Your browser doesn't support javascript.
loading
Alcohol synthesis based on the SN2 reactions of alkyl halides with the squarate dianion.
Sato, Kazuto; Fujita, Tomoyuki; Takeuchi, Takashi; Suzuki, Takahiro; Ikeuchi, Kazutada; Tanino, Keiji.
Afiliación
  • Sato K; Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan.
  • Fujita T; Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan.
  • Takeuchi T; Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan.
  • Suzuki T; Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. ktanino@sci.hokudai.ac.jp.
  • Ikeuchi K; Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. ktanino@sci.hokudai.ac.jp.
  • Tanino K; Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. ktanino@sci.hokudai.ac.jp.
Org Biomol Chem ; 22(7): 1369-1373, 2024 Feb 14.
Article en En | MEDLINE | ID: mdl-38232248
ABSTRACT
A convenient method has been developed for transforming alkyl halides into the corresponding alcohols via an SN2 reaction. Treatment of an alkyl halide with the squarate dianion at high temperature produces mono-alkyl squarate, and a one-pot basic hydrolysis of the intermediate affords the alcohol in good yield.
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2024 Tipo del documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2024 Tipo del documento: Article