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Reversible P-P bond cleavage at an iridium(III) metal centre.
Coles, Simon J; Horton, Peter N; Kimber, Patrick; Klooster, Wim T; Liu, Pingchuan; Plasser, Felix; Smith, Martin B; Tizzard, Graham J.
Afiliación
  • Coles SJ; UK National Crystallography Service, School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
  • Horton PN; UK National Crystallography Service, School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
  • Kimber P; Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU, UK. m.b.smith@lboro.ac.uk.
  • Klooster WT; UK National Crystallography Service, School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
  • Liu P; Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU, UK. m.b.smith@lboro.ac.uk.
  • Plasser F; Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU, UK. m.b.smith@lboro.ac.uk.
  • Smith MB; Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU, UK. m.b.smith@lboro.ac.uk.
  • Tizzard GJ; UK National Crystallography Service, School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
Chem Commun (Camb) ; 58(37): 5598-5601, 2022 May 05.
Article en En | MEDLINE | ID: mdl-35437547
ABSTRACT
Treatment of a κ1-P-monodentate bicyclic diphosphane iridium(III) complex with a labile gold(I) precursor afforded an unusual IrIII/AuI complex in which the P-P single bond has been cleaved. This reaction was cleanly reversed upon addition of tertiary phosphine. Carbon-carbon bond activation, across neighbouring P2C2N rings of the coordinated bicyclic diphosphane, occurred upon thermolysis of the IrIII/AuI complex.
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article