Bi-functional super-hydrophilic/underwater super-oleophobic 2D lamellar Ti3C2Tx MXene/poly (arylene ether nitrile) fibrous composite membrane for the fast purification of emulsified oil and photodegradation of hazardous organics.

Developing the multi-functional membranes including oil/water emulsion separation and removal of hazardous organic pollutants is essential to the purification of the complicated wastewater. However, it remains a daunting challenge to combine these intended functions while maintaining high separation efficiency. Herein, we developed a new 2D lamellar MXene/poly (arylene ether nitrile) (PEN) fibrous composite membrane through the self-assembly of TiO2 nanoparticles intercalated MXene nanosheets onto the porous PEN nanofibrous mats and bioinspired polydopamine triggered chemical-crosslinking with polyethyleneimine (PEI). Such nano-intercalation and mussel-inspired crosslinking could effectively regulate the interlayer spacing of the MXene nanosheet skin layer and surface wettability of the composite membrane, which also further contributed to the fast separation and unique bifunctional feature. It was found that the MXene@TiO2/PEN fibrous composite membrane exhibited low oil-adhesion and superhydrophilic (WCA = 0°)/underwater superoleophobic (UOCA > 155°) properties, which could efficiently separate various surfactant-stabilized oil-in-water emulsions under low pressure of 0.04 MPa while keeping good stability (Under 1 M HCl and 2 M NaOH solutions) and recyclability. Interestingly, the fibrous composite membrane achieved favorable permeation flux of 908-1003 Lm-2h-1 (2270-2507.5 Lm-2h-1bar-1) in comparison to other reported MXene based multifunctional composite membranes. Moreover, owing to the synergistic effect of MXene nanosheets and TiO2 nanoparticles, the MXene@TiO2/PEN membrane showed excellent photocatalytic degradation performance for various dyes under visible light, i.e. the photocatalytic degradation efficiency for 15 ppm MB, MO, CV, and MeB solutions achieved 92.31%, 93.50%, 98.06%, and 99.30% within 60 min, respectively. Such 2D MXene bio-functional composite membranes with outstanding oil/water emulsions separation and photocatalytic degradation of dyes pave an avenue for treating complicated oily wastewater.

Controllable preparation of monodisperse alginate microcapsules with oil cores.

Here we report a novel strategy for controllable preparation monodisperse alginate microcapsules with oil cores, where the thickness of the alginate shells, as well as the number and diversity of the oil cores can be tailored precisely. Monodisperse oil-in-water-in-oil (O/W/O) emulsions are generated in a microfluidic device as templates, which contain alginate molecules and a water-soluble calcium complex in the middle aqueous phase. Alginate microcapsules are produced by gelling O/W/O emulsions in oil solution with acetic acid, where the pH decreasing will trigger the calcium ions being released from calcium complex and cross-linking with alginate molecules. Increasing the alginate molecule concentration in emulsion templates affects little on the thickness of the microcapsules but improves their stability in DI water. The strength of alginate microcapsules can be reinforced by post cross-linking in calcium chloride, polyetherimide, or chitosan solution. Typical payloads, such as thyme essential oil, lavender essential oil and W/O emulsions are encapsulated in alginate microcapsules successfully. Furthermore, tailoring the thickness of the alginate shells, as well as the number and the diversity of the oil cores precisely by manipulation the emulsion templates with microfluidics is also demonstrated. The proposed method shows excellent controllability in designing alginate microcapsules with oil cores.