Catalytic mechanism of N-containing biochar on volatile-biochar interaction for the same origin pyrolysis.

Nitrogen, as a common element, is widely present in biomass. The effects of nitrogenous substances on the same origin pyrolysis of biomass and the consequences of N-containing biochar on the catalytic process of volatiles are important for further analyzing the pyrolysis mechanism of biomass. In this research, N-containing biochar was prepared under different conditions, and the interaction between N-containing biochar and biomass pyrolysis volatiles at 400-700 °C was studied. The results show that N-containing biochar can simultaneously participate in reactions as adsorbents, catalysts, and reactants. Its catalytic effect is obviously different for various N configurations. Pyridinic N and pyrrolic N can promote the cracking of lignin into methoxy phenol compounds and promote the further cracking of 5-hydroxymethylfurfural. Graphitic N and oxidized N can promote the further decomposition of phenol and the conversion of D-xylose into small-molecule ketones. In addition, oxidized N can also inhibit the cracking of lignin to produce guaiacol. In the long-term interaction, the highly active pyridinic N tends to convert to a more stable graphitic N.

Optimizing biochar addition strategies in combined processes: Comprehensive assessment of earthworm growth, lignocellulose degradation and vermicompost quality.

The sustainable management of agricultural waste is essential for curtailing environmental contamination. To address the shortcomings of single treatment methods, this study evaluated the feasibility of combining membrane-covered composting (MC) with vermicomposting. Based on this, the integrated effects of different biochar addition strategies on the combined process were investigated. The aim was to improve the efficiency of vermicomposting while eliminating the negative effects of biochar on earthworms. Addition of biochar before membrane-covered composting increased total earthworm biomass by 25.6 - 31.4 % and reproduction rate by 13.4 - 23.9 %. Specifically, the electrical conductivity (EC) (1061.0 - 1112.0 uS/cm) of the vermicompost was significantly reduced, while the total nutrient content (42.3 - 42.6 mg/g) and germination index (GI) (103.9 - 108.4 %) were maximized. Additionally, reductions in the carbon-to-nitrogen ratio and volatile content were observed. Overall, combination process is a promising approach to improve the quality of vermicomposting. The study's results offer a novel perspective on the value-added treatment of agricultural waste.

Biorefining waste into nanobiotechnologies can revolutionize sustainable agriculture.

Modern agriculture has evolved technological innovations to sustain crop productivity. Recent advances in biorefinery technology use crop residue as feedstock, but this raises carbon sequestration concerns as biorefining utilizes carbon that would otherwise be returned to the soil, thus causing a decline in crop productivity. Furthermore, biorefining generates abundant lignin waste that significantly impedes the efficiency of biorefineries. Valorizing lignin into advanced nanobiotechnologies for agriculture provides a unique opportunity to balance bioeconomy and soil carbon sequestration. Integration of agricultural practices such as utilization of agrochemicals, fertilizers, soil modifiers, and mulching with lignin nanobiotechnologies promotes crop productivity and also enables advanced manufacturing of high-value bioproducts from lignin. Lignin nanobiotechnologies thus represent state-of-the-art innovations to transform both the bioeconomy and sustainable agriculture.

Effects of different fermentation assisted enzyme treatments on the composition, microstructure and physicochemical properties of wheat straw used as a substitute for peat in nursery substrates.

To solve the central problems caused by traditional composting treatments, such as long-time consumption and poor regulation effects, this study used three fermentation methods and four enzymes to develop rapid and directional regulation methods to convert wheat straw into a suitable substrate. The results showed that the mixed anaerobic method led to better pH (4.39-5.75) and EC values (1.27-1.89 mS/cm) in the straw substrates, while the aerobic method retained more nutrients and increased lignin and cellulose contents by 5.07-8.04% and 1.52-3.32%. The cellulase mixed with hemicellulase or laccase treatments all increased the crystallinity by 0.45-7.23%. The TG/DTG results showed that all treatments decreased the initial straw glass transition temperature, particularly when using the mixed anaerobic method, with decreases of 10.63-25.48 °C. Overall, mixed anaerobic fermentation and multiple enzymes, including cellulase, have been suggested as alternative biological modification methods for straw substrates.

Influence of the structure and properties of lignocellulose on the physicochemical characteristics of lignocellulose-based residues used as an environmentally friendly substrate.

The extensive use of nonrenewable peat does not meet the strategic goals of sustainable development. This study explores the advantages and disadvantages of using lignocellulose-based agricultural and forestry wastes as peat substitute in substrates for soilless cultivation; further, it also investigates the key factors influencing the physical and chemical properties of the substrates. Accordingly, the physical and chemical properties of four gramineous crop straws and two woody forestry wastes were determined and compared with those of peat and coconut bran. In addition, cellulose, hemicellulose, and lignin were extracted from wheat straw and pine sawdust, and their basic characteristics and structures were compared and analyzed. The results showed that the influence of particle size on the physical properties of substrates was significantly higher (P < 0.01) than the influence of the substrate type, especially with respect to the water-holding and aeration porosities, which had effect sizes (Eta2) of 73.8% and 68.2%, respectively. The electrical conductivity values of the four straws (1.87-3.42 mS/cm) were higher than those of peat and coconut bran (0.50-0.96 mS/cm), which was mainly due to the high hemicellulose contents (28.52%-30.10%) and total nutrient contents (28.46-47.81 g/kg) of the straws. In contrast, the electrical conductivity values of the woody waste substrates were lower (0.28-0.33 mS/cm) than those of peat and coconut bran. Peat and coconut bran contained the lowest cellulose (17.84%-20.95%) and hemicellulose contents (5.14%-7.19%) of all substrates, resulting in a low degradability and good stability. The crystallinity of coconut bran (23.06%) was significantly lower than that of all other substrates (30.36%-43.03%), which mainly contributed to the superior compressibility of coconut bran. The best pretreatment method for biomass waste used as a substrate should be selected according to the target properties of the corresponding components.