Mechanistic study on the promotion of Ca2+ leaching in steel slag through high-temperature solid waste modification.

Indirect carbonation of steel slag is an effective method for CO2 storage, reducing emissions, and promoting cleaner production in the steel industry. However, challenges remain, such as low Ca2+ leaching rates and slag management complexities arising from variations in mineral compositions. To address this, a high-temperature modification process is proposed to alter the mineral composition and facilitate the synergistic utilization of calcium and iron. This study delves into the effects of various solid waste modifications on the leaching of Ca2+ and the total iron content within steel slag. Results show that high-basicity modified slag forms Ca2(Al, Fe)2O5, reducing calcium leaching. Low-alkalinity modified slag produces calcium-rich aluminum minerals and also reduces the leaching of Ca2+ ions. At a basicity of 2.5, coal gangue, fly ash, and blast slag achieve maximum Ca2+ leaching rates of 88.93%, 89.46%, and 90.17%, respectively, with corresponding total iron contents of 41.46%, 37.72%, and 35.29%. Upgraded coal gangue exhibits a 50.02% increase in calcium leaching and a 15.58% increase in total iron content compared to the original slag. This enhances CO2 fixation and iron resource utilization. Overall, the proposed indirect carbonation and iron enrichment modification offer a novel approach for the resource utilization and environmental stability of steel slag.

The reflection of guided waves from simple dents in pipes.

Guided elastic waves have been anticipated as a rapid screening technique for pipe inspection. Dents occurring in pipes are a severe problem which may lead to the possibility of pipe failure. A study of the reflection characteristics of guided waves from dents of varying geometrical profile in pipes is investigated through experiments. Dented region is represented by a series of circumferential cross-sections and its geometric parameters are described by axial length and the maximum and minimum outer diameters. Both single and double sided dents are mechanically simulated in hollow aluminum pipes and then experimentally tested by exciting the longitudinal L(0,2) mode. A quantitative parameter, so-called deformation rate relating to the maximum and minimum outer diameters of the dents is defined to evaluate the effect of the extent of the deformation on the reflection. For both types of dents, it is shown that the reflection coefficients of the L(0,2) mode are all approximately a linear function of their respective deformation rates. Mode conversion occurs at the dents and reflections of the F(1,3) mode are identified. The results show that the amplitude of the reflected F(1,3) mode is generally higher when the dent has stronger non-axisymmetric features.