Morphotropic Phase Boundary in Polarized Organic Piezoelectric Materials.

Designing the morphotropic phase boundary (MPB) has been the most sought-after approach to achieve high piezoelectric performance of piezoelectric materials. However, MPB has not yet been found in the polarized organic piezoelectric materials. Here, we discover MPB with biphasic competition of ß and 3/1-helical phases in the polarized piezoelectric polymer alloys (PVTC-PVT) and demonstrate a mechanism to induce MPB using the compositionally tailored intermolecular interaction. Consequently, PVTC-PVT exhibits a giant quasistatic piezoelectric coefficient of >32 pC/N while maintaining a low Young's modulus of 182 MPa, with a record-high figure of merit of piezoelectricity modulus of about 176 pC/(N·GPa) among all piezoelectric materials.

Tough and Degradable Self-Healing Elastomer from Synergistic Soft-Hard Segments Design for Biomechano-Robust Artificial Skin.

Increasing biomechanical applications of skin-inspired devices raise higher requirements for the skin-bionic robustness and environmental compatibility of elastomers. Here, a tough and degradable self-healing elastomer (TDSE) is developed by a synergistic soft-hard segments design. The polyester/polyether copolymer is introduced in soft segments to endow TDSE with flexibility and degradability. The two isomeric diamines are regulated in hard segments for elevating the toughness and fracture energy to 82.38 MJ/m3 and 43299 J/m2 and autonomous self-healing ability with 93% efficiency in 7 h for the TDSE. Employing TDSE and ionic liquid, a biomechano-robust artificial skin (BA-skin) is constructed with a stretch-insensitive mechanosensation capability during 50% cyclic stretching. The BA-skin has high biomechano-robustness to bear tear damage and good environmental compatibility with total decomposability in a lipase solution. This work provides a molecular design guideline for high-performance skin-bionic elastomers for applications in skin-inspired devices.

Highly Robust and Self-Powered Electronic Skin Based on Tough Conductive Self-Healing Elastomer.

Self-powered electronic skin (E-skin) can be endowed with high robustness by employing self-healing materials. However, most self-powered E-skin employs two heterogeneous materials with high modulus mismatch at the interface and poor fully self-healing ability, which reduces the robustness of the whole device. Here, a conductive polyurethane elastomer (PUE) with excellent mechanical toughness and self-healing ability is prepared. Based on the self-healing insulated/conductive PUE homogeneous structure and triboelectric-electrostatic induction effect, a highly robust and self-powered E-skin (HRSE-skin) is developed. The HRSE-skin possesses stable mechanosensation capability during the 50% stretching deformation due to a low modulus mismatch in the homogeneous structure. In addition, the stretchability and mechanosensation capability of the HRSE-skin can be restored after the fracture owing to the fully self-healing ability of the homogeneous structure. Therefore, the HRSE-skin has high robustness of the whole device including stable service behaviors and excellent restorability. The developed HRSE-skin demonstrates high robustness in the detection of the force and bending angle of the prosthetic joint. This work solves the low robustness of self-powered E-skin by the preparation of conductive self-healing PUE and the construction of the homogeneous structure, which is important for the practical applications of self-powered E-skin in prosthetic limbs and advanced robotics.