RESUMO
Cyclodextrin (CD)-based polyrotaxanes (PR) are widely used to construct high-mechanical-performance materials because of the high degree of conformational freedom. However, strong hydrogen bonds between CDs greatly limit the application of CD-PR in the preparation of ductile neutral hydrogels. In this work, spiropyrane (SP) into α-CD-based PR is introduced to "visualize" the segment motion of the network in neutral water. The aggregation-induced cohesion and critical factors for the force transmission are disclosed. This system offers a new approach for the fundamental research for the complicated topologically cross-linked structures, which is important for the design of CD-PR-based biocompatible soft materials.
Assuntos
Ciclodextrinas , Rotaxanos , Materiais Biocompatíveis/química , Ciclodextrinas/química , Hidrogéis/química , Rotaxanos/química , SolventesRESUMO
The force response of nanosized vesicles shows substantial applications in drug delivery, cancer therapies, and so on. Conventional methods in mechanical studies on vesicles rely on a camera and an optical microscope, which can hardly work for nanosized particles. Herein, we use self-assembled polydiacetylene (PDA) as a chromic mechanoresponsive group to study the responsiveness of nanovesicles under sonication. The sonication-induced deformation of the PDA backbone and reduction in its conjugation length leads to a color transition from blue to red. Three internal and external factors, including greater shear stress, lower polymerization degree, and higher viscosity of the continue phase, have been found to promote the mechanochromism of the vesicles. These results, for the first time, reveal that the force response of vesicles depends on the actual capillary number (correlated with the three explored factors), even at the nanoscale level, which opens a new avenue to mechanical modulation of nanovesicles for the development of vesicle-based bio- and nanotechniques.
Assuntos
Sistemas de Liberação de Medicamentos , Ultrassom , Polímero PoliacetilênicoRESUMO
Intrinsically and fully stretchable active-matrix-driven displays are an important element to skin electronics that can be applied to many emerging fields, such as wearable electronics, consumer electronics and biomedical devices. Here, we show for the first time a fully stretchable active-matrix-driven organic light-emitting electrochemical cell array. Briefly, it is comprised of a stretchable light-emitting electrochemical cell array driven by a solution-processed, vertically integrated stretchable organic thin-film transistor active-matrix, which is enabled by the development of chemically-orthogonal and intrinsically stretchable dielectric materials. Our resulting active-matrix-driven organic light-emitting electrochemical cell array can be readily bent, twisted and stretched without affecting its device performance. When mounted on skin, the array can tolerate to repeated cycles at 30% strain. This work demonstrates the feasibility of skin-applicable displays and lays the foundation for further materials development.