Cascade aryne insertion/vinylogous aldol reaction of vinyl-substituted ß-keto/enol carbonyls.
Chem Commun (Camb)
; 58(19): 3178-3181, 2022 Mar 03.
Article
en En
| MEDLINE
| ID: mdl-35171160
ABSTRACT
Cyclic and acyclic vinyl substituted ß-keto/enol carbonyl substrates, on reaction with arynes, result in differentially substituted naphthyl carbocycles, hitherto difficult to synthesize with existing protocols. While the substitutions on the arynes have no role, the ring size of the cyclic ß-keto/enol esters has a profound influence on the product formation.
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Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2022
Tipo del documento:
Article