Base-catalyzed Diels-Alder reactions of 2H-pyran-2,5-diones: a mild approach to basiliolide B.
Org Lett
; 10(24): 5525-8, 2008 Dec 18.
Article
en En
| MEDLINE
| ID: mdl-19053740
ABSTRACT
A new class of base-catalyzed Diels-Alder reactions of 2H-pyran-2,5-diones has been developed using catalytic amount of dicyclohexylmethylamine in tert-butyl alcohol. This method has been successfully employed for construction of the tricyclic core of basiliolide B at room temperature with good yields and exclusive endo selectivity.
Texto completo:
1
Base de datos:
MEDLINE
Asunto principal:
Piranos
/
Pironas
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Inhibidores Enzimáticos
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Thapsia
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2008
Tipo del documento:
Article