Intercalating a potassium-aqua complex cation into an &#945;-MoO<sub>3</sub> layer without reducing molybdenum: a potential storage system.

Jana, Debu; Mishra, Shalini Sanjay; Das, Samar K

Intercalating a potassium-aqua complex cation into an α-MoO₃ layer without reducing molybdenum: a potential storage system.

Jana, Debu; Mishra, Shalini Sanjay; Das, Samar K.

Afiliación

Jana D; School of Chemistry, University of Hyderabad, P.O. Central University, Hyderabad - 500046, India. skdas@uohyd.ac.in.
Mishra SS; School of Chemistry, University of Hyderabad, P.O. Central University, Hyderabad - 500046, India. skdas@uohyd.ac.in.
Das SK; School of Chemistry, University of Hyderabad, P.O. Central University, Hyderabad - 500046, India. skdas@uohyd.ac.in.

Chem Commun (Camb) ; 60(41): 5439-5442, 2024 May 16.

Article en En | MEDLINE | ID: mdl-38686497

ABSTRACT

ABSTRACT

We have demonstrated a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)]·H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]·2H2O (1) by {K(H2O)4}+ in an aqueous solution of 1 and KCl. Compound 2 acts as a potential storage system of alkali metal ions.

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Texto completo: 1 Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article

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