Rationalisation of weak ferromagnetism in manganese(III) chains: the relation between structure and ordering phenomena.
Dalton Trans
; (4): 632-9, 2004 Feb 21.
Article
en En
| MEDLINE
| ID: mdl-15252527
ABSTRACT
The synthesis, structure and magnetic properties of the one-dimensional chain compounds [Mn(cyclam)(SO4)]ClO4.H2O (1) and [Mn(cyclam)(HCOO)](CF3SO3)(ClO4) (2) are reported. Cyclam is the cyclic tetradentate ligand 1,4,7,11-tetraazacyclotetradecane. Both chain compounds exhibit antiferromagnetic interactions within the chains. A magnetic ordering phase transition at 5.5 K in (1) is investigated by magnetisation measurements along the three principal crystallographic axes of a single crystal and the results show unambiguously that the ferromagnetic ordering is only taking place along one crystallographic axis. The spin structure of the magnetic ordered phase and the magnitude of the ferromagnetic moment are correlated with the crystal structure and symmetry of the compound.
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Base de datos:
MEDLINE
Asunto principal:
Compuestos de Manganeso
/
Magnetismo
Idioma:
En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2004
Tipo del documento:
Article