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A dendrite-free and anticaustic Zn anode enabled by high current-induced reconstruction of the electrical double layer.
Cui, Yang-Feng; Cao, Ren-Fei; Du, Jia-Yi; Zhuang, Zhen-Bang; Xie, Zi-Long; Wang, Qing-Shuang; Bao, Di; Liu, Wan-Qiang; Zhu, Yun-Hai; Huang, Gang.
Afiliación
  • Cui YF; School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China. wqliu1979@126.com.
  • Cao RF; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Du JY; School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China. wqliu1979@126.com.
  • Zhuang ZB; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Xie ZL; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Wang QS; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Bao D; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Liu WQ; Research Center for Nanotechnology, Changchun University of Science and Technology, Changchun 130022, China.
  • Zhu YH; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China. ghuang@ciac.ac.cn.
  • Huang G; School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China. wqliu1979@126.com.
Chem Commun (Camb) ; 59(17): 2437-2440, 2023 Feb 23.
Article en En | MEDLINE | ID: mdl-36723296
ABSTRACT
Aqueous Zn-based batteries deliver thousands of cycles at high rates but poor recyclability at low rates. Herein, we reveal that this illogical phenomenon is attributed to the reconstructed electrode/electrolyte interface at high rates, wherein the condensed electrical double layer (EDL) and the tightly absorbed Zn2+ ions on the Zn electrode surface afford compact and corrosion-resistant Zn deposits.
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article