Microstructure evolution and catalytic activity of AlCo1-xFeNiTiMox high entropy alloys fabricated by powder metallurgy route.

ABSTRACT

This investigation presents the synthesis of equiatomic and non-equiatomic AlCo1-xFeNiTiMox (x = 0, 0.1, 0.25 and 1.0) high entropy alloys fabricated by mechanical alloying. Mo partially replaced Co. Classic thermodynamic calculations, such as mixing enthalpy (ΔHmix), configurational entropy (ΔSmix), the atomic size difference (δ), entropy to enthalpy ratio (Ω), electronegativity difference (△χ), and valence electron concentration (VEC) were used. Considering δ, Ω and VEC parameters, a BCC solid solution and an intermetallic phase can be predicted due to the partial replacement of Co by Mo. X-ray and electron diffraction of equiatomic HEA without Mo content revealed that after 35 h of milling, a Fe-type BCC lattice phase was formed in the alloy and two L21 phases, in addition to a minimal amount of FCC phase. As the Mo content increased, the Fe-type BCC phase was steadily replaced by the Mo-type BCC phase and the Fe-type FCC phase, and two L21 phases were also developed. When the 5 at% Mo-containing (x = 0.25) alloy was further milled for 80 h, the amount of phases remained almost the same; only the grain size was strongly reduced. The influence of the Mo addition on the properties of studied alloys was also confirmed in the decolourisation of Rhodamine B using a modified photo-Fenton process. The decolourisation efficiency within 20 min was 72% for AlCoFeNiTi and 87% for AlCo0.75FeNiTiMo0.25 using UV light with 365 nm wavelength.