Selective recovery of salt from coal gasification brine by nanofiltration membranes.

The selective extraction and concentration of salt from coal gasification brine (CGB) by nanofiltration membranes is a promising technology to achieve near-zero liquid discharge of coal gasification wastewater. To investigate the feasibility of recovery of salts and the interaction of organic compounds, multivalent ions and monovalent ions on the rejection ratio, three nanofiltration membranes (OWNF1, NF270 and Desal-5 DK) with an 1812 spiral-wound module were used in crossflow filtration. The rejection mechanism was analyzed by comparing the rejection performance as a function of the operation pressure (increasing from 1.0 MPa to 2.5 MPa), the concentration (increasing from 10,000 mg/L to 25,000 mg/L) and pH values (increasing from 3.0 to 10.0). The concentrations of anions and cations were determined using an ion chromatographic analyzer and an inductively coupled plasma emission spectrometer, respectively. The results show that the rejection of sulfate and the chemical oxygen demand were higher than 92.12% and 78.84%, respectively, at appropriate operation, while negative rejection of chloride was observed in the CGB. The decreasing rejection of organic compounds was due to swelling of the membrane pore in high-concentration solutions. Meanwhile, the organic compounds weakened the negative charge of the membrane active layer, consequently decreasing the ion rejection. More than 85% of the sodium chloride could be recovered, indicating that this technology is suitable for resource recovery from CGB and near-zero liquid discharge of coal gasification industry.

Antimicrobial research of carbohydrate polymer- and protein-based hydrogels as reservoirs for the generation of reactive oxygen species: A review.

Reactive oxygen species (ROS) play an important role in biological milieu. Recently, the rapid growth in our understanding of ROS and their promise in antibacterial applications has generated tremendous interest in the combination of ROS generators with bulk hydrogels. Hydrogels represent promising supporters for ROS generators and can locally confine the nanoscale distribution of ROS generators whilst also promoting cellular integration via biomaterial-cell interactions. This review highlights recent efforts and progress in developing hydrogels derived from biological macromolecules with embedded ROS generators with a focus on antimicrobial applications. Initially, an overview of passive and active antibacterial hydrogels is provided to show the significance of proper hydrogel selection and design. These are followed by an in-depth discussion of the various approaches for ROS generation in hydrogels. The structural engineering and fabrication of ROS-laden hydrogels are given with a focus on their biomedical applications in therapeutics and diagnosis. Additionally, we discuss how a compromise needs to be sought between ROS generation and removal for maximizing the efficacy of therapeutic treatment. Finally, the current challenges and potential routes toward commercialization in this rapidly evolving field are discussed, focusing on the potential translation of laboratory research outcomes to real-world clinical outcomes.

Enhanced anaerobic degradation of quinoline and indole with the coupling of sodium citrate and polyurethane.

A coupling system of sodium citrate and biofilm based on polyurethane was prepared to analyse the coupling enhancement degradation on quinoline and indole. Four reactors (R1: sludge, R2: sludge + sodium citrate, R3: biofilm on polyurethane, and R4: biofilm + sodium citrate) were operated 120 days to compare the degradation efficiency. During whole running phases, R4 showed high degradation efficiency on quinoline (≥98.55%) and indole (≥95.44%). Analysis of bacterial colony showed anaerobic sludge reactors benefited the enrichment of Aminicenantes, Levilinea, and Longilinea, while anaerobic biofilm reactors benefited the enrichment of Giesbergeria and Comamonas. Furthermore, analysis of archaea colony showed acetic acid metabolism to produce methane was the main mode in anaerobic sludge reactors, while acetic acid and hydrogen metabolism to produce methane were both the main modes in biofilm reactors. This study can provide some references for the treatment of nitrogen heterocyclic wastewater.

Enhanced anaerobic degradation of quinoline, pyriding, and indole with polyurethane (PU), Fe3O4@PU, powdered activated carbon (PAC), Fe(OH)3@PAC, biochar, and Fe(OH)3@biochar and analysis of microbial succession in different reactors.

The study was to explore the feasibility of polyurethane (PU), Fe3O4@PU, powdered activated carbon (PAC), Fe(OH)3@PAC, biochar, and Fe(OH)3@biochar as biological carriers in strengthening anaerobic degradation of quinoline, pyridine, and indole. When the concentrations of pollutants were 25 mg/L and 50 mg/L, reactors based on PAC and Fe(OH)3@PAC had higher degradation ratios than the other reactors. However, when the concentrations of pollutants were 75 mg/L and 100 mg/L, with the addition of PU and Fe3O4@PU, reactors began to show their superiority in the degradation of the selected NHCs. Among these, the reactor based on Fe3O4@PU had the optimal degradation ratio on quinoline, pyridine, and indole. PU, PAC, Fe(OH)3@PAC, biochar, and Fe(OH)3@biochar benefited the enrichment of Acinetobacter, Comamonas, Levilinea, Longilinea, and Desulfomicrobium. The reactor with the carrier of Fe3O4@PU had some specificity, which benefited the enrichment of Zoogloea, Thiobacillus, Anaeromyxobacter, Sphingobium, Terrimonas, Parcubacteria genera incertae sedis, Bdellovibrio, Rhizobium, and Acidovorax.

Enhanced biodegradation of coal gasification wastewater with anaerobic biofilm on polyurethane (PU), powdered activated carbon (PAC), and biochar.

The primary objective was to explore the feasibility of anaerobic biofilm on polyurethane (PU), powdered activated carbon (PAC), and biochar in strengthening anaerobic degradation of phenolic compounds and selected nitrogen heterocyclic compounds (NHCs) in coal gasification wastewater (CGW). When total phenols (TPh) was less than 300 mg/L, PAC-based biofilm was more efficient. Whereas, when the TPh concentration was more than 450 mg/L, PU-based biofilm performed the optimal degradation efficiency. Furthermore, microbial community structure analysis showed that PAC and biochar had little effect on the microbial community structure after 120 days of operation, while the addition of PU could lead to the enrichment of Giesbergeria, Caldisericum, Thauera, Methanolinea, and Methanoregula.

Enhanced nitrogen removal of coal pyrolysis wastewater with low COD to nitrogen ratio by partial nitrification-denitrification bioprocess assisted with polycaprolactone.

The purpose of this study is to investigate the enhancement of polycaprolactone (PCL) on total nitrogen (TN) removal of coal pyrolysis wastewater (CPW) with low COD to nitrogen ratio by partial nitrification-denitrification bioprocess (PNDB) in one single reactor. With the innovative combination of PCL and PNDB, the TN removal efficiency in the experimental reactor (signed as R1) was 10.21% higher than control reactor (R2). Nitrite accumulation percentage (NAP) in R1 was 82.02%, which was 17.49% higher than R2 at the dissolved oxygen (DO) concentration of 0.9-1.5 mg/L, for the reason that the extra DO was consumed by PCL biodegradation at the aerobic period. Gel permeation chromatography (GPC) results demonstrated that organics with the molecular weight of 185 Da, which could serve as additional carbon sources for denitrifiers, were generated during the PCL hydrolysis process at the anoxic period. PCL was hydrolyzed by extracellular enzymes with the break of the ester bond which was confirmed by FT-IR spectrometer. Microbial community analysis revealed that Ferruginibacter was the dominant hydrolysis bacteria in R1. Nitrosomonas were the main ammonium-oxidizing bacteria (AOB) and Hyphomicrobium were the denitrifiers in this study.

Removal of selected nitrogenous heterocyclic compounds in biologically pretreated coal gasification wastewater (BPCGW) using the catalytic ozonation process combined with the two-stage membrane bioreactor (MBR).

Three identical anoxic-aerobic membrane bioreactors (MBRs) were operated in parallel for 300 consecutive days for raw (R1), ozonated (R2) and catalytic ozonated (R3) biologically pretreated coal gasification wastewater (BPCGW) treatment. The results demonstrated that catalytic ozonation process (COP) applied asa pretreatment remarkably improved the performance of the unsatisfactory single MBR. The overall removal efficiencies of COD, NH3-N and TN in R3 were 92.7%, 95.6% and 80.6%, respectively. In addition, typical nitrogenous heterocyclic compounds (NHCs) of quinoline, pyridine and indole were completely removed in the integrated process. Moreover, COP could alter sludge properties and reshape microbial community structure, thus delaying the occurrence of membrane fouling. Finally, the total cost for this integrated process was estimated to be lower than that of single MBR. The results of this study suggest that COP is a good option to enhance pollutants removal and alleviate membrane fouling in the MBR for BPCGW treatment.