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Copper(i)-catalyzed intermolecular cyanoarylation of alkenes: convenient access to α-alkylated arylacetonitriles.
Chen, Xin-Jie; Gui, Qing-Wen; Yi, Rongnan; Yu, Xianyong; Wu, Zhi-Lin; Huang, Ying; Cao, Zhong; He, Wei-Min.
Afiliación
  • Chen XJ; Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China. 512098818@qq.com.
  • Gui QW; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China. weiminhe2016@yeah.net.
  • Yi R; Department of Chemistry, Hunan University, Changsha 410082, China.
  • Yu X; Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China. 512098818@qq.com.
  • Wu ZL; School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China.
  • Huang Y; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China. weiminhe2016@yeah.net.
  • Cao Z; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China. weiminhe2016@yeah.net.
  • He WM; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, 410114, China. weiminhe2016@yeah.net.
Org Biomol Chem ; 18(27): 5234-5237, 2020 07 15.
Article en En | MEDLINE | ID: mdl-32602499
ABSTRACT
A novel Cu(i)-catalyzed intermolecular cyanoarylation of alkenes with diaryliodonium salts as a radical arylating reagent and tetra-butylammonium cyanide as an electrophilic cyanating reagent was established. A broad range of α-alkylated arylacetonitriles were efficiently constructed in good to excellent yields under base- and oxidant-free and mild conditions.
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2020 Tipo del documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2020 Tipo del documento: Article