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Solvent-Induced Reversible Spin-Crossover in a 3D Hofmann-Type Coordination Polymer and Unusual Enhancement of the Lattice Cooperativity at the Desolvated State.
Mondal, Dibya Jyoti; Roy, Subhadip; Yadav, Jyoti; Zeller, Matthias; Konar, Sanjit.
Afiliación
  • Mondal DJ; Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal Bypass Road, Bhauri, Bhopal 462066, India.
  • Roy S; Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal Bypass Road, Bhauri, Bhopal 462066, India.
  • Yadav J; Department of Chemistry, The ICFAI University Tripura, Kamalghat, Mohanpur, Agartala, Tripura 799210, India.
  • Zeller M; Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Bhopal Bypass Road, Bhauri, Bhopal 462066, India.
  • Konar S; Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.
Inorg Chem ; 59(18): 13024-13028, 2020 Sep 21.
Article en En | MEDLINE | ID: mdl-32865405
ABSTRACT
The new 3D Hofmann-type coordination polymer [Fe(dpyu){Pt(CN)4}]·9H2O [dpyu = 1,3-di(pyridin-4-yl)urea] exhibits reversible interchange between two- and one-step spin-crossover behavior, associated with desorption/resorption of lattice water molecules. Solvent water removal also induces an increase of the spin-transition temperature, indicating strong lattice cooperativity, observed for the first time in a 3D Hofmann-type coordination polymer.
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2020 Tipo del documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2020 Tipo del documento: Article