Photoresponsive Hydrogen-Bonded Organic Frameworks-Enabled Organic Photoelectrochemical Transistors for Sensitive Bioanalysis.

A facile route for exponential magnification of transconductance (gm) in an organic photoelectrochemical transistor (OPECT) is still lacking. Herein, photoresponsive hydrogen-bonded organic frameworks (PR-HOFs) have been shown to be efficient for gm magnification in a typical poly(ethylene dioxythiophene):poly(styrenesulfonate) OPECT. Specifically, 450 nm light stimulation of 1,3,6,8-tetrakis (p-benzoic acid) pyrene (H4TBAPy)-based HOF could efficiently modulate the device characteristics, leading to the considerable gm magnification over 78 times from 0.114 to 8.96 mS at zero Vg. In linkage with a DNA nanomachine-assisted steric hindrance amplification strategy, the system was then interfaced with the microRNA-triggered structural DNA evolution toward the sensitive detection of a model target microRNA down to 0.1 fM. This study first reveals HOFs-enabled efficient gm magnification in organic electronics and its application for sensitive biomolecular detection.

One-step preparation of carboxyl-functionalized porous organic polymer as sorbent for enrichment of phenols in bottled water, juice and honey samples.

Herein, a novel carboxyl-functionalized porous organic polymer (COOH-POP) was prepared as sorbent. Due to multiple hydrogen bonds and π-π interactions between COOH-POP and phenols, COOH-POP shows good enrichment ability and very fast adsorption rate for phenols. Then, an analytical method was developed for determination of five phenols (2-chlorophenol, bisphenol A, 2,6-dichlorophenol, 2,4-dichlorophenol and p-tert-butylphenol) in bottled water, lemon juice, peach juice and honey samples using COOH-POP as solid phase extraction sorbent in combination with high performance liquid chromatography. Under optimal conditions, the COOH-POP based method gave the detection limits (S/N = 3) of 0.02-0.10 ng mL-1 for bottled water, 0.03-0.12 ng mL-1 for lemon juice, 0.03-0.25 ng mL-1 for peach juice and 0.7-1.5 ng g-1 for honey samples. The recoveries for spiked samples ranged from 84.0 % to 119.0 % with relative standard deviation less than 7.6 %. This study provides a new yet effective method for enrichment of phenols by designing carboxyl-functionalized porous organic polymer as sorbent.

Synthesis of phosphate-functionalized magnetic porous organic polymer: A sorbent for sensitive determination of neonicotinoid insecticides in water and lemon juice.

There is an urgent need to prepare advanced functional materials for extraction and enrichment of trace organic pollutants from different samples. In this work, two novel phosphate-functionalized porous organic polymers (DBP-POP and DPP-POP) were synthesized for the first time. Compared with phosphate-free counterpart, both phosphate-functionalized POPs showed excellent adsorption performance for the neonicotinoids due to the hydrogen bonding, π-π interaction and hydrophobic interaction. For ease of separating the sorbent from solution, magnetic DBP-POP (M-DBP-POP) was further prepared as sorbent to extract neonicotinoids from environmental water and lemon juice samples prior to their determination by high performance liquid chromatography-ultraviolet detection. Under optimal conditions, the detection limits (S/N = 3) of the method were 0.01-0.08 ng mL-1 for water and 0.03-0.10 ng mL-1 for lemon juice. The recoveries were in the range of 80.0% to 113.0% with relative standard deviation less than 10.6%. This work demonstrated the feasibility of phosphate-functionalized POPs for adsorption applications.