Norcorroles as antiaromatic π-electronic systems that form dimension-controlled assemblies.
Chem Sci
; 15(20): 7603-7609, 2024 May 22.
Article
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| MEDLINE
| ID: mdl-38784757
ABSTRACT
Norcorrole derivatives with 3,4,5-trialkoxyphenyl moieties at the meso positions were synthesized to form various stacking assemblies in single crystals and thermotropic liquid crystals (LCs) depending on aliphatic chain lengths. Triple-decker stacking structures were formed via the interactions between the antiaromatic systems formed for the butoxy and dodecyloxy derivatives in the single-crystal and LC states, respectively. In particular, the LC state exhibited discotic columnar structures comprising triple deckers to exhibit high electric conductivity, as supported by molecular dynamics simulations.
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Chem Sci
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2024
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Article