Photo- and Cu-Mediated 11C Cyanation of (Hetero)Aryl Thianthrenium Salts.
Org Lett
; 26(16): 3419-3423, 2024 Apr 26.
Article
en En
| MEDLINE
| ID: mdl-38630573
ABSTRACT
We present a photo- and Cu-mediated 11C cyanation of bench-stable (hetero)aryl thianthrenium salts via an aryl radical addition pathway. The thianthrenium substrates can be readily accessed via C-H functionalization, and the radiocyanation protocol proceeds under mild conditions (<50 °C, 5 min) and can be automated using open-source, readily accessible augmentations to existing radiochemistry equipment.
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MEDLINE
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En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2024
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Article