Preparation and characterization of a novel polyethyleneimine cation-modified persimmon tannin bioadsorbent for anionic dye adsorption.

A novel and recyclable bioadsorbent (PTP) has been prepared by the cationization of persimmon tannin (PT) using polyethyleneimine (PEI) for application in the removal of the anionic dye methyl orange (MO) from aqueous solution. The physicochemical properties of the prepared PTP were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, Zeta potential measurements, Brunauer-Emmett-Teller and thermogravimetric analysis. Systematic batch adsorption experiments were carried out with pH, bioadsorbent dosage, initial MO concentration and contact time. Kinetic regression analysis indicated that the adsorption processes followed the pseudo-second order model. The equilibrium isotherm was in good fit with the Freundlich model with a maximum adsorption capacity of 225.74 mg/g. Thermodynamics data revealed that the adsorption of MO onto PTP was feasible, spontaneous and endothermic. A possible biosorption mechanism was presented where electrostatic interactions, hydrogen bonding, and π-π interactions dominated the adsorption of MO onto PTP. Moreover, the regeneration of the PTP was easily achieved and MO removal efficiency remained high (81.47%) after six cycles. The actual sewage treatment simulation was evaluated and the PTP had a good preference to adsorption MO. All these results indicated that PTP could be considered a high performance and promising candidate for the effective removal of anionic dyes from aqueous solutions.

Persimmon tannin functionalized polyacrylonitrile fiber for highly efficient and selective recovery of Au(III) from aqueous solution.

An efficient fibrous adsorbent (PANF-TETA-PT) was prepared via grafting triethylenetetramine (TETA) on polyacrylonitrile fiber (PANF), followed by persimmon tannin (PT) immobilizing. Detailed characterization certified that plenty amounts of amino and phenolic hydroxyl groups existed on the surface of PANF-TETA-PT, which would provide excellent active sites for Au(III) adsorption. The batch characteristic results found that the adsorption equilibrium data could be fitted well with Langmuir equation, while the obtained kinetic data were consistent with the Pseudo-second-order equation. The maximum equilibrium adsorption capacity of PANF-TETA-PT towards Au(III) (801.2 mg/g) was apparently superior than that of the reported adsorbents, and the competitive adsorption showed that PANF-TETA-PT had a good preference to adsorption Au(III) in spite of some coexisting pollutants. The characterization analysis of Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffractometer spectrum (XRD) revealed that the electrostatic attraction and chelation dominated the uptake of Au(III) on PANF-TETA-PT, in which a part of loaded Au(III) was reduced to Au particles with the help of reductive functional groups. Thus, this adsorbent could be as a promising candidate to separation and preconcentration of Au(III) from wastewater.