A Sustainable and Regenerative Process for the Treatment of Textile Effluents Using Nonphotocatalytic Water Splitting by Nanoporous Oxygen-Deficient Ferrite.

ABSTRACT

Water is crucial for life. Being the world's third-largest industry, the textile industry pollutes 93 billion cubic meters of water each year. Only 28% of textile wastewater is treated by lower- to middle-income countries due to the costly treatment methods. The present work demonstrates the utilization of surface oxygen defects and nanopores in Mg0.8Li0.2Fe2O4 (Li-MgF) to treat textile effluents by a highly economical, scalable, and eco-friendly process. Nanoporous, oxygen-deficient Li-MgF splits water by a nonphotocatalytic process at room temperature to produce green electricity as hydroelectric cell. The adsorbent Li-MgF can be easily regenerated by heat treatment. A 70-90% reduction in the UV absorption intensity of adsorbent-treated textile effluents was observed by UV-visible spectroscopy. The oxygen defects on Li-MgF surface and nanopores were confirmed by X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller (BET) measurements, respectively. To analyze the adsorption mechanism, three known organic water-soluble dyes, brilliant green, crystal violet, and congo red, were treated with nanoporous Li-MgF. The dye decolorization efficiency of Li-MgF was recorded to be 99.84, 99.27, and 99.31% at 250 µM concentrations of brilliant green, congo red, and crystal violet, respectively. The results of Fourier transform infrared (FTIR) spectroscopy confirmed the presence of dyes on the material surface attached through hydroxyl groups generated by water splitting on the surface of the material. Total organic carbon analysis confirmed the removal of organic carbon from the dye solutions by 82.8, 77.0, and 46.5% for brilliant green, Congo red, and crystal violet, respectively. Based on the kinetic and isotherm models, the presence of a large number of surface hydroxyl groups on the surface of the material and OH- ions in solutions generated by water splitting was found to be responsible for the complete decolorization of all of the dyes. Adsorption of chemically diverse dyes by the nanoporous, eco-friendly, ferromagnetic, economic, and reusable Li-MgF provides a sustainable and easy way to treat textile industry effluents in large amounts.