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1.
J Surg Res ; 257: 597-604, 2021 01.
Artículo en Inglés | MEDLINE | ID: mdl-32932192

RESUMEN

BACKGROUND: Standardized prescribing practices are recommended to decrease opioid abuse, however, data regarding the handling and disposal of leftover narcotics are lacking. This quality improvement project and analysis evaluated implementation of standardized prescribing, opioid education, and a narcotic disposal system. METHODS: This initiative was implemented over a 1-y period among patients who underwent breast surgery. The project included the following: 1) implementation of standardized prescribing, 2) voluntary and anonymous survey analysis, and 3) preoperative education regarding risks of opioids, charcoal disposal bag distribution, and follow-up survey to assess use and use of intervention. RESULTS: Preintervention surveys were completed by 53 patients, and 60% (n = 32) underwent lumpectomy. Narcotic prescriptions were filled by 90%; median number of pills taken was 3 (range 0-24), however 93% felt that a non-narcotic was more effective. Eighty three percentage of patients had unused pills, and 58% kept these pills in an unlocked cabinet. Postintervention surveys were completed by 66 patients, and 48% (n = 32) underwent lumpectomy. Narcotic prescriptions were filled by 88%, median number of pills taken was 4 (range 0-40), and 89% of patients had pills leftover. Sixty seven percentage of patients found the education handout useful and charcoal bag use was reported by 37% (n = 17). The median postoperative pain control satisfaction score was 4.5 (5-point Likert scale, 1 = very dissatisfied, 5 = very satisfied) on both preintervention and postintervention surveys. CONCLUSIONS: This study, which included standardized prescribing parameters, opioid education, and implementation of a disposal method, was found to be feasible, beneficial, and did not compromise postoperative pain control.


Asunto(s)
Analgésicos Opioides , Prescripciones de Medicamentos/normas , Trastornos Relacionados con Opioides/prevención & control , Dolor Postoperatorio/prevención & control , Neoplasias de la Mama/cirugía , Estudios de Factibilidad , Femenino , Humanos , Mastectomía Segmentaria/efectos adversos , Persona de Mediana Edad , Dolor Postoperatorio/etiología , Educación del Paciente como Asunto , Mejoramiento de la Calidad , Administración de Residuos/instrumentación
3.
Chemosphere ; 258: 127148, 2020 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-32535434

RESUMEN

Tetrahydrofuran (THF) is a common highly toxic cyclic aliphatic ether that frequently exists in waste gases. Removal of gaseous THF is a serious issue with important environmental ramifications. A novel three-phase airlift bioreactor (TPAB) loaded with immobilized cells was developed for efficient THF removal from gas streams. An effective THF-degrading transformant, Pseudomonas oleovorans GDT4, which contains the pTn-Mod-OTc-gfp plasmid and was tagged with a green fluorescent protein (GFP), was constructed. Continuous treatment of THF-containing waste gases was succeeded by the GFP-labelled cells immobilized with calcium alginate and activated carbon fiber in the TPAB for 60 days with >90% removal efficiency. The number of fluorescent cells in the beads reached 1.7 × 1011 cells·g-1 of bead on day 10, accounting for 83.3% of the total number of cells. The amount further increased to 3.0 × 1011 cells·g-1 of bead on day 40. However, it decreased to 2.5 × 1011 cells·g-1 of bead with a substantial increase in biomass in the liquid because of cell leakage and hydraulic shock. PCR-DGGE revealed that P. oleovorans was the dominant microorganism throughout the entire operation. The maximum elimination capacity was affected by empty bed residence time (EBRT). The capacity was only 25.9 g m-3·h-1 at EBRT of 80 s, whereas it reached 37.8 g m-3·h-1 at EBRT of 140 s. This work provides an alternative method for full-scale removal of gaseous THF and presents a useful tool for determining the biomass of a specific degrader in immobilized beads.


Asunto(s)
Reactores Biológicos/microbiología , Furanos/metabolismo , Pseudomonas oleovorans/metabolismo , Administración de Residuos/métodos , Alginatos/química , Biodegradación Ambiental , Biomasa , Fibra de Carbono , Células Inmovilizadas/metabolismo , Carbón Orgánico , Diseño de Equipo , Gases , Proteínas Fluorescentes Verdes/genética , Microbiota , Microorganismos Modificados Genéticamente , Pseudomonas oleovorans/citología , Pseudomonas oleovorans/genética , Administración de Residuos/instrumentación
4.
Artículo en Inglés | MEDLINE | ID: mdl-32475209

RESUMEN

Grilling restaurants are a major contributor to airborne particulate matter (PM) in metropolitan areas. In this study, the removal of PM during the grilling of pork belly using an orifice scrubber, which is a form of gas-induced spray scrubber, was assessed. During grilling, the particle mass concentration was the highest for 1.0 < PM ≤ 2.5 µm (55.5% of total PM emissions), followed by 0.5 < PM ≤ 1.0 (27.1%), PM ≤ 0.5 (10.7%), and PM > 2.5 µm (7.0%). The PM removal efficiency of the orifice scrubber at a gas flow of 4.5 m3 min-1 was > 99.7% for PM ≥ 2.5 µm, 89.4% for 1.0 < PM ≤ 2.5 µm, 62.1% for 0.5 < PM ≤ 1.0, and 36.5% for PM ≤ 0.5 µm. Although further research is necessary to optimize its use, the orifice scrubber offers a user-friendly technology for the control of PM in small grilling restaurants because of its simple design, uncomplicated operation, and satisfactory PM removal performance.


Asunto(s)
Contaminantes Atmosféricos/aislamiento & purificación , Contaminación del Aire/prevención & control , Material Particulado/aislamiento & purificación , Restaurantes , Administración de Residuos/instrumentación , Animales , Culinaria , Tamaño de la Partícula , Carne Roja , República de Corea , Porcinos
5.
Environ Sci Pollut Res Int ; 26(30): 31038-31054, 2019 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-31456151

RESUMEN

In this research, waste tyre rubber was used for activated carbon production with a novel route by modified physo-chemical approach. Potassium hydroxide and carbon dioxide were selected as chemical and physical activating agents, respectively and the process was carried out without carbonization under inert atmospheric conditions. The experiments were designed by applying the central composite design (CCD) as one of the subsets of response surface methodology (RSM). The effects of activation temperature (550-750 °C), activation time (15-75 min), impregnation ratio of KOH/rubber (0.75-3.75) and CO2 flow rate (200-400 mL/min) on production yield and specific surface area of produced activated carbon were studied. Based on the results, the 2FI and quadratic models were selected for production yield and specific surface area, respectively. The activation temperature was the main effective parameter on both responses in this process. The production yield and specific surface area of produced activated carbon at optimized conditions for each model were 47% and 928 m2/g, respectively. BET, XRF, XRD, FT-IR, EDS and FE-SEM analyses were carried out on the optimized sample of specific surface area model in order to investigate the residual salts and morphological porous structures. Based on the surface properties and the presence of sulfur compounds in produced activated carbon, this activated carbon has the ability of eliminating heavy metals such as mercury from industrial waste water.


Asunto(s)
Carbón Orgánico/química , Goma/química , Dióxido de Carbono/química , Carbón Orgánico/síntesis química , Diseño de Equipo , Hidróxidos/química , Microscopía Electrónica de Rastreo , Porosidad , Compuestos de Potasio/química , Espectrometría por Rayos X , Espectroscopía Infrarroja por Transformada de Fourier , Propiedades de Superficie , Temperatura , Administración de Residuos/instrumentación , Administración de Residuos/métodos , Residuos , Difracción de Rayos X
6.
Environ Sci Pollut Res Int ; 26(6): 5372-5380, 2019 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-30628002

RESUMEN

This research paper presents the results of an experimental investigation of the degradation of three different contaminants including progesterone (PGS), ibuprofen (IBU), and naproxen (NAP) using ZnO as the photocatalyst and ultraviolet (UV) light as a source for catalysts activation. Two operating parameters, namely, catalyst loading and initial concentration of contaminants, were tested in a batch photocatalytic reactor. To demonstrate the large-scale applications, experiments were also conducted in a submerged membrane photocatalytic reactor. It has proven that ZnO photocatalyst degraded the three contaminants very efficiently under almost all the studied experimental conditions, with efficiency rates of 92.3, 94.5, and 98.7 % for PSG, IBU, and NAP, respectively. The photodegradation kinetics study was performed to calculate the reaction rate constant, which is found to follow pseudo-first order kinetics. The membrane photocatalytic reactor was efficient to remove pollutants and it is observed that the degradation rate increases with increasing the membrane oscillation frequency approaching that of the stirred reactor.


Asunto(s)
Preparaciones Farmacéuticas/química , Administración de Residuos/instrumentación , Administración de Residuos/métodos , Óxido de Zinc/química , Catálisis , Contaminantes Ambientales/química , Diseño de Equipo , Ibuprofeno/química , Cinética , Naproxeno/química , Procesos Fotoquímicos , Fotólisis , Progesterona/química , Rayos Ultravioleta
7.
Artículo en Inglés | MEDLINE | ID: mdl-31906118

RESUMEN

Cattle slaughterhouses generate wastewater that is rich in organic contaminant and nutrients, which is considered as high strength wastewater with a high potential for energy recovery. Work was undertaken to evaluate the efficiency of the 12 L laboratory scale conventional and a modified upflow anaerobic sludge blanket (UASB) reactors (conventional, R1 and modified, R2), for treatment of cattle slaughterhouse wastewater (CSWW) under mesophilic condition (35 ± 1 °C). Both reactors were acclimated with synthetic wastewater for 30 days, then continuous study with real CSWW proceeds. The reactors were subjected to the same loading condition of OLR, starting from 1.75, 3, 5 10, 14, and 16 g L-1d-1, corresponding to 3.5, 6, 10, 20, 28, and 32 g COD/L at constant hydraulic retention time (HRT) of 24 h. The performance of the R1 reactor drastically dropped at OLR 10 g L-1d-1, and this significantly affected the subsequent stages. The steady-state performance of the R2 reactor under the same loading condition as the R1 reactor revealed a high COD removal efficiency of 94% and biogas and methane productions were 27 L/d and 89%. The SMP was 0.21 LCH4/gCOD added, whereas the NH3-N alkalinity ratio stood at 651 mg/L and 0.2. SEM showed that the R2 reactor was dominated by Methanosarcina bacterial species, while the R1 reactor revealed a disturb sludge with insufficient microbial biomass.


Asunto(s)
Mataderos , Biocombustibles , Reactores Biológicos , Eliminación de Residuos Líquidos/métodos , Administración de Residuos/métodos , Aguas Residuales , Anaerobiosis , Animales , Biomasa , Reactores Biológicos/microbiología , Bovinos , Eliminación de Residuos Líquidos/instrumentación , Administración de Residuos/instrumentación , Aguas Residuales/microbiología
8.
Waste Manag ; 81: 33-40, 2018 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-30527041

RESUMEN

Co-combustion experiments of municipal solid waste and coal were carried out in a drop tube furnace at high temperature 1300 °C. The effect of different simulated municipal solid waste (SMSW) added proportion (0, 7.5, 15, 20 and 25 wt%) in the blend fuels on the characteristics of gaseous pollutants emissions, e.g. CO, HCl, SO2, NOx, and heavy metals, and fly ash were studied. The results indicated that CO and CH4 emission concentrations were at a low level under all conditions. With the increasing proportion of SMSW, the combustion efficiency decreased slightly, the HCl emission increased obviously at 25% conditions while at lower proportion conditions the change was not significant; the NOx emission concentration showed a tendency to rise first and then decrease, while the SO2 showed an exactly opposite trend; besides, Fe, Cl and S content in the fly ash increased obviously. Under all experimental conditions, only a small amount of heavy metals were emitted in the flue gas while most of the heavy metals were retained in the fly ash. The leaching results showed that Ni leaching concentration was beyond the national standard which means the fly ash needs further treatment before they can be disposed of by landfill, while the HCl, NOx and SO2 emissions can easily reach the national emission standard under the desulfurization and denitrification system operating conditions in real power plants. These findings are helpful for the further development of co-combustion with renewable energy in coal-fired incinerators, yet more investigation on heavy metal emission in fly ash is still required to be further conducted in the future.


Asunto(s)
Contaminantes Atmosféricos/análisis , Ceniza del Carbón/química , Gases/química , Residuos Sólidos/análisis , Administración de Residuos/instrumentación , Calor , Administración de Residuos/métodos
9.
Comput Intell Neurosci ; 2018: 5060857, 2018.
Artículo en Inglés | MEDLINE | ID: mdl-30515197

RESUMEN

This study proposes a multilayer hybrid deep-learning system (MHS) to automatically sort waste disposed of by individuals in the urban public area. This system deploys a high-resolution camera to capture waste image and sensors to detect other useful feature information. The MHS uses a CNN-based algorithm to extract image features and a multilayer perceptrons (MLP) method to consolidate image features and other feature information to classify wastes as recyclable or the others. The MHS is trained and validated against the manually labelled items, achieving overall classification accuracy higher than 90% under two different testing scenarios, which significantly outperforms a reference CNN-based method relying on image-only inputs.


Asunto(s)
Algoritmos , Aprendizaje Profundo , Redes Neurales de la Computación , Reciclaje , Residuos/clasificación , Humanos , Administración de Residuos/instrumentación , Administración de Residuos/métodos
10.
Environ Sci Pollut Res Int ; 25(30): 30191-30198, 2018 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-30155629

RESUMEN

The propagation of antibiotic resistance is a challenge for human health worldwide, which has drawn much attention on the reduction of the resistance genes. To understand their occurrence during different treatment processes, in this study, four classes of antibiotics (tetracyclines, sulfonamides, quinolones, and macrolides), eight antibiotic resistance genes (ARGs) (tetB, tetW, sul1, sul2, gyrA, qepA, ermB, and ermF), and two mobile elements (int1 and int2) were investigated in a typical pharmaceutical plant. The total concentrations of antibiotics were detected in the range of 2.6 × 102 to 2.5 × 103 ng/L in the treatment processes, and the high abundance of ARGs was detected in the biological treatment unit. The dynamic trend analysis showed that antibiotics were partially removed in the anaerobic/aerobic processes, where ARGs were proliferated. The abundance of tetB and gyrA genes was positively correlated with pH and EC (p < 0.05), and the tetW, sul1 and sul2 genes were significantly correlated with TOC, TN, and DO (p < 0.05), indicating the influence of physicochemical properties of the solution on the levels of ARG subtypes. The phylogenetic analysis showed that the tetW clones had high homology with some pathogenic microorganisms, such as Klebsiella pneumonia and Neisseria meningitides, which would threaten human health. Results indicated that the horizontal transfer acted as a major driver in the ARGs evolution.


Asunto(s)
Antibacterianos/farmacología , Bacterias/efectos de los fármacos , Proteínas Bacterianas/genética , Farmacorresistencia Bacteriana , Administración de Residuos/instrumentación , Aguas Residuales/microbiología , Antibacterianos/análisis , Bacterias/clasificación , Bacterias/genética , Bacterias/aislamiento & purificación , Proteínas Bacterianas/metabolismo , Filogenia , Quinolonas/análisis , Quinolonas/farmacología , Sulfonamidas/análisis , Sulfonamidas/farmacología , Tetraciclinas/análisis , Tetraciclinas/farmacología , Aguas Residuales/análisis
11.
Water Res ; 142: 256-266, 2018 10 01.
Artículo en Inglés | MEDLINE | ID: mdl-29890474

RESUMEN

As the main intermediate metabolite in anaerobic digestion of wasted activated sludge (WAS), volatile fatty acids (VFAs) are proper substrate for mixed culture (MC) polyhydroxyalkanoate (PHA) synthesis. To further optimize the performance of MC PHA production process, VFA_odd (i.e., VFA with odd carbon atoms) oriented acidification process was proposed and conducted in this study. Three regulation factors including reaction pH, fraction of added ß-cyclodextrin (ß-CD) and glycerol were selected and response surface methodology (RSM) was used to enhance and effectively regulate the VFA_odd production while maintaining enough acidification degree in the WAS acidification. High percentage of VFA_odd (larger than 60% and dominated by propionic acid) can be obtained in the operating condition area with glycerol addition ratio (quantified by C/N) ranging from 15 to 20 and reaction pH ranging from 8.0 to 9.5 when ß-CD addition was held at zero level (0.2 g/gTSS) according to the RSM. Semi-continuous acidification and MC PHA production assays further verified the reliability and effectiveness of the VFA_odd oriented acidification strategy. Microbial function group related to propionic acid production (Gprop) was defined based on the relationships between system function and microbial community structure, and 13 frequent species were found being involved in the Gprop. Roles of the group members in the oriented acidification were analyzed to understand the mechanisms of the regulation of VFA_odd production at microbial ecological level. A synergistic effect of WAS and glycerol on the VFA_odd production in the acidification process was revealed based on the ecological analysis.


Asunto(s)
Ácidos Grasos Volátiles/metabolismo , Microbiota/fisiología , Polihidroxialcanoatos/metabolismo , Aguas del Alcantarillado/microbiología , Administración de Residuos/métodos , Reactores Biológicos/microbiología , Carbono/química , Ácidos Grasos Volátiles/química , Glicerol/química , Glicerol/metabolismo , Concentración de Iones de Hidrógeno , Reproducibilidad de los Resultados , Aguas del Alcantarillado/química , Administración de Residuos/instrumentación , beta-Ciclodextrinas/química , beta-Ciclodextrinas/metabolismo
12.
Water Res ; 142: 167-175, 2018 10 01.
Artículo en Inglés | MEDLINE | ID: mdl-29870950

RESUMEN

This study demonstrated the removal and recovery of uranium(VI) in a fed-batch stirred tank reactor (STR) using waste digested activated sludge (WDAS). The batch adsorption experiments showed that WDAS can adsorb 200 (±9.0) mg of uranium(VI) per g of WDAS. The maximum adsorption of uranium(VI) was achieved even at an acidic initial pH of 2.7 which increased to a pH of 4.0 in the equilibrium state. Desorption of uranium(VI) from WDAS was successfully demonstrated from the release of more than 95% of uranium(VI) using both acidic (0.5 M HCl) and alkaline (1.0 M Na2CO3) eluents. Due to the fast kinetics of uranium(VI) adsorption onto WDAS, the fed-batch STR was successfully operated at a mixing time of 15 min. Twelve consecutive uranium(VI) adsorption steps with an average adsorption efficiency of 91.5% required only two desorption steps to elute more than 95% of uranium(VI) from WDAS. Uranium(VI) was shown to interact predominantly with the phosphoryl and carboxyl groups of the WDAS, as revealed by in situ infrared spectroscopy and time-resolved laser-induced fluorescence spectroscopy studies. This study provides a proof-of-concept of the use of fed-batch STR process based on WDAS for the removal and recovery of uranium(VI).


Asunto(s)
Uranio/aislamiento & purificación , Administración de Residuos/métodos , Contaminantes Radiactivos del Agua/aislamiento & purificación , Adsorción , Técnicas de Cultivo Celular por Lotes/instrumentación , Reactores Biológicos , Concentración de Iones de Hidrógeno , Cinética , Aguas del Alcantarillado , Espectrometría de Fluorescencia , Espectroscopía Infrarroja por Transformada de Fourier , Administración de Residuos/instrumentación
13.
J Air Waste Manag Assoc ; 68(10): 1118-1125, 2018 10.
Artículo en Inglés | MEDLINE | ID: mdl-29708470

RESUMEN

Excessive accumulation of biomass within gas-phase biofilters often results in the deterioration of removal performance. Compared with chemical and biological technologies, physical technologies are more effective in removing biomass and inducing less inhibition of the biofilter performance. This study applied different physical technologies, namely, air sparging, mechanical mixing, and washing with water at various temperatures, to remove excess biomass in biofilters treating toluene. Filter pressure drop, removed dry biomass, biofilter performance, and microbial metabolic characteristics were analyzed to evaluate the effectiveness of the methods. Results showed that air sparging was inefficient for biomass removal (1 kg dry biomass/m3 filter), whereas mechanical mixing significantly inhibited removal efficiencies (<30%). Washing of the packing with fluids was feasible, and hot fluids can remove a large amount of biomass. However, hot fluids reduce microbial activity and inhibit removal performance. Washing of the packing with either 20°C or 50°C water showed efficiency as >3 kg dry biomass/m3 filter can be removed at both temperatures with removal efficiencies at approximately 40% after treatment. Finally, different technologies were compared and summarized to propose an optimized strategy of biomass control for industrial biofilters. IMPLICATIONS: This study is to apply different physical technologies, namely, air sparging, mechanical mixing, and washing with water of different temperatures, to remove the excess biomass in biofilters treating toluene. The filter pressure drop, removed dry biomass, biofilter performance, and microbial metabolic characteristics were all analyzed to evaluate the effectiveness of the methods. The results of this study provide useful information regarding biomass control of industrial biofilters.


Asunto(s)
Biomasa , Filtración , Tolueno , Administración de Residuos , Contaminación de Equipos , Filtración/instrumentación , Filtración/métodos , Gases , Residuos Industriales , Solventes/análisis , Solventes/química , Tolueno/análisis , Tolueno/química , Administración de Residuos/instrumentación , Administración de Residuos/métodos
14.
Appl Microbiol Biotechnol ; 102(13): 5625-5634, 2018 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-29717342

RESUMEN

A novel gas-scrubbing bioreactor based on a downflow hanging sponge (DHS) reactor was developed as a new volatile organic compound (VOC) treatment system. In this study, the effects of varying the space velocity and gas/liquid ratio were investigated to assess the effectiveness of using toluene gas as a model VOC. Under optimal conditions, the toluene removal rate was greater than 80%, and the maximum elimination capacity was observed at approximately 13 g-C m-3 h-1. The DHS reactor demonstrated slight pressure loss (20 Pa) and a high concentration of suspended solids (up to 30,000 mg/L-sponge). Cloning analysis of the 16S rRNA and functional genes of toluene degradation pathways (tmoA, todC, tbmD, xylA, and bssA) revealed that the clones belonging to the toluene-degrading bacterium Pseudomonas putida constituted the predominant species detected at the bottom of the DHS reactor. The toluene-degrading bacteria Pseudoxanthomonas spadix and Pseudomonas sp. were also detected by tmoA- and todC-targeted cloning analyses, respectively. These results demonstrate the potential for the industrial application of this novel DHS reactor for toluene gas treatment.


Asunto(s)
Reactores Biológicos , Tolueno/metabolismo , Compuestos Orgánicos Volátiles/metabolismo , Administración de Residuos/instrumentación , Administración de Residuos/métodos , Bacterias/genética , Bacterias/metabolismo , Biodegradación Ambiental , ARN Ribosómico 16S , Compuestos Orgánicos Volátiles/química
15.
Environ Sci Pollut Res Int ; 25(22): 21811-21821, 2018 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-29796883

RESUMEN

Anaerobic co-digestion of sewage sludge and glycerol from the biodiesel industry was evaluated in three experimental stages. In the first step, the addition of higher proportions of crude glycerol (5-20% v/v) to the sludge was evaluated, and the results showed a marked decrease in pH and inhibition of methane production. In the second step, co-digestion of sludge with either a lower proportion (1% v/v) of crude glycerol or glycerol pretreated to remove salinity resulted in volatile acid accumulation and low methane production. The accumulation of volatile acids due to the rapid degradation of glycerol in the mixture was more detrimental to methanogenesis than the salinity of the crude glycerol. In the third step, much lower amounts of crude glycerol were added to the sludge (0.3, 0.5, 0.7% v/v), resulting in buffering of the reaction medium and higher methane production than in the control (pure sludge). The best condition for co-digestion was with the addition of 0.5% (v/v) crude glycerol to the sewage sludge, which equals 0.6 g glycerol/g volatile solids applied. Under this condition, the specific methane production (mL CH4/g volatile solids applied) was 1.7 times higher than in the control.


Asunto(s)
Glicerol , Metano/biosíntesis , Aguas del Alcantarillado , Administración de Residuos/métodos , Anaerobiosis , Biocombustibles , Reactores Biológicos , Glicerol/química , Salinidad , Aguas del Alcantarillado/química , Administración de Residuos/instrumentación
16.
J Air Waste Manag Assoc ; 68(10): 1077-1084, 2018 10.
Artículo en Inglés | MEDLINE | ID: mdl-29693499

RESUMEN

Conversion of sewage sludge to activated carbon is attractive as an alternative method to ocean dumping for the disposal of sewage sludge. Injection of activated carbon upstream of particulate matter control devices has been suggested as a method to remove elemental mercury from flue gas. Activated carbon was prepared using various activation temperatures and times and was tested for their mercury adsorption efficiency using lab-scale systems. To understand the effect of the physical property of the activated carbon, its mercury adsorption efficiency was investigated as a function of its Brunauer-Emmett-Teller (BET) surface area. Two simulated flue gas conditions, (1) without hydrogen chloride (HCl) and (2) with 20 ppm HCl, were used to investigate the effect of flue gas composition on the mercury adsorption capacity of activated carbon. Despite very low BET surface area of the prepared sewage sludge activated carbons, their mercury adsorption efficiencies were comparable under both simulated flue gas conditions to those of pinewood and coal activated carbons. After injecting HCl into the simulated flue gas, all sewage sludge activated carbons demonstrated high adsorption efficiencies, that is, more than 87%, regardless of their BET surface area. IMPLICATIONS: We tested activated carbons prepared from dried sewage sludge to investigate the effect of their physical properties on their mercury adsorption efficiency. Using two simulated flue gas conditions, we conducted mercury speciation for the outlet gas. We found that the sewage sludge activated carbon had mercury adsorption efficiency comparable to pinewood and coal activated carbons, and the presence of HCl minimized the effect of physical property of the activated carbon on its mercury adsorption efficiency.


Asunto(s)
Carbono/química , Mercurio , Aguas del Alcantarillado , Hollín , Administración de Residuos , Adsorción , Mercurio/química , Mercurio/aislamiento & purificación , Material Particulado , Aguas del Alcantarillado/análisis , Aguas del Alcantarillado/química , Hollín/análisis , Hollín/química , Administración de Residuos/instrumentación , Administración de Residuos/métodos
17.
Water Res ; 140: 24-33, 2018 09 01.
Artículo en Inglés | MEDLINE | ID: mdl-29684699

RESUMEN

A wide variety of inhibitors can induce anaerobic digester disruption. To avoid performance losses, support media can be used to mitigate inhibitions. However, distinguishing the physico-chemical from the biological mechanisms of such strategies remains delicate. In this framework, the impact of 10  g/L of different types of zeolites and activated carbons (AC) on microbial community dynamics during anaerobic digestion of biowaste in the presence of 1.3 g/L of phenol was evaluated with 16 S rRNA gene sequencing. In the presence of AC, methanogenesis inhibition was rapidly removed due to a decrease of phenol concentration. This abiotic effect related to the physico-chemical properties of AC led to increased final CH4 and CO2 productions by 29-31% compared to digesters incubated without support. Interestingly, although zeolite did not adsorb phenol, final CH4 and CO2 production reached comparable levels as with AC. Nevertheless, compared to digesters incubated without support, methanogenesis lag phase duration was less reduced in the presence of zeolites (5 ±â€¯1 days) than in the presence of activated carbons (12 ±â€¯2 days). Both types of support induced biotic effects. AC and zeolite both allowed the preservation of the major representative archaeal genus of the non-inhibited ecosystem, Methanosarcina. By contrast, they distinctly shaped bacterial populations. OTUs belonging to class W5 became dominant at the expense of OTUs assigned to orders Clostridiales, Bacteroidales and Anaerolinales in the presence of AC. Zeolite enhanced the implantation of OTUs assigned to bacterial phylum Cloacimonetes. This study highlighted that supports can induce biotic and abiotic effects within digesters inhibited with phenol, showing potentialities to enhance anaerobic digestion stability under disrupting conditions.


Asunto(s)
Reactores Biológicos/microbiología , Medios de Cultivo/metabolismo , Metano/biosíntesis , Fenoles/metabolismo , Administración de Residuos/métodos , Anaerobiosis , Archaea/genética , Bacterias/genética , Bacterias/metabolismo , Methanosarcina/genética , Methanosarcina/metabolismo , Consorcios Microbianos/fisiología , Administración de Residuos/instrumentación , Zeolitas/metabolismo
18.
Environ Sci Pollut Res Int ; 25(36): 35981-35989, 2018 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-29558790

RESUMEN

Furanic and phenolic compounds are problematic compounds resulting from the pretreatment of lignocellulosic biomass for biofuel production. Microbial electrolysis cell (MEC) is a promising technology to convert furanic and phenolic compounds to renewable H2. The objective of the research presented here was to elucidate the processes and electron equivalents flow during the conversion of two furanic (furfural, FF; 5-hydroxymethyl furfural, HMF) and three phenolic (syringic acid, SA; vanillic acid, VA; 4-hydroxybenzoic acid, HBA) compounds in the MEC bioanode. Cyclic voltammograms of the bioanode demonstrated that purely electrochemical reactions in the biofilm attached to the electrode were negligible. Instead, microbial reactions related to the biotransformation of the five parent compounds (i.e., fermentation followed by exoelectrogenesis) were the primary processes resulting in the electron equivalents flow in the MEC bioanode. A mass-based framework of substrate utilization and electron flow was developed to quantify the distribution of the electron equivalents among the bioanode processes, including biomass growth for each of the five parent compounds. Using input parameters of anode efficiency and biomass observed yield coefficients, it was estimated that more than 50% of the SA, FF, and HMF electron equivalents were converted to current. In contrast, only 12 and 9% of VA and HBA electron equivalents, respectively, resulted in current production, while 76 and 79% remained as fermentation end products not further utilized in exoelectrogenesis. For all five compounds, it was estimated that 10% of the initially added electron equivalents were used for fermentative biomass synthesis, while 2 to 13% were used for exoelectrogenic biomass synthesis. The proposed mass-based framework provides a foundation for the simulation of bioanode processes to guide the optimization of MECs converting biomass-derived waste streams to renewable H2.


Asunto(s)
Biotecnología/métodos , Electrólisis/métodos , Administración de Residuos/métodos , Biopelículas/crecimiento & desarrollo , Biocombustibles , Biomasa , Electrodos , Electrones , Fermentación , Furaldehído/análogos & derivados , Furaldehído/metabolismo , Ácido Gálico/análogos & derivados , Ácido Gálico/metabolismo , Hidrógeno/metabolismo , Parabenos/metabolismo , Ácido Vanílico/metabolismo , Administración de Residuos/instrumentación
19.
J Air Waste Manag Assoc ; 68(1): 73-91, 2018 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-29120693

RESUMEN

In order to address the bottleneck problem of low fine-particle removal efficiency of self-excited dust scrubbers, this paper is focused on the influence of the intermittent gas-liquid two-phase flow on the mesoscale behavior of collector aggregations. The latter is investigated by the application of high-speed dynamic image technology to the self-excited dust scrubber experimental setup. The real-time-scale monitoring of the dust removal process is provided to clarify its operating mechanism at the mesoscale level. The results obtained show that particulate capturing in self-excited dust scrubber is provided by liquid droplets, liquid films/curtains, bubbles, and their aggregations. Complex spatial and temporal structures are intrinsic to each kind of collector morphology, and these are considered as the major factors controlling the dust removal mechanism of self-excited dust scrubbers. For the specific parameters of gas-liquid two-phase flow under study, the evolution patterns of particular collectors reflect the intrinsic, intermittent, and complex characteristics of the temporal structure. The intermittent initiation of the collector and the air hole formation-collapse cyclic processes provide time and space for the fine dust to escape from being trapped by the collectors. The above mesoscale experimental data provide more insight into the factors reducing the dust removal efficiency of self-excited dust scrubbers. IMPLICATIONS: This paper focuses on the reconsideration of the capturer aggregations of self-excited dust scrubbers from the mesoscale. Complex structures in time and space scales exist in each kind of capturer morphology. With changes of operating parameters, the morphology and spatial distributions of capturers diversely change. The change of the capturer over time presents remarkable, intermittent, and complex characteristics of the temporal structure.


Asunto(s)
Polvo/análisis , Contaminantes Ambientales/análisis , China , Carbón Mineral , Monitoreo del Ambiente , Contaminantes Ambientales/química , Contaminación Ambiental/prevención & control , Tamaño de la Partícula , Administración de Residuos/instrumentación , Administración de Residuos/métodos
20.
Radiat Prot Dosimetry ; 178(3): 254-259, 2018 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-28981719

RESUMEN

Operational measures taken for the repatriation of Alcyon II 60Co Teletherapy head and El Dorado 6 60Co Teletherapy devices located in Yaounde and Douala respectively are reported. Operations carried out have permit to store Alcyon head in the CC 33 container and to transfer 60Co source from El Dorado 6 device to YKT1B container. These containers are approved as Type B package for securely transport. Optically stimulated luminescence dosimeters had been distributed to all involved persons to estimate the received effective dose during operations. It appears by the present study that, the most received individual effective dose is 130 µSv during the whole process.


Asunto(s)
Exposición a Riesgos Ambientales/prevención & control , Exposición Profesional/prevención & control , Monitoreo de Radiación/métodos , Protección Radiológica/métodos , Residuos Radiactivos , Administración de Residuos/métodos , Camerún , Humanos , Dosis de Radiación , Administración de Residuos/instrumentación
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