RESUMEN
NCF/GO hybrid nanofillers with excellent UV-shielding properties were prepared by using TEMPO-oxidized nanocellulose fibrils (NCF) and graphene oxide (GO) as raw materials; different mass ratios of NCF to GO (2: 1, 4: 1, 8: 1, and 16: 1) were used. The NCF and GO were then combined and used as a hybrid filler to study the synergistic effects on polyvinyl alcohol (PVA) nanocomposites. With 5% hybrid nanofiller, the UV-shielding performance of the PVA/NCF/GO composite film was higher than 90%. The tensile strength and Young's modulus of the PVA/CG-2 composite film increased by 74.5% and 278.0%, respectively, and the water absorption decreased by 59%. Moreover, the thermal stabilities of the nanocomposites also improved. This synergistic effect improved the performance of the hybrid nanofiller by avoiding the agglomeration of nanofillers in the polymer matrix and improving the homogeneity of the dispersion. The synergistic effect between the fillers provides a new idea for the preparation of novel multifunctional nanocomposites.