Ready-to-Use Free-Standing Super-Powder Made with Complex Nanoparticles for SERS.

ABSTRACT

This study presents a straightforward and efficient synthetic approach for producing high-yield, ready-to-use, free-standing super-powder. The synthesis protocol demonstrates versatility, enabling the creation of assemblies from various nanoparticle morphologies and compositions without the need for specific substrates. Au nanorings are employed as building blocks for fabricating the super-powder, which can be used in surface-enhanced Raman spectroscopy (SERS). The distinctive aspect ratio of the ring nanoframes allows the formation of densely packed columnar assemblies on the substrate, aligning the exposed gaps perpendicular to the laser beam. This arrangement significantly enhances the charge separation among nanorings, leading to a highly focused near-field that is applicable to SERS analysis. The SERS detection feasibility of this powder in both pre- and post-contamination conditions is demonstrated. Using a wide range of building blocks, encompassing various shapes (for instance, rods, hexagons, cubes, cuboctahedrons, elongated dodecahedrons, triangular rings, double-rings, elongated dodecahedra frames, cuboctahedra frames, and double-walled frames), the generalizability of the process for synthesizing super-powders with diverse morphologies is substantiated.