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Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion.
de Azevedo Santos, Lucas; van der Voort, Storm; Burema, Shiri R; Fonseca Guerra, Célia; Bickelhaupt, F Matthias.
Afiliación
  • de Azevedo Santos L; Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.
  • van der Voort S; Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.
  • Burema SR; Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.
  • Fonseca Guerra C; Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.
  • Bickelhaupt FM; Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.
Chemphyschem ; 25(1): e202300918, 2024 Jan 02.
Article en En | MEDLINE | ID: mdl-38169096
ABSTRACT
The front cover artwork is provided by the TheoCheM group at the Vrije Universiteit Amsterdam. The image shows how, in X- •••H3 C-Y complexes, the Lewis base X- tetrel-binds to the central C while sterically pushing the H atoms towards C; hence, the compression and blueshift of the H-C bonds. Read the full text of the Research Article at 10.1002/cphc.202300480.
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: ChemPhysChem (Internet) / Chemphyschem Asunto de la revista: BIOFISICA / QUIMICA Año: 2024 Tipo del documento: Article
Texto completo
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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: ChemPhysChem (Internet) / Chemphyschem Asunto de la revista: BIOFISICA / QUIMICA Año: 2024 Tipo del documento: Article