RESUMO
Photoresponsive behaviors are studied in hybrid liquid-crystalline (LC) films prepared with light-responsive LC polymer microparticles as dopants using photoinert polymers as a host material. Upon mechanical stretching, both topological shape change and mesogenic alignment occur in the LC polymer microparticles, enabling the polymer-dispersed LC (PDLC)-like films to bend toward a light source upon UV irradiation. The rough morphologies of the hydrophobic LC microparticles enhance their interactions with hydrophilic polymer substrates. The bilayer-like structures of the hybrid film formed in the fabrication processes are responsible for the photomechanical behavior, which is reversibly controlled by combing light irradiation with the stretching processes.