A nanocellulose-based flexible multilayer sensor with high sensitivity to humidity and strain response for detecting human motion and respiration.

Biomass-based flexible sensors with excellent mechanical and sensing properties have attracted significant attention. In this study, based on the excellent dispersibility and degradability of nanocellulose crystals, we designed a polyvinyl alcohol/nanocellulose crystals/phytic acid (PCP) composite film with good flexibility and high sensitivity to humidity. A layer of multiwalled carbon nanotubes (MWCNT) and nanocellulose crystals (CNC) was further sandwiched between two PCP layers as a flexible multifunctional sensor (PCPW) to detect human movement and respiration. Phytic acid contains abundant phosphate groups that enhance proton conduction, allowing the PCPW composite film to change its electrical resistance in a sensitive and repeatable manner when the relative humidity was varied between 35 %-93 %. Meanwhile, CNC derived from sisal fibers enhanced the PCPW sensor's conductivity (3.3 S/m) and mechanical properties (elongation at break: 99 %) by improving the dispersion and connectivity of MWCNT. The PCPW sensor displayed a high sensitivity to strain (gauge factor: 49.5) and could monitor both facial expressions (smiling and winking) and the bending of joints. The sensor also generated stable electrical responses during breathing and blowing due to the change in humidity. Therefore, this biodegradable and multifunctional sensor has good application prospects.

Biodegradable ion-conductive polyvinyl alcohol/okra polysaccharide composite films for fast-response respiratory monitoring sensors.

Polyvinyl alcohol (PVA) and okra polysaccharide (OP) are biodegradable polymers with high hydrophilicity and good biocompatibility with potential for use as flexible humidity-sensitive materials. Herein, biodegradable flexible composite films (named POP films) were prepared from PVA, OP, and phytic acid using a solution-casting method based on. POP films exhibited excellent mechanical strength, flexibility, flame retardancy, water resistance, humidity response, and humidity-sensing characteristics. Notably, the POP humidity sensors exhibited a hysteresis value of 1.88 % relative humidity for the adsorption and desorption processes and good sensitivity over a wide humidity range of 35-95 %. In addition, the humidity sensor distinguished the frequency of nose breathing, and its response and recovery times were 0.9 and 1.98 s, respectively. The excellent performance of POP sensors in monitoring humidity and human respiratory rates demonstrates the sensor's potential for wearable smart devices.

Highly stretchable, self-healing, and degradable ionic conductive cellulose hydrogel for human motion monitoring.

Self-healing biomass-based conductive hydrogels are applied as flexible strain sensors for wearable devices and human movement monitoring. Cellulose is the most abundant biomass-based materials and exhibits excellent toughness, dispersion and degradability. In this paper, nanocellulose crystals (NCCs) prepared from sisal, used as reinforcing fillers were coated with tannic acid (TA) to prepare inexpensive bio-nanocomposite hydrogels that also included polyvinyl alcohol, okra polysaccharide (OP), and borax. These hydrogels exhibit excellent self-healing and mechanical properties with the maximum elongation, toughness, and self-healing efficiency (9 min) of 1426.2 %, 264.4 kJ/m3, and 62.1 %, respectively. A fabricated hydrogel strain sensor was successfully used to detect and monitor various human movements such as wrist bending, elbow bending, and slight changes in facial expression. In addition, this sensor possessed excellent durability and good working stability after repeated circulation. The nanocomposite hydrogel synthesized in this work utilized natural polysaccharide to manufacture flexible functional materials with good application prospects in the field of flexible sensors.

Interfacial reaction of intermetallic compounds of ultrasonic-assisted brazed joints between dissimilar alloys of Ti6Al4V and Al4Cu1Mg.

Ultrasonic-assisted brazing of Al4Cu1Mg and Ti6Al4V using Zn-based filler metal (without and with Si) has been investigated. Before brazing, the Ti6Al4V samples were pre-treated by hot-dip aluminizing and ultrasonic dipping in a molten filler metal bath in order to control the formation of intermetallic compounds between the Ti6Al4V samples and the filler metal. The results show that the TiAl(3) phase was formed in the interface between the Ti6Al4V substrate and the aluminized coating. For the Zn-based filler metal without Si, the Ti6Al4V interfacial area of the brazed joint did not change under the effect of the ultrasonic wave, and only consisted of the TiAl(3) phase. For the Zn-based filler metal with Si, the TiAl(3) phase disappeared and a Ti(7)Al(5)Si(12) phase was formed at the interfacial area of the brazed joints under the effect of the ultrasonic wave. Due to the TiAl(3) phase completely changing to a Ti(7)Al(5)Si(12) phase, the morphology of the intermetallic compounds changed from a block-like shape into a lamellar-like structure. The highest shear strength of 138MPa was obtained from the brazed joint free of the block-like TiAl(3) phase.