Electrochemical ring-opening carboxylation of cyclic carbonate with carbon dioxide.
Chem Commun (Camb)
; 60(44): 5735-5738, 2024 May 28.
Article
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| MEDLINE
| ID: mdl-38742637
ABSTRACT
Electroreductive ring-opening carboxylation of styrene carbonates with CO2 to achieve dicarboxylic acids and/or ß-hydroxy acids has been developed via the selective cleavage of the C(sp3)-O bond in cyclic carbonates. The product selectivity is probably determined by the stability and reactivity of the key benzylic radical and carbanion intermediate.
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1
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
/
Chem. commun. (Lond., 1996, Online)
/
Chemical communications (London. 1996. Online)
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article