Gasification characteristics and synergistic effects of typical organic solid wastes under CO2/steam atmospheres.

Gasification technology is an effective way to achieve efficient, safe, and resourceful disposal of organic solid wastes (OSWs). Due to the complex sources and variable components of the OSWs, the co-disposal is highly essential. Various typical OSWs, including food waste (cooked rice, CR), agricultural waste (rice husk, RH; sugarcane bagasse, SB), and industrial waste (furfural residue, FR), were selected for this study. The gasification characteristics and synergistic performance were examined in terms of thermal weight loss characteristics under the CO2 atmosphere and gaseous product characteristics under the steam atmosphere. The synergistic indices of performance parameters were introduced to quantify the synergistic effects. The gasification activity of FR was remarkably higher than that of other OSWs. In the co-gasification with CR under the CO2 atmosphere, FR played an excellent positive synergistic effect, but the agricultural wastes played a slight or no synergistic effect. In the steam co-gasification, RH, SB, and FR all promoted the generation of syngas, in which FR showed still significant synergistic effects, with the synergistic indices of H2 yield, syngas yield, CCE, and CGE being 4-12 times higher than those of other blended wastes. The excellent performance of FR in (co-)gasification was mainly attributed to the acidic properties of FR, which was confirmed by comparing the (co-)gasification performance of FR with and without water-washing pretreatment. The work provides guidance for the co-disposal of OSWs in industrial applications.

In-situ pyrolysis kinetic analysis and fixed-bed pyrolysis behavior of ex-service wind turbine blades.

After the peak of rapid wind power development, a large amount of wind turbine blades reach/exceed their service life due to aging or damage. These ex-service wind turbine blades (EWTB) will increase the issue of its high-efficient utilization in the future decades. Among several treatment methods, pyrolysis has been considered as a promising solution to separate inorganic fiberglass and make organic epoxy resin (OER) high-value-added converted. However, the pyrolysis mechanism, chemical composition, and fiberglass separation of EWTB have not been deeply studied. In this paper, the synthetic model compound of epoxy resin was firstly used to investigate the thermal weight loss and pyrolysis kinetics, the thermal weight loss temperature range of which was 300 âˆ¼ 480 °C. The apparent activation energy was minimum when the conversion rate was 0.6, and the pyrolysis mechanism was determined by the Coats-Redfern method as a diffusion control. On this basis, a lab-scale fixed-bed was conducted to study fast-heating pyrolysis characteristics of EWTB. It could be analyzed that the chemicals in the pyrolytic liquid were a series of phenolics with methyl and vinyl substituted benzene rings (e.g., bisphenol A, p-isopropenyl phenol, and phenol). Bisphenol A presented a relatively high selectivity of 51.02%, which could be recycled as the main raw material for the synthesis of epoxy resins. Furthermore, clean fiberglass could be separated by combusting the residual carbon in pyrolytic solids. These results might be useful for achieving the separation and resource utilization of organic and inorganic components of EWTB.