RESUMO
Particulate matter (PM) air pollution has been established as a significant threat to public health and a destructive factor to the climate and eco-systems. In order to eliminate the effects of PM air pollution, various air filtering strategies based on electrospun nanofibers have recently been developed. However, to date, almost none of the existing nanofibers based air filters can meet the requirements of high-performance air PM filtering, including high PM removal efficiency, low resistance to airflow, and long service life, etc. For the first time, we report a fabrication process using the electrospinning method for air filters based on thermoplastic polyurethane (TPU) nanofibers. The average diameters of TPU nanofibers are tunable from 0.14 ± 0.06 µm to 0.82 ± 0.22 µm by changing the TPU concentrations in polymeric solutions. The optimized TPU nanofibers based air filters demonstrate the attractive attributes of high PM2.5 removal efficiency up to 98.92%, good optical transparency of â¼60%, low pressure drop of â¼10 Pa, high quality factor of 0.45 Pa-1, and long service life under the flow rate of 200 ml min-1, which is ground-breaking compared with the existing nanofibers based air filters. These TPU nanofibers based air filters, with the excellent filtration performance and light transmittance, will shed light on the future research of nanofibers for various filtration applications and greatly benefit the public health by reducing the effects of PM air pollution.
Assuntos
Filtros de Ar , Poluentes Atmosféricos/análise , Material Particulado/análise , Plásticos/química , Poliuretanos/química , Eletricidade Estática , Temperatura , Nanofibras/química , Nanofibras/ultraestruturaRESUMO
In this study, we developed an enhanced heterogeneous interface intelligent conductive hydrogel NH3 sensor for individualized treatment of infected wounds. The sensor achieved monitoring, self-diagnosis, and adaptive gear adjustment functions. The PPY@PDA/PANI(3/6) sensor had a minimum NH3 detection concentration of 50 ppb and a response value of 2.94 %. It also had a theoretical detection limit of 49 ppt for infected wound gas. The sensor exhibited a fast response time of 23.2 s and a recovery time of 42.9 s. Tobramycin (TOB) was encapsulated in a self-healing QCS/OD hydrogel formed by quaternized chitosan (QCS) and oxidized dextran (OD), followed by the addition of polydopamine-coated polypyrrole nanowires (PPY@PDA) and polyaniline (PANI) to prepare electrically conductive drug-loaded PPY@PDA/PANI hydrogels. The drug-loaded PPY@PDA/PANI hydrogel was combined with a PANI/PVDF membrane to form an enhanced heterogeneous interfacial PPY@PDA/PANI/PVDF-based sensor, which could adaptively learn the individual wound ammonia response and adjust the speed of drug release from the PPY@PDA/PANI hydrogel with electrical stimulation. Drug release and animal studies demonstrated the efficacy of the PPY@PDA/PANI hydrogel in inhibiting infection and accelerating wound healing. In conclusion, the gas-sensitive conductive hydrogel sensing system is expected to enable intelligent drug delivery and provide personalized treatment for complex wound management.