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1.
Ecotoxicol Environ Saf ; 243: 113997, 2022 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-35988380

RESUMEN

Concerns about the micro/nano plastics (MNPs) exposure risks have risen in recent years. The ecological corona (EC), which is generated by the interaction between MNPs and environmental substances, has a significant impact on their environmental fate and ecological risks. As the largest sink of MNPs, the aquatic environment is of great significance for understanding the environmental behaviour of MNPs. Transmission Electron Microscope (TME), Fourier Transform Infra-Red (FTIR), Scanning Electron Microscope (SEM), Dynamic Light Scattering (DLS) and other analytical methods have been used as effective methods to analyse the formation process of EC and detect the existing EC directly or indirectly on the surface of MNPs. The physicochemical properties of MNPs, complex aquatic environments and ageing time have been identified as the key factors affecting EC formation in aquatic environments. Moreover, the EC absorbed on MNPs significantly changed their environmental behaviour and toxicity to aquatic organisms. This review gives a full understanding of the EC formation progress on the surface of MNPs and different analytical methods for EC have been summarised which can further assist the ecological risk assessment of MNPs in the aquatic environment.


Asunto(s)
Organismos Acuáticos , Contaminantes Químicos del Agua , Microplásticos/toxicidad , Contaminantes Químicos del Agua/análisis , Contaminantes Químicos del Agua/toxicidad
2.
Comput Assist Surg (Abingdon) ; 28(1): 2210744, 2023 12.
Artículo en Inglés | MEDLINE | ID: mdl-37256777

RESUMEN

IntroductionIn craniofacial surgery, magnetic navigation systems can effectively extend the doctor's limited visual range, improve their surgical precision, shorten the operation time, and reduce the incidence of surgical complications. Owing to the ease of magnetic navigation, the accuracy of the magnetic navigation system is affected by various equipment in the operating room. Therefore, its large-scale application is lacking because the navigation accuracy requirement can be extremely high during craniofacial surgery. Therefore, the accuracy of magnetic navigation systems is crucial. Various surgical instruments have been evaluated to effectively reduce the interference of magnetic navigation systems with surgical instruments. In craniofacial surgery, magnetic navigation systems can effectively extend the doctor's limited visual range, improve their surgical precision, shorten the operation time, and reduce the incidence of surgical complications. Owing to the ease of magnetic navigation, the accuracy of the magnetic navigation system is affected by various equipment in the operating room. Therefore, its large-scale application is lacking because the navigation accuracy requirement can be extremely high during craniofacial surgery. Therefore, the accuracy of magnetic navigation systems is crucial. Various surgical instruments have been evaluated to effectively reduce the interference of magnetic navigation systems with surgical instruments. In the surgical environment, the use of surgical instruments during mandibular surgery was simulated by selecting several conventional surgical instruments to record errors in the magnetic navigation system. The fluctuation values of the magnetic navigation errors were subsequently estimated and changes in its accuracy measured. MATLAB was used to calculate and analyze the fluctuations of the magnetic navigation errors. As results, the high-frequency electrosurgical system caused the greatest interference with the magnetic navigation system during surgery while powered on, with a maximum fluctuation error value of 1.8120 mm, and the maximum fluctuation error values of the stitch scissors, teeth forceps, and a needle holder were 1.3662, 1.3781, and 0.3912 mm, respectively. The closer the instrument is to the magnetic field generator or navigation target, the greater its impact. In conclusion, stitch scissors, teeth forceps, a needle holder, and the high-frequency electrosurgical system all affect magnetic navigation system accuracy. Therefore, it is necessary to avoid magnetic navigation system use and surgical instrument disturbances during surgery or select surgical instruments that do not interfere with the system. Surgical instruments must be evaluated for electromagnetic interference before they can be used in surgery with a magnetic navigation system.


Asunto(s)
Robótica , Cirugía Asistida por Computador , Humanos , Cirugía Asistida por Computador/métodos , Instrumentos Quirúrgicos , Tempo Operativo , Fenómenos Magnéticos
3.
Small ; 2(11): 1283-91, 2006 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-17192975

RESUMEN

A method to functionalize single-walled carbon nanotubes (SWNTs) in a field-effect transistor (FET) device for the selective detection of heavy-metal ions is presented. In this method, peptide-modified polymers were electrochemically deposited onto SWNTs and the selective detection of metal ions was demonstrated by choosing appropriate peptide sequences. The signal transduction mechanism of the peptide-modified SWNT-FETs has also been studied.


Asunto(s)
Iones Pesados , Nanotubos de Carbono/química , Cobre/química , Electroquímica/métodos , Glicina/química , Oro/química , Iones , Cinética , Ensayo de Materiales , Níquel/química , Péptidos/química , Polímeros/química , Transducción de Señal , Termodinámica , Agua/química
4.
ACS Nano ; 7(11): 10319-26, 2013 Nov 26.
Artículo en Inglés | MEDLINE | ID: mdl-24161197

RESUMEN

Nanopores were fabricated with an integrated microscale Pd electrode coated with either a hydrogen-bonding or hydrophobic monolayer. Bare pores, or those coated with octanethiol, translocated single-stranded DNA with times of a few microseconds per base. Pores functionalized with 4(5)-(2-mercaptoethyl)-1H-imidazole-2-carboxamide slowed average translocation times, calculated as the duration of the event divided by the number of bases translocated, to about 100 µs per base at biases in the range of 50 to 80 mV.


Asunto(s)
ADN/química , Electrodos , Nanoporos , Transporte Biológico , ADN de Cadena Simple/química , Diseño de Equipo , Enlace de Hidrógeno , Ensayo de Materiales , Membranas Artificiales , Microscopía de Fuerza Atómica , Nanotecnología/métodos , Distribución Normal , Paladio/química , Compuestos de Sulfhidrilo/química , Propiedades de Superficie , Factores de Tiempo
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