Strictly non-adiabatic quantum control of the acetylene dication using an infrared field.
J Chem Phys
; 152(18): 184302, 2020 May 14.
Article
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| MEDLINE
| ID: mdl-32414271
ABSTRACT
We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a time dependent Schrödinger equation simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.
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J Chem Phys
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2020
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Article