First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold.

Cetiner, Derya; Jacques, Béatrice; Payet, Elina; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Tranchier, Jean-Philippe; Herson, Patrick

Cetiner, Derya; Jacques, Béatrice; Payet, Elina; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Tranchier, Jean-Philippe; Herson, Patrick.

Afiliación

Cetiner D; UPMC Univ Paris 06, UMR CNRS 7611, Laboratoire de Chimie Organique, Institut de Chimie Moléculaire (FR 2769), Case 181, 4 place Jussieu, F-75252, Paris Cedex 05, France.

Dalton Trans ; (1): 27-9, 2009 Jan 07.

Article en En | MEDLINE | ID: mdl-19081966

ABSTRACT

ABSTRACT

The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.

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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2009 Tipo del documento: Article

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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2009 Tipo del documento: Article