: 0.493 ml (v/v), RPD: 40.2, a 10-fold average R2: 0.996 and RMSE: 1.27 ml (v/v) for predicting 32 sugar concentrations. The STM achieved a Matthews Correlation Coefficient (MCC) of 99.7% and a Kappa score of 99.7%, a 10-fold average MCC of 98.9% and a Kappa score of 98.9% for classifying the six sugar ranges and 12 categories of honey types and a sugar.

Detection and quantification of cocoa powder adulteration using Vis-NIR spectroscopy with chemometrics approach.

The rising demand for cocoa powder has resulted in an upsurge in market prices, leading to the emergence of adulteration practices aimed at achieving economic benefits. This study aimed to detect and quantify cocoa powder adulteration using visible and near-infrared spectroscopy (Vis-NIRS). The adulterants used in this study were powdered carob, cocoa shell, foxtail millet, soybean, and whole wheat. The NIRS data could not be resolved using Savitzky-Golay smoothing. Nevertheless, the application of a random forest and support vector machine successfully classified the samples with 100% accuracy. Quantification of adulteration using partial least squares (PLS), Lasso, Ridge, elastic Net, and RF regressions provided R2 higher than 0.96 and root mean square error <2.6. Coupling PLS with the Boruta algorithm produced the most reliable regression model (R2 = 1, RMSE = 0.0000). Finally, an online application was prepared to facilitate the determination of adulterants in the cocoa powder.

Displacement of mining vibrating screen obtained from acceleration based on improved S-G filter.

Vibration displacement is one of the key parameters in fault diagnosis of vibrating screens. Monitoring of acceleration signals of vibrating screens can be disturbed due to various factors such as on-site working conditions and equipment. In order to obtain accurate displacement signals of vibrating screen, the method for converting vibration acceleration to displacement based on improved Savitzky-Golay (S-G) filter is proposed. The Particle Swarm Optimization (PSO) algorithm is used to optimize the window length of the S-G filter with the fixed polynomial. The filters are cascaded to denoise the signals multiple times. The reasonable regularization parameter of the Smoothed Prior Approach (SPA) is calculated to remove the trend item from the acceleration signals. The vibration displacement is obtained by integrating the preprocessed acceleration data in the frequency domain. The results demonstrate that the objectivity of parameter selection of filter is improved, and the denoising effect is significant. The filtering effect of the filter is further improved after cascading. It becomes better as the number of stages of cascade increases. The vibration displacement can be obtained accurately by the proposed method. The vibration test platform is built to verify the correctness of the method.

A UV-Vis spectroscopic detection method for cobalt ions in zinc sulfate solution based on discrete wavelet transform and extreme gradient boosting.

Zinc is a crucial strategic metal resource. The concentration of cobalt ions in zinc refining solution significantly impacts the efficiency of zinc electrolysis production. The traditional method of detecting cobalt ions in zinc solution is time-consuming, labor-intensive and ineffective. However, optical detection offers the advantage of high efficiency and low cost, making it a potential replacement for the traditional method. In this study, the spectral curve of cobalt ions in zinc solution is detected by ultraviolet-visible (UV-Vis) spectrophotometry. Additionally, we propose a model for the concentration-absorbance relationship of cobalt ions in zinc solution based on discrete wavelet transform and extreme gradient boosting (DWT-XGBoost) algorithms. First, the spectral curve's information region is denoised by using Savitzky-Golay (S-G) smoothing. Then, the denoised spectra is utilized to extract features through discrete wavelet transform and principal component analysis. These features are used as inputs to the XGBoost model to establish prediction models for low and high cobalt ions in zinc solution. Bayesian optimization is implemented to adjust the model's hyperparameters, including learning rate, feature sampling ratio, to enhance the prediction performance. Finally, applying the model to zinc solution samples from a zinc smelter and compared with other state-of-the-art algorithms, the DWT-XGBoost algorithm exhibits the lowest RMSE, MAE and MAPE, with values of 0.034 mg/L, 0.025 mg/L, 6.983 % for low cobalt and with values of 0.231 mg/L, 0.067 mg/L and 0.472 % for high cobalt. The experimental results demonstrate that the DWT-XGBoost model exhibits significantly superior prediction performance.

Evolutionary gravitational neocognitron neural network optimized with marine predators optimization algorithm for MRI brain tumor classification.

Magnetic resonance imaging (MRI) is a powerful tool for tumor diagnosis in human brain. Here, the MRI images are considered to detect the brain tumor and classify the regions as meningioma, glioma, pituitary and normal types. Numerous existing methods regarding brain tumor detection were suggested previously, but none of the methods accurately categorizes the brain tumor and consumes more computation period. To address these problems, an Evolutionary Gravitational Neocognitron Neural Network optimized with Marine Predators Algorithm is proposed in this article for MRI Brain Tumor Classification (EGNNN-VGG16-MPA-MRI-BTC). Initially, the brain MRI pictures are collected under Brats MRI image dataset. By using Savitzky-Golay Denoising approach, these images are pre-processed. The features are extracted utilizing visual geometry group network (VGG16). By utilizing VGG16, the features, like Grey level features, Haralick Texture features are extracted. These extracted features are given to EGNNN classifier, which categorizes the brain tumor as glioma, meningioma, pituitary gland and normal. Batch Normalization (BN) layer of EGNNN is eliminated and included with VGG16 layer. Marine Predators Optimization Algorithm (MPA) optimizes the weight parameters of EGNNN. The simulation is activated in MATLAB. Finally, the EGNNN-VGG16-MPA-MRI-BTC method attains 38.98%, 46.74%, 23.27% higher accuracy, 24.24%, 37.82%, 13.92% higher precision, 26.94%, 47.04%, 38.94% higher sensitivity compared with the existing AlexNet-SVM-MRI-BTC, RESNET-SGD-MRI-BTC and MobileNet-V2-MRI-BTC models respectively.

Evolutionary Gravitational Neocognitron Neural Network optimized with Marine Predators Algorithm is proposed in this article for MRI Brain Tumor Classification (EGNNN-VGG16-MPA-MRI-BTC). Initially, the brain MRI pictures are collected under Brats MRI image dataset. By using Savitzky-Golay Denoising approach, these images are pre-processed. The features are extracted utilizing visual geometry group network (VGG16). By utilizing VGG16, the features, like Grey level features, Haralick Texture features are extracted. These extracted features are given to EGNNN classifier, which categorizes the brain tumor as glioma, meningioma, pituitary gland and normal. Batch Normalization (BN) layer of EGNNN is eliminated and included with VGG16 layer. Marine Predators Optimization Algorithm (MPA) optimizes the weight parameters of EGNNN.

Comparison of ATR-FTIR and NIR spectroscopy for identification of microplastics in biosolids.

Biosolids are considered a potentially major input of microplastics (MPs) to agricultural soils. Our study aims to identify the polymeric origin of MPs extracted from biosolid samples by comparing their Attenuated Total Reflection (ATR) - Fourier-transform infrared (FTIR) spectra with the corresponding near-infrared (NIR) spectra. The reflectance spectra were preprocessed by Savitzky-Golay (SG), first derivative (FD) and compared with analogous spectra acquired on a set of fifty-two selected commercial plastic (SCP) materials collected from readily available products. According to the results portrayed in radar chart and built from both ATR-FTIR and NIR spectral datasets, the MPs showed high correlations with polymers such as polyethylene (LDPE, HDPE), polyethylene terephthalate (PET), polystyrene (PS), polypropylene (PP) and polyamide (PA), determined in SCP samples. Each unknown MP sample had on average three or more links to several types of SCP, according to the correlation coefficients for each polymer ranging from 0.7 up to 1. The comparison analysis classified the majority of MPs as composed mainly by LDPE/HDPE, according to the top correlation coefficients (r > 0.90). PP and PET were better identified with NIR than ATR-FTIR. In contrast to ATR-FTIR analysis, NIR was unable to identify PS. Based on these results, the primary sources of MPs in the biosolids could be identified as discarded consumer packaging (containers, bags, bottles) and fibers from laundry, disposable glove, and cleaning cloth. SYNOPSIS: Microplastics (MPs) are considered contaminants of emerging concern. This study compares two simple and fast spectroscopy techniques to identify microplastics in the biosolid matrix.

Temperature vegetation dryness index (TVDI) for drought monitoring in the Guangdong Province from 2000 to 2019.

Drought monitoring is crucial for assessing and mitigating the impacts of water scarcity on various sectors and ecosystems. Although traditional drought monitoring relies on soil moisture data, remote sensing technology has have significantly augmented the capabilities for drought monitoring. This study aims to evaluate the accuracy and applicability of two temperature vegetation drought indices (TVDI), TVDINDVI and TVDIEVI, constructed using the Normalized Difference Vegetation Index (NDVI) and the Enhanced Vegetation Index (EVI) vegetation indices for drought monitoring. Using Guangdong Province as a case, enhanced versions of these indices, developed through Savitzky-Golay filtering and terrain correction were employed. Additionally, Pearson correlation analysis and F-tests were utilized to determine the suitability of the Standardized Precipitation Index (SPI) and the Standardized Precipitation Evapotranspiration Index (SPEI) in correlation with TVDINDVI and TVDIEVI. The results show that TVDINDVI had more meteorological stations passing both significance test levels (P < 0.001 and P < 0.05) compared to TVDIEVI, and the average Pearson'R correlation coefficient was slightly higher than that of TVDIEVI, indicating that TVDINDVI responded better to drought in Guangdong Province. Our conclusion reveals that drought-prone regions in Guangdong Province are concentrated in the Leizhou Peninsula in southern Guangdong and the Pearl River Delta in central Guangdong. We also analyzed the phenomenon of winter-spring drought in Guangdong Province over the past 20 years. The area coverage of different drought levels was as follows: mild drought accounted for 42% to 64.6%, moderate drought accounted for 6.96% to 27.92%, and severe drought accounted for 0.002% to 1.84%. In 2003, the winter-spring drought in the entire province was the most severe, with a drought coverage rate of up to 84.2%, while in 2009, the drought area coverage was the lowest, at 49.02%. This study offers valuable insights the applicability of TVDI, and presents a viable methodology for drought monitoring in Guangdong Province, underlining its significance to agriculture, environmental conservation, and socio-economic facets in the region.

Application of Near-Infrared Spectroscopy and Fuzzy Improved Null Linear Discriminant Analysis for Rapid Discrimination of Milk Brands.

The quality of milk is tightly linked to its brand. A famous brand of milk always has good quality. Therefore, this study seeks to design a new fuzzy feature extraction method, called fuzzy improved null linear discriminant analysis (FiNLDA), to cluster the spectra of collected milk for identifying milk brands. To elevate the classification accuracy, FiNLDA was applied to process the near-infrared (NIR) spectra of milk acquired by the portable near-infrared spectrometer. The principal component analysis and Savitzky-Golay (SG) filtering algorithm were employed to lower dimensionality and eliminate noise in this system, respectively. Thereafter, improved null linear discriminant analysis (iNLDA) and FiNLDA were applied to attain the discriminant information of the NIR spectra. At last, the K-nearest neighbor classifier was utilized for assessing the performance of the identification system. The results indicated that the maximum classification accuracies of LDA, iNLDA and FiNLDA were 74.7%, 88% and 94.67%, respectively. Accordingly, the portable NIR spectrometer in combination with FiNLDA can classify milk brands correctly and effectively.

Improved T-wave detection in electrocardiogram signals based non-stationary wavelet transform and QRS complex cancellation with kurtosis analysis.

Objective. The T-wave in electrocardiogram (ECG) signal has the potential to enumerate various cardiac dysfunctions in the cardiovascular system. The primary objective of this research is to develop an efficient method for detecting T-waves in ECG signals, with potential applications in clinical diagnosis and continuous patient monitoring.Approach. In this work, we propose a novel algorithm for T-wave peak detection, which relies on a non-decimated stationary wavelet transform method (NSWT) and involves the cancellation of the QRS complex by utilizing its local extrema. The proposed scheme contains three stages: firstly, the technique is pre-processed using a two-stage median filter and Savitzky-Golay (SG) filter to remove the various artifacts from the ECG signal. Secondly, the NSWT technique is implemented using the bior 4.4 mother wavelet without downsampling, employing 24scale analysis, and involves the cancellation of QRS-complex using its local positions. After that, Sauvola technique is used to estimate the baseline and remove the P-wave peaks to enhance T-peaks for accurate detection in the ECG signal. Additionally, the moving average window and adaptive thresholding are employed to enhance and identify the location of the T-wave peaks. Thirdly, false positive T-peaks are corrected using the kurtosis coefficients method.Main results. The robustness and efficiency of the proposed technique have been corroborated by the QT database (QTDB). The results are also validated on a self-recorded database. In QTDB database, the sensitivity of 98.20%, positive predictivity of 99.82%, accuracy of 98.04%, and detection error rate of 1.95% have been achieved. The self-recorded dataset attains a sensitivity, positive predictivity, accuracy, and detection error rate of 99.94%, 99.96%, 99.90%, and 0.09% respectively.Significance. A T-wave peak detection based on NSWT and QRS complex cancellation, along with kurtosis analysis technique, demonstrates superior performance and enhanced detection accuracy compared to state-of-the-art techniques.

A multi-step water quality prediction model based on the Savitzky-Golay filter and Transformer optimized network.

Effective water quality prediction techniques are essential for the sustainable development of water resources and implementation of emergency response mechanisms. However, the water environment conditions are complex, and the presence of a large amount of noise in the water quality data makes it difficult to reveal the long-term trends or cycles of the data, affecting the acquisition of serial correlation in the data. In addition, the loss function based on the vertical Euclidean distance will produce a prediction lag problem, and it is difficult to make an accurate multi-step prediction of water quality series. This paper presents a multi-step water quality prediction model for watersheds that combines Savitzky-Golay (SG) filter with Transformer optimized networks. Among them, the SG filter highlights data trend change and improves sequence correlation by smoothing the potential noise of original data. The transformer network adopts a sequence-to-sequence framework, which contains a position encoding module and a self-attentive mechanism to perform multi-step prediction while effectively obtaining the sequence correlation. Moreover, the DIstortion Loss including shApe and TimE (DILATE) loss function is introduced into the model to solve the problem of prediction lag from two aspects of shape error and time error to improve the model's generalization ability. An example validates the model with the benchmark model at four monitoring stations in the Lanzhou section of the Yellow River basin in China. The results show that the predictions of the proposed model have the correct shape, temporal positioning, and the best accuracy in a multi-step prediction task for four sites. It can provide a decision-making basis for comprehensive water quality control and pollutant control in the basin.

An Integrated Method for Tunnel Health Monitoring Data Analysis and Early Warning: Savitzky-Golay Smoothing and Wavelet Transform Denoising Processing.

A tunnel health monitoring (THM) system ensures safe operations and effective maintenance. However, how to effectively process and denoise several data collected by THM remains to be addressed, as well as safety early warning problems. Thus, an integrated method for Savitzky-Golay smoothing (SGS) and Wavelet Transform Denoising (WTD) was used to smooth data and filter noise, and the coefficient of the non-uniform variation method was proposed for early warning. The THM data, including four types of sensors, were attempted using the proposed method. Firstly, missing values, outliers, and detrend in the data were processed, and then the data were smoothed by SGS. Furthermore, data denoising was carried out by selecting wavelet basis functions, decomposition scales, and reconstruction. Finally, the coefficient of non-uniform variation was employed to calculate the yellow and red thresholds. In data smoothing, it was found that the Signal Noise Ratio (SNR) and Root Mean Square Error (RMSE) of SGS smoothing were superior to those of the moving average smoothing and five-point cubic smoothing by approximately 10% and 30%, respectively. An interesting phenomenon was discovered: the maximum and minimum values of the denoising effects with different wavelet basis functions after selection differed significantly, with the SNR differing by 14%, the RMSE by 8%, and the r by up to 80%. It was found that the wavelet basis functions vary, while the decomposition scales are consistently set at three layers. SGS and WTD can effectively reduce the complexity of the data while preserving its key characteristics, which has a good denoising effect. The yellow and red warning thresholds are categorized into conventional and critical controls, respectively. This early warning method dramatically improves the efficiency of tunnel safety control.

The Prediction of Residual Electrical Life in Alternating Current Circuit Breakers Based on Savitzky-Golay-Long Short-Term.

In order to improve the accuracy of predicting the remaining electrical life of AC circuit breakers, ensure the safe operation of electrical equipment, and reduce economic losses caused by equipment failures, this paper studies a method based on the Savitzky-Golay convolution smoothing long short-term memory neural network for predicting the electrical life of AC circuit breakers. First, a full lifespan test is conducted to obtain degradation data throughout the entire life cycle of the AC circuit breaker, from which feature parameters that effectively reflect its operational state are extracted. Next, principal component analysis and the maximum information coefficient are used to remove redundancy in the feature parameters and choose the best subset of features. Subsequently, the Savitzky-Golay convolutional smoothing algorithm is employed to smooth the feature sequence, reducing the impact of noise and outliers on the feature sequence while preserving its main trends. Then, a secondary feature extraction is performed on the smoothed feature subset to obtain the optimal secondary feature subset. Finally, the remaining electrical lifespan of the AC circuit breaker is treated as a long-term sequence problem and the long short-term memory neural network method is used for precise time-series forecasting. The proposed model outperforms backpropagation neural networks and the gate recurrent unit in terms of prediction precision, achieving an impressive 97.4% accuracy. This demonstrates the feasibility of using time-series forecasting for predicting the residual electrical lifespan of electrical equipment and provides a reference for optimizing the method of predicting remaining electrical life.

Non-Contact Assessment of Swallowing Dysfunction Using Smartphone Captured Skin Displacements.

Early and accurate dysphagia diagnosis is essential for reducing the risk of associated co-morbidities and mortalities. Barriers to current evaluation methods may alter the effectiveness of identifying at-risk patients. This preliminary study evaluates the feasibility of using iPhone X-captured videos of swallowing as a non-contact dysphagia screening tool. Video recordings of the anterior and lateral necks were captured simultaneously with videofluoroscopy in dysphagic patients. Videos were analyzed using an image registration algorithm (phase-based Savitzky-Golay gradient correlation (P-SG-GC)) to determine skin displacements over hyolaryngeal regions. Biomechanical swallowing parameters of hyolaryngeal displacement and velocity were also measured. Swallowing safety and efficiency were assessed by the Penetration Aspiration Scale (PAS), Residue Severity Ratings (RSR), and the Normalized Residue Ratio Scale (NRRS). Anterior hyoid excursion and horizontal skin displacements were strongly correlated with swallows of a 20 mL bolus (rs = 0.67). Skin displacements of the neck were moderately to very strongly correlated with scores on the PAS (rs = 0.80), NRRS (rs = 0.41-0.62), and RSR (rs = 0.33). This is the first study to utilize smartphone technology and image registration methods to produce skin displacements indicating post-swallow residual and penetration-aspiration. Enhancing screening methods provides a greater chance of detecting dysphagia, reducing the risk of negative health impacts.

Investigating spectroscopic and copper binding characteristics of dissolved organic matter in wastewater using EEMs with two-dimensional Savitzky-Golay second-order differentiation-PARAFAC.

Dissolved organic matter (DOM) in wastewater interacts with heavy metal particles in aquatic environments, which changes their dynamics and bioavailability. For quantifying the DOM, an excitation-emission matrix (EEM) paired alongside parallel factor analysis (PARAFAC) is typically employed. However, a drawback of PARAFAC has been revealed in recent studies, i.e., the rise of overlapping spectra or wavelength shifts in fluorescent components. Here, traditional EEM-PARAFAC and, for the first time, two-dimensional Savitzky-Golay second-order differential-PARAFAC (2D-SG-2nd-df-PARAFAC) were used to study the DOM-heavy metal binding. The samples from four treatment units of a wastewater treatment plant, i.e., influent, anaerobic, aerobic, and effluent, underwent the process of fluorescence titration with Cu2+. Four components were separated with dominant peaks in regions I, II, and III (proteins and fulvic acid-like) through PARAFAC and 2D-SG-2nd-df-PARAFAC. A single peak was observed in region V (humic acid-like) by PARAFAC. In addition, Cu2+-DOM complexation indicated clear differences in DOM compositions. The binding strength increased between Cu2+ and fulvic acid-like components in contrast to protein-like components from influent to the effluent, and increasing fluorescence intensity with the addition of Cu2+ in the effluent indicated changes in their structural composition. Moreover, when comparing both methods, the 2D-SG-2nd-df-PARAFAC provided the components without peak shifts and better fitting for Cu2+-DOM complexation model, demonstrating it to be a more reliable technique compared to only traditional PARAFAC for DOM characterization and quantifying metal-DOM in wastewater.

Machine Fault Detection Using a Hybrid CNN-LSTM Attention-Based Model.

The predictive maintenance of electrical machines is a critical issue for companies, as it can greatly reduce maintenance costs, increase efficiency, and minimize downtime. In this paper, the issue of predicting electrical machine failures by predicting possible anomalies in the data is addressed through time series analysis. The time series data are from a sensor attached to an electrical machine (motor) measuring vibration variations in three axes: X (axial), Y (radial), and Z (radial X). The dataset is used to train a hybrid convolutional neural network with long short-term memory (CNN-LSTM) architecture. By employing quantile regression at the network output, the proposed approach aims to manage the uncertainties present in the data. The application of the hybrid CNN-LSTM attention-based model, combined with the use of quantile regression to capture uncertainties, yielded superior results compared to traditional reference models. These results can benefit companies by optimizing their maintenance schedules and improving the overall performance of their electric machines.

Searching for Alternatives to the Savitzky-Golay Filter in the Spectral Processing Domain.

An elegant, well-established effective data filter concept, proposed originally by Abraham Savitzky and Marcel J.E. Golay, is undoubtedly a very effective tool, however not free from limitations and drawbacks. Despite the latter, over the years it has become a "monopolist" in many fields of spectra processing, claiming a "commercial" superiority over alternative approaches, which would potentially allow to obtain equivalent or in some cases even more reliable results. In order to show that basic operations performed on spectral datasets, like smoothing or differentiation, do not have to be equated to the application of the one particular single algorithm, several of such alternatives are briefly presented within this paper and discussed with regard to their practical realization. A special emphasis is put on the fast Fourier methodology (FFT), being widespread in the general domain of signal processing. Finally, a user-friendly Matlab routine, in which the outlined algorithms are implemented, is shared, so that one can select and apply the technique of spectral data processing more adequate for their individual requirements without the need to code it prior to use.

Optimal Temporal Filtering of the Cosmic-Ray Neutron Signal to Reduce Soil Moisture Uncertainty.

Cosmic ray neutron sensors (CRNS) are increasingly used to determine field-scale soil moisture (SM). Uncertainty of the CRNS-derived soil moisture strongly depends on the CRNS count rate subject to Poisson distribution. State-of-the-art CRNS signal processing averages neutron counts over many hours, thereby accounting for soil moisture temporal dynamics at the daily but not sub-daily time scale. This study demonstrates CRNS signal processing methods to improve the temporal accuracy of the signal in order to observe sub-daily changes in soil moisture and improve the signal-to-noise ratio overall. In particular, this study investigates the effectiveness of the Moving Average (MA), Median filter (MF), Savitzky-Golay (SG) filter, and Kalman filter (KF) to reduce neutron count error while ensuring that the temporal SM dynamics are as good as possible. The study uses synthetic data from four stations for measuring forest ecosystem-atmosphere relations in Africa (Gorigo) and Europe (SMEAR II (Station for Measuring Forest Ecosystem-Atmosphere Relations), Rollesbroich, and Conde) with different soil properties, land cover and climate. The results showed that smaller window sizes (12 h) for MA, MF and SG captured sharp changes closely. Longer window sizes were more beneficial in the case of moderate soil moisture variations during long time periods. For MA, MF and SG, optimal window sizes were identified and varied by count rate and climate, i.e., estimated temporal soil moisture dynamics by providing a compromise between monitoring sharp changes and reducing the effects of outliers. The optimal window for these filters and the Kalman filter always outperformed the standard procedure of simple 24-h averaging. The Kalman filter showed its highest robustness in uncertainty reduction at three different locations, and it maintained relevant sharp changes in the neutron counts without the need to identify the optimal window size. Importantly, standard corrections of CRNS before filtering improved soil moisture accuracy for all filters. We anticipate the improved signal-to-noise ratio to benefit CRNS applications such as detection of rain events at sub-daily resolution, provision of SM at the exact time of a satellite overpass, and irrigation applications.