Synthesis of Cellulose Acetate Butyrate Microspheres as Precursor for Hard Carbon-Based Electrodes in Symmetric Supercapacitors.

Cellulose microspheres have a wide range of applications due to their unique properties and versatility. Various preparation methods have been explored to tailor these microspheres for specific applications. Among these methods, the acetate method using cellulose acetate is well known. However, replacement of the acetate group through the butyrate group significantly extends the variety of morphological properties. In the present work, microspheres based on cellulose acetate butyrate are being developed with modified characteristics in terms of particle size, porosity, surface morphology and the inner structure of the microspheres. While the inner structure of cellulose acetate microspheres is predominantly porous, microspheres prepared from cellulose acetate butyrate are mainly filled or contain several smaller microspheres. Carbon materials from cellulose acetate butyrate microspheres exhibit a high specific surface area of 567 m2 g-1, even without further activation. Activation processes can further increase the specific surface area, accompanied by an adaptation of the pore structure. The prepared carbons show promising results in symmetrical supercapacitors with aqueous 6 M KOH electrolytes. Activated carbons derived from cellulose acetate butyrate microspheres demonstrate an energy density of 12 Wh kg-1 at a power density of 0.9 kW kg-1.

Activated Carbon for CO2 Adsorption from Avocado Seeds Activated with NaOH: The Significance of the Production Method.

The rise in atmospheric greenhouse gases like CO2 is a primary driver of global warming. Human actions are the primary factor behind the surge in CO2 levels, contributing to two-thirds of the greenhouse effect over the past decade. This study focuses on the chemical activation of avocado seeds with sodium hydroxide (NaOH). The influence of various preparation methods was studied under the same parameters: carbon precursor to NaOH mass ratio, carbonization temperature, and nitrogen flow. For two samples, preliminary thermal treatment was applied (500 °C). NaOH was used in the form of a saturated solution as well as dry NaOH. The same temperature of 850 °C of carbonization combined with chemical activation was applied for all samples. The applied modifications resulted in the following textural parameters: specific surface area from 696 to 1217 m2/g, total pore volume from 0.440 to 0.761 cm3/g, micropore volume from 0.159 to 0.418 cm3/g. The textural parameters were estimated based on nitrogen sorption at -196 °C. The XRD measurements and SEM pictures were also performed. CO2 adsorption was performed at temperatures of 0, 10, 20, and 30 °C and pressure up to 1 bar. In order to calculate the CO2 selectivity over N2 nitrogen adsorption at 20 °C was investigated. The highest CO2 adsorption (4.90 mmol/g) at 1 bar and 0 °C was achieved.

Structural and Electrochemical Evolution of Water Hyacinth-Derived Activated Carbon with Gamma Pretreatment for Supercapacitor Applications.

This study introduces a gamma pretreatment of water hyacinth powder for activated carbon (AC) production with improved electrochemical properties for supercapacitor applications. The structural and morphological changes of post-irradiation were meticulously analyzed using scanning electron microscopy (SEM), Raman spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) analysis, and X-ray photoelectron spectroscopy (XPS). The pretreatment significantly modifies the pore structure and reduces the particle size of the resulting activated carbon (WHAC). Nitrogen adsorption-desorption isotherms indicated a substantial increase in micropore volume with escalating doses of gamma irradiation. Electrochemically, the activated carbon produced from pretreated WH at 100 kGy exhibited a marked increase in specific capacitance, reaching 257.82 F g-1, a notable improvement over the 95.35 F g-1 of its untreated counterpart, while maintaining 99.40% capacitance after 7000 cycles. These findings suggest that gamma-pretreated biomasses are promising precursors for fabricating high-performance supercapacitor electrodes, offering a viable and environmentally friendly alternative for energy storage technology development.

A comprehensive review on the production of durian fruit waste-derived bioadsorbents for water treatment.

Global water pollution by various pollutants is becoming an urgent problem. The conversion of durian fruit waste into adsorbents can help to mitigate this issue. Transforming durian waste into adsorbents can reduce pollution risk from waste discharged directly into the environment, while also effectively eliminating existing contaminants. Here, this work explores the potential of durian fruit waste and supplies insights into the synthesis and application of durian fruit waste-derived adsorbents such as biosorbents, modified-biosorbents, biochars, activated carbons, and composites. Several factors affecting the adsorption process of pollutants and the mechanism how pollutants can be adsorbed onto durian fruit waste-derived adsorbents are elucidated. This review also analyzes some aspects of limitations and prospects of biosorbents derived from durian fruit waste. It is anticipated that the promising properties and applications of durian fruit waste-derived adsorbents open up a new field for water waste treatment.

Thermochemical Activation of Wood with NaOH, KOH and H3PO4 for the Synthesis of Nitrogen-Doped Nanoporous Carbon for Oxygen Reduction Reaction.

Carbonization of biomass residues followed by activation has great potential to become a safe process for the production of various carbon materials for various applications. Demand for commercial use of biomass-based carbon materials is growing rapidly in advanced technologies, including in the energy sector, as catalysts, batteries and capacitor electrodes. In this study, carbon materials were synthesized from hardwood using two carbonization methods, followed by activation with H3PO4, KOH and NaOH and doping with nitrogen. Their chemical composition, porous structure, thermal stability and structural order of samples were studied. It was shown that, despite the differences, the synthesized carbon materials are active catalysts for oxygen reduction reactions. Among the investigated carbon materials, NaOH-activated samples exhibited the lowest Tafel slope values, of -90.6 and -88.0 mV dec-1, which are very close to the values of commercial Pt/C at -86.6 mV dec-1.

The Resource Utilization of Poplar Leaves for CO2 Adsorption.

Every late autumn, fluttering poplar leaves scatter throughout the campus and city streets. In this work, poplar leaves were used as the raw material, while H3PO4 and KOH were used as activators and urea was used as the nitrogen source to prepare biomass based-activated carbons (ACs) to capture CO2. The pore structures, functional groups and morphology, and desorption performance of the prepared ACs were characterized; the CO2 adsorption, regeneration, and kinetics were also evaluated. The results showed that H3PO4 and urea obviously promoted the development of pore structures and pyrrole nitrogen (N-5), while KOH and urea were more conductive to the formation of hydroxyl (-OH) and ether (C-O) functional groups. At optimal operating conditions, the CO2 adsorption capacity of H3PO4- and KOH-activated poplar leaves after urea treatment reached 4.07 and 3.85 mmol/g, respectively, at room temperature; both showed stable regenerative behaviour after ten adsorption-desorption cycles.

Gasification chars and activated carbon: Systematic physico-chemical characterization and effect on biogas production.

Gasification residues/chars (GR) and activated carbon (AC) are added to wastewater treatment processes mainly as a fourth purification stage, e.g., to adsorb heavy metals or pharmaceutical residues. However, the effects of GR or AC, which are transferred to the anaerobic digestion (AD) via the sludge, are not yet fully understood. Although, the positive effect of char addition on AD has been demonstrated in several investigations, systematic studies with chemically well described chars are still missing. Therefore, in this study, different chars were characterized in detail, subjected to AD in different concentrations, and their effect on methane production investigated. GR of a gasification plant with a floating fixed bed technology, carbon made by chemical impregnation with ZnCl2 from waste-wood, carbon produced by thermochemical activation with CO2 from GR and commercial powdered AC were used for the experiments. Among others, thermogravimetric analysis, physisorption, pH, and conductivity analysis were used to characterize the chars. Mesophilic AD batch tests with different concentrations (0.025, 0.05, 0.5, 1.0, 7.0, 14.0 gL-1) of all chars (GR and ACs, respectively) were performed with digester sludge from a wastewater treatment plant for a period of 47 d. Volatile fatty acids (VFA) as well as biogas production and CH4 concentrations were monitored. It could be shown, that concentrations below 1.0 g char L-1 did not result in significant effects on CH4 and/or VFA production, whereas high concentrations of GR and AC influenced both, the CH4 yield and kinetics. Depending on the production process and the characteristics of the chars, the effect on AD varied, whereby both, positive and negative effects on biogas yield and methane production were observed. This study provides the first systematic evaluation of char application to AD processes, and therefore allows for better predictions of char applicability and effect.

Evaluation of acetanilide and antipyrine adsorption on lignin-derived activated carbons.

In this study, the removal of two emerging pollutants (EPs), antipyrine and acetanilide, through adsorption on activated carbons (ACs) prepared by chemical activation of Organosolv lignin with H3PO4 were evaluated. ACs with different pore size distribution were obtained at different impregnation ratios (H3PO4/lignin, 0.5-3.0 w/w) and activating temperatures (500-900 °C). The porosity and surface chemistry of the ACs were determined, and a bimodal size distribution of micropores and narrow mesopores was observed for the different ACs. These ACs were tested for antipyrine and acetanilide adsorption in aqueous solutions in a batch system at 20 °C and low concentration levels (0.5-10 ppm). In general, the ACs exhibited higher adsorption affinity to acetanilide than to antipyrine due to its smaller molecular size. Langmuir adsorption isotherm was able to describe the adsorption equilibrium data. A new Linear Driving Force (2-LDF) kinetic model, based on the bimodal size distribution of micropores and narrow mesopores observed for the ACs has been developed. The new model provided a more accurate description of the batch adsorption rates than that obtained from conventional kinetic models, and also enabled to relate the pore size distribution of the adsorbent with the adsorption kinetics. The validity of this model was checked in small-scale column fixed bed adsorption for the AC showing the highest affinity for both EP. The kinetic model and equilibrium adsorption isotherm obtained from the batch experiments were successfully used to provide an accurate description of the bed service time and the full breakthrough profile of acetanilide and antipyrine.

Investigation of Ionic Polymers' Stabilizing and Flocculating Properties in Dispersed Activated Carbons Systems.

Activated carbons obtained via the thermochemical treatment of lemon balm and mint herbs were applied for ionic polymers adsorption, which directly affects the stability of these types of aqueous suspensions. The examined carbonaceous materials were characterized by well-developed specific surface area (approximately 1000 m2/g) and mesoporous structure. The adsorbed amounts of anionic poly(acrylic acid) and cationic polyethyleneimine from one-component solutions reached significant levels, but the efficiency of adsorption of these compounds from binary solutions slightly decreased. Moreover, the ionic polymers showed stabilizing properties towards the activated carbons suspensions. For both adsorbents, the most stable suspensions were systems containing both types of polymeric macromolecules with different ionic characters. This was due to the occurrence of electrosteric and depletion stabilization mechanisms. Furthermore, the zeta potential and size of particle aggregates were also influenced by the presence of polymers in the aqueous suspensions of activated carbons.

Application of Activated Carbons Obtained from Polymer Waste for the Adsorption of Dyes from Aqueous Solutions.

Plastic waste disposal is a major environmental problem worldwide. One recycling method for polymeric materials is their conversion into carbon materials. Therefore, a process of obtaining activated carbons through the carbonization of waste CDs (as the selected carbon precursor) in an oxygen-free atmosphere, and then the physical activation of the obtained material with CO2, was developed. Dyes such as methylene blue (MB) and malachite green (MG) are commonly applied in industry, which contaminate the water environment to a large extent and have a harmful effect on living organisms; therefore, adsorption studies were carried out for these cationic dyes. The effects of the activation time on the physicochemical properties of the activated materials and the adsorption capacity of the dyes were investigated. The obtained microporous adsorbents were characterized by studying the porous structure based on low-temperature nitrogen adsorption/desorption, scanning electron microscopy (SEM-EDS), elemental analysis (CHNS), Raman spectroscopy, X-ray powder diffraction (XRD), infrared spectroscopy (ATR FT-IR), thermal analysis (TG, DTG, DTA), Boehm's titration method, and pHpzc (the point of zero charge) determination. Moreover, adsorption studies (equilibrium and kinetics) were carried out. The maximum adsorption capacities (qm exp) of MB and MG (349 mg g-1 and 274 mg g-1, respectively) were identified for the obtained material after 8 h of activation. The results show that the use of waste CDs as a carbon precursor facilitates the production of low-cost and effective adsorbents.

Spherical Lignin-Derived Activated Carbons for the Adsorption of Phenol from Aqueous Media.

In this work, a synthesis and activation path, which enabled the preparation of spherical activated carbon from a lignin precursor, characterized by high adsorption capacity in the removal of phenolic compounds from water, was successfully developed. Two industrial by-products, i.e., Kraft lignin and sodium lignosulfonate, were used to form spherical nanometric lignin grains using pH and solvent shift methods. The obtained materials became precursors to form porous activated carbons via chemical activation (using K2CO3 or ZnCl2 as activating agents) and carbonization (in the temperature range of 600-900 °C). The thermal stabilization step at 250 °C was necessary to ensure the sphericity of the grains during high-temperature heat treatment. The study investigated the influence of the type of chemical activator used, its quantity, and the method of introduction into the lignin precursor, along with the carbonization temperature, on various characteristics including morphology (examined by scanning electron microscopy), the degree of graphitization (evaluated by powder X-ray diffraction), the porosity (assessed using low-temperature N2 adsorption), and the surface composition (analyzed with X-ray photoelectron spectroscopy) of the produced carbons. Finally, the carbon materials were tested as adsorbents for removing phenol from an aqueous solution. A conspicuous impact of microporosity and a degree of graphitization on the performance of the investigated adsorbents was found.

The Impact of N/O-Functional Groups on the Sorption Capabilities of Activated Carbons Derived from Furfuryl Alcohol.

This work describes the effect of nitrogen and oxygen functional groups on the sorption properties of activated carbons produced from furfuryl alcohol. The poly(furfuryl) alcohol underwent carbonization in nitrogen, ammonia, and ammonia and air (in a 3:2 proportion) atmospheres at 600 °C for 4 h. The resulting materials were subsequently activated in a carbon dioxide atmosphere for 1 h at temperatures of 700 °C, 800 °C, 900 °C, and 1000 °C. The X-ray photoelectron spectroscopy (XPS) findings suggest that ammoxidation is superior to amination in terms of nitrogen doping. The maximum nitrogen concentration achieved after ammoxidation was 25 at.%, which decreased to 4 at.% after activation. Additionally, it was observed that oxygen functional groups have a greater impact on porous structure development compared to nitrogen functional groups. The materials activated through carbonization under an ammonia/air atmosphere attained the highest oxygen concentration of roughly 19 at.% as confirmed by XPS. The materials were evaluated for their sorption capacities for carbon dioxide and ethylene, which were 2.2 mmol/g and 2.9 mmol/g, respectively, at 30 °C.

Preparation of nitrogen-doped activated carbon used for catalytic oxidation removal of H2S.

In this study, nitrogen-doped modified activated carbons were synthesized for H2S removal from Zhuxi activated carbon and 4,4'-bipyridine as raw material and nitrogen source, respectively. The synthesis strategy was hydrothermal treatment and subsequent NH3 annealing, and the formation and conversion patterns of the different N configurations were investigated. When the annealing temperatures were 500 °C and 600 °C, N-5 account for the majority. As the annealing temperature increased, the proportion of N-6 gradually increased. After the temperature increased to 1000 °C, N-5 and N-6 were converted to N-Q to a certain degree, while the amount of nitrogen doping decreased significantly. The sample H160-0.2-800 exhibited excellent H2S removal with a high sulfur capacity of up to 206.89 mg/g, significantly higher than that of the original activated carbon ZX1200 (67.56 mg/g). The reason for this is that the micropores (Vmic = 0.5155 cm3/g) and specific surface area (SBET = 1369.5 m2/g) of the modified activated carbon are more developed than those of the original activated carbon. A high nitrogen content (3.14 wt%) and N-6 configuration proportion (73.56 %) are significant reasons for the excellent adsorption properties. The mechanism of the catalytic oxidation was investigated. The introduction of surface nitrogen-containing functional groups alkalizes the activated carbon surface, enhancing the adsorption and dissociation of H2S and O2 and facilitating the formation of sulfur radicals and elemental sulfur.

Efficient removal of triclosan from water through activated carbon adsorption and photodegradation processes.

This study investigated the application of adsorption with activated carbons (ACs) and photodegradation to reduce the concentration of triclosan (TCS) in aqueous solutions. Concerning adsorption, ACs (Darco, Norit, and F400) were characterised and batch experiments were performed to elucidate the effect of pH on equilibrium. The results showed that at pH = 7, the maximum adsorption capacity of TCS onto the ACs was 18.5 mg g-1 for Darco, 16.0 mg g-1 for Norit, and 15.5 mg g-1 for F400. The diffusional kinetic model allowed an adequate interpretation of the experimental data. The effective diffusivity varied and increased with the amount of TCS adsorbed, from 1.06 to 1.68 × 10-8 cm2 s-1. In the case of photodegradation, it was possible to ensure that the triclosan molecule was sensitive to UV light of 254 nm because the removal was over 80 % using UV light. The removal of TCS increased in the presence of sulfate radicals. It was possible to identify 2,4-dichlorophenol as one of the photolytic degradation products of triclosan, which does not represent an environmental hazard at low concentrations of triclosan in water. These results confirm that the use of AC Darco, Norit, and F400 and that photodegradation processes with UV light and persulfate radicals are effective in removing TCS from water, reaching concentration levels that do not constitute a risk to human health or environmental hazard. Both methods effectively eliminate pollutants with relatively easy techniques to implement.

Adsorption of 2,4-dichlorophenoxyacetic acid on activated carbons from macadamia nut shells.

This study reports on the application of activated carbons from macadamia nut shells as adsorbents for the removal of 2,4-dichlorophenoxyacetic acid, a commonly used pesticide, from water. Different activating agents (FeCl3, ZnCl2, KOH and H3PO4) were used to obtain adsorbents within a wide range of porous texture and surface properties. The characterization of the resulting activated carbons was performed by N2 adsorption-desorption, elemental analysis, TG and pHPZC. The adsorption experiments were conducted in batch at 25, 45 and 65 °C. The adsorption kinetics on activated carbons obtained with FeCl3 H3PO4 or KOH was well described by the pseudo-second order model, whereas for the resulting from ZnCl2 activation the experimental data fit better the pseudo-first order model. The equilibrium studies were performed with the KOH- and ZnCl2-activated carbons, the two showing higher surface area values. In both cases, high adsorption capacities were obtained (c.a. 600 mg g-1) and the experimental data were better described by the Langmuir and Toth models. The thermodynamic study allows concluding the spontaneous and endothermic character of the adsorption process, as well as an increase of randomness at the solid/liquid interface. Breakthrough curves were also obtained and fitted to the logistic model.

Highly efficient adsorption of ciprofloxacin from aqueous solutions by waste cation exchange resin-based activated carbons: Performance, mechanism, and theoretical calculation.

This study focused on the preparation of a highly efficient activated carbon adsorbent from waste cation exchange resins through one-step carbonization to remove ciprofloxacin (CIP) from aqueous solutions. Scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectrometry, and X-ray photoelectron spectroscopy were used to characterize the physicochemical properties of the carbonized materials. The CIP removal efficiency, influencing factors, and adsorption mechanisms of CIP on the carbonized resins were investigated. Density functional theory (DFT) computations were performed to elucidate the adsorption mechanisms. The CIP removal reached 93 % when the adsorbent dosage was 300 mg/L at 25 °C. The adsorption capacity of the carbonized resins to CIP gradually decreased with an increasing pH from 3.0 to 7.0 and sharply declined with a pH from 7.0 to 11.0. The adsorption process better fitted by the pseudo second-order kinetic and Langmuir models, indicating that the interaction between CIP and the carbonized resins was monolayer adsorption. The maximum adsorption capacity fitted by the Langmuir model was 384.4 mg/g at 25 °C. Microstructural analysis showed that the adsorption of CIP on the carbonized resins was a joint effect of H-bonding, ion exchange, and graphite-N adsorption. Computational results signified the strong H-bonding and ion exchange interactions existed between CIP and carbonized resins. The high adsorption and reusability suggest that waste cation exchange resin-based activated carbons can be used as an effective and reusable adsorbent for removing CIP from aqueous solutions.

An Effective Strategy to Synthesize Well-Designed Activated Carbon Derived from Coal-Based Carbon Dots via Oxidation before Activation with a Low KOH Content as Supercapacitor Electrodes.

The development of coal-based activated carbon for supercapacitors provides a robust and effective approach toward the clean and efficient use of coal, and it also offers high-quality and low-cost raw materials for energy storage devices. However, the one-step activation method for preparing coal-based activated carbon has problems, such as difficulty in introducing surface-functional groups and high KOH dosage. In our work, activated carbon was prepared through an effective strategy of oxidation and KOH activation with a low KOH content by employing coal-based carbon dots as raw material. The influence of temperature during the KOH activation of carbon dots on a specific surface area, pore structure, and various quantities and types of surface-functional groups, as well as on the electrochemical performance of supercapacitors, was systematically studied. The as-prepared sample, with the alkali-carbon ratio of 0.75, processes a large specific surface area (1207 m2 g-1) and abundant surface-functional groups, which may provide enormous active sites and high wettability, thus bringing in high specific capacitance and boosted electrochemical performances. The oxygen and nitrogen content of the activated carbon decreases while the carbon content increases, and the activation temperature also increases. The as-prepared activated carbon reaches the highest specific capacitance of 202.2 F g-1 in a 6 M KOH electrolyte at a current density of 10 A g-1. This study provides new insight into the design of high-performance activated carbon and new avenues for the application of coal-based carbon dots.

Electrochemical Performance of Nitrogen Self-Doping Carbon Materials Prepared by Pyrolysis and Activation of Defatted Microalgae.

Pyrolysis and activation processes are important pathways to utilize residues after lipid extraction from microalgae in a high-value way. The obtained microalgae-based nitrogen-doped activated carbon has excellent electrochemical performance. It has the advantage of nitrogen self-doping using high elemental nitrogen in microalgae. In this study, two kinds of microalgae, Nanochloropsis and Chlorella, were used as feedstock for lipid extraction. The microalgae residue was firstly pyrolyzed at 500 °C to obtain biochar. Then, nitrogen-doped activated carbons were synthesized at an activation temperature of 700-900 °C with different ratios of biochar and KOH (1:1, 1:2, and 1:4). The obtained carbon materials presented rich nitrogen functional groups, including quaternary-N, pyridine-N-oxide, pyrrolic-N, and pyridinic-N. The nitrogen content of microalgae-based activated carbon material was up to 2.62%. The obtained materials had a specific surface area of up to 3186 m2/g and a pore volume in the range of 0.78-1.54 cm3/g. The microporous pore sizes of these materials were distributed at around 0.4 nm. Through electrochemical testing such as cyclic voltammetry and galvanostatic charge-discharge of materials, the materials exhibited good reversibility and high charge-discharge efficiency. The sample, sourced from microalgae Chlorella residue at activation conditions of 700 °C and biochar/KOH = 1:4, exhibited excellent endurance of 94.1% over 5000 cycles at 2 A/g. Its high specific capacitance was 432 F/g at 1 A/g.

Production of Mineral-Carbon Composites and Activated Carbons as a Method of Used Gear Oil, Ashes, and Low-Quality Brown Coals Management.

The main objective of this study was to assess the usefulness of the low-quality brown coal, ash obtained as a result of its combustion, as well as used gear oil for the production of mineral-carbon adsorbents. The adsorbents were characterized in terms of textural parameters, acidic-basic character of the surface, mineral matter contribution to the structure, as well as their suitability for drinking water purification. Adsorption tests were carried out against two synthetic dyes-methylene blue and methyl orange. In order to understand the nature of the organic pollutants adsorption, the effect of the initial dye concentration, temperature, and pH of the system as well as the phase contact time were investigated. The obtained mineral-carbon composite and activated carbons significantly differed not only in terms of the elemental composition and chemical character of the surface (from slightly acidic to strongly alkaline), but also showed a very diverse degree of specific surface development (from 21 to 656 m2/g) and the type of porous structure generated (from micro/mesoporous to typically mesoporous). Adsorption tests showed that the efficiency of organic dye removal from aqueous solutions primarily depends on the type of the adsorbent and adsorbate applied, and, to a lesser extent, on the temperature and pH of the system. In turn, kinetic studies have shown that the sorption of dyes on such materials is consistent with a pseudo-second-order kinetics model, regardless of the type of adsorbed dye.

CO2 adsorption on carbonaceous materials obtained from forestry and urban waste materials: a comparative study.

The increasing emissions of gaseous pollutants of anthropogenic origin, such as carbon dioxide (CO2), which causes global warming, have raised great interest in developing and improving processes that allow their mitigation. Among them, adsorption on porous materials has been proposed as a sustainable alternative. This work presents a study of CO2 equilibrium adsorption at low temperatures (0, 10, and 20 °C) over a wide range of low pressures, on activated carbon derived from Eucalyptus (ES) and Patula pine (PP) forest waste, and carbonaceous material derived from waste tires (WT). The precursors of these materials were previously prepared, and their physicochemical properties were characterized. ES and PP were thermochemically treated with phosphoric acid, and WT was oxidized with nitric acid. Additionally, these materials were used to obtain monoliths using uniaxial compaction techniques and different binding agents, with better results obtained with montmorillonite. A total of six adsorbent solids had their textural and chemical properties characterized and were tested for CO2 adsorption. The highest specific surface area (1405 m2 g-1), and micropore properties were found for activated carbon derived from Eucalyptus whose highest adsorption capacity ranged from 2.27 mmol g-1 (at 0 °C and 100 kPa) to 1.60 mmol g-1 (at 20 °C and 100 kPa). The activated carbon monoliths presented the lowest CO2 adsorption capacities; however, the studied materials showed high potential for CO2 capture and storage applications at high pressures. The isosteric heats of adsorption were also estimated for all the materials and ranged from 16 to 45 kJ mol-1 at very low coverage explained by the energetic heterogeneity and weak repulsive interactions among adsorbed CO2 molecules.