High-resolution IR studies of hydrogen bonded clusters: large amplitude dynamics in (HCl)n.
Faraday Discuss
; (118): 63-78; discussion 109-19, 2001.
Article
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| MEDLINE
| ID: mdl-11605282
ABSTRACT
Structural and dynamical information on small hydrogen-bonded systems is revealed by high-resolution IR spectroscopy of HCl dimer, trimer and tetramer. In (HCl)2, four combination bands tentatively assigned to the Van der Waals stretch nu 4 and geared band nu 5 vibrations are observed. The study focuses on two unexpected results:
(i) all of the observed bands are built only on the bound HCl stretch nu 2, and (ii) the bands predominantly originate from the 9-fold less populated upper tunneling level of the ground state. Model 3D quantum calculations are presented to show that both these surprising trends originate from the large amplitude tunneling dynamics in the dimer. The (HCl)3 spectra are assigned and analyzed for multiple isotopomeric contributions. The spectral fit reveals large homogeneous line broadening indicating the excited state lifetime of approximately 1.6 ns and tentatively associated with dynamics of intramolecular vibrational energy distribution (IVR) induced trimer ring opening. Finally, first high-resolution data on the HCl stretch fundamental spectrum of (HCl)4 are presented.
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Base de datos:
MEDLINE
Idioma:
En
Revista:
Faraday Discuss
Asunto de la revista:
QUIMICA
Año:
2001
Tipo del documento:
Article