Appropriate flame-spraying treatment exacerbates thermal oxidative degradation of residual polyethylene films.

ABSTRACT

In dryland farming, plastic film mulching can significantly increase crop yields, but the resulting residues impair soil health. Heretofore, only few studies had examined how heat treatment facilitates the rapid degradation of polyethylene (PE) residual films. Herein, we characterized the variations in micro-morphology, functional groups, and crystallinity of PE residual films after moderate heat exposure using a self-made flame-spraying equipment. The results revealed that solid residues (SR) obtained from flame-spraying showed a gravimetric weight loss of 9.39 %-15.35 % compared with untreated PE residual films (UPF). Scanning electron microscope equipped with energy dispersive X-ray spectroscopy revealed considerable pits, cracks, and visible roughness in appearance and an increase in the oxygen-to-carbon (O/C) atomic ratio. Fourier-transform infrared spectroscopy identified characteristic oxygen-containing functional groups and double bonds. X-ray diffraction showed that flame-spraying treatments did not alter the crystal form of polymer, but increased the crystallinity. Higher flame-spraying temperatures resulted in larger oxygen-containing bond indices and lower crystallinity, suggesting a more severe decomposition of PE residual film. The possible volatile gaseous products at different reaction temperatures were predicted using thermogravimetric analysis coupled with Fourier transform infrared spectroscopy (TG-FTIR). Degradation of the PE residual film started at 220 °C, and concentrated release of major products such as long-chain aliphatic hydrocarbons, ketones, and CO2, occurred in the temperature range of 340 °C-440 °C. These results highlighted the effectiveness of the moderate flame-spraying method in accelerating rapid decomposition of residual films, and a flame-spraying temperature range of 220 °C-340 °C should be recommended to avoid potential environmental risks induced by the release of large quantities of degradation products. This study will contribute to enhance our understanding of the thermal oxidative degradation behavior of PE waste and provide a scientific basis for the rapid and clean establishment of PE residual films mitigation in agricultural fields.