RESUMO
Efficient and sustainable methods for eliminating polycyclic aromatic hydrocarbon pollutants (PAHPs) are in highly desired. Proven technologies involve physical and chemical reactions that absorb PAHPs, however they encounter formidable challenges. Here, a bottom-up refining-grain strategy is proposed to rationally design ultrafine CuO/graphene oxide-cellulose nanocomposites (LCelCCu) with a mirror-like for tetracycline (TC) to substantially improve the efficient of the purification process by active integrated-sorption. The LCelCCu captures TC with a higher affinity and lower energy demand, as determined by sorption kinetic, isotherms, thermodynamics, and infrared and X-ray Photoelectron Spectroscopy. The resulting material could achieve ultra-high sorption capacity (2775.23 mg/g), kinetic (1.2499 L g-1 h-1) and high selectivity (up to 99.9 %) for TC, nearly surpassing all recent adsorbents. This study simultaneously unveils the pioneering role of simultaneous multi-site match sorption and subsequent advanced oxidation synergistically, fundamentally enhancing understanding of the structure-activity-selectivity relationship and inspires more sustainable water purification applications and broader material design considerations.
Assuntos
Celulose , Grafite , Nanocompostos , Hidrocarbonetos Policíclicos Aromáticos , Poluentes Químicos da Água , Grafite/química , Nanocompostos/química , Hidrocarbonetos Policíclicos Aromáticos/química , Poluentes Químicos da Água/química , Celulose/química , Adsorção , Purificação da Água/métodos , Cobre/química , CinéticaRESUMO
Fouling mechanism of the forward osmosis membrane, which was peculiarly featured by the asymmetric membrane structure and reverse solute diffusion, was investigated at the molecular level and from the energy perspective. Two noteworthy fouling behaviors were observed in batch fouling tests conducted in AL-FS mode (active layer facing feed solution) and AL-DS mode (active layer facing draw solution) after filtering foulants with identical volume: 1) after filtering 100 mL of foulants, the flux decline rate in AL-DS mode was 1.78 times faster than that in AL-FS mode, but the flux decline behaviors of the two modes were similar in the subsequent filtration stages; 2) although the foulant layer weight of the same mode increased linearly in middle and late stages, the flux loss rate was distinctly different. Thermodynamic analysis indicated that the attractive interaction energy between the foulants and the support layer was about 5 times higher than that between the foulants and the active layer, well interpreting the higher flux decline rate of AL-DS mode in initial stage. Meanwhile, a non-invasive microscope observed that the structure of the fouling layer remarkably changed from loose to dense in the middle stage, and stabilized in the late stage. Furthermore, quantum chemistry calculation proved that the reverse diffusion of NaCl brought alginate molecular chains closer, whereas the distance between them tended to be constant as the continuous increase of NaCl. Based on these findings, the thermodynamic fouling mechanism proposed by combining the structure change process of the fouling layer with Flory-Huggins lattice theory satisfactorily interpreted the noteworthy fouling behaviors caused by reverse NaCl diffusion in middle and late stages. The revealed fouling mechanism unifies the adhesion and filtration behaviors related to the unique properties of FO membrane, deepening understanding of membrane fouling in the dynamic and complex ternary system of the FO process.
Assuntos
Membranas Artificiais , Purificação da Água , Filtração , Osmose , Soluções , TermodinâmicaRESUMO
While transparent exopolymer particles (TEP) has high fouling potential, its underlying fouling mechanisms have not yet been well revealed. In current work, fouling characteristics of TEP under different Ca2+ concentrations (0 to 1.5 mM) were investigated. TEP quantification and filtration tests showed that TEP contents increased with Ca2+ concentration, while TEP's specific filtration resistance (SFR) under the influence of Ca2+ concentration presented a unimodal pattern. The peak of TEP's SFR reached at Ca2+ concentration of 1 mM when SA concentration was 0.3 g·L-1. A series of characterizations suggested that microstructure transformation of TEP particles was the main contributor to the resistance variations of TEP solution. The optical microscope observation showed that above and below the critical Ca2+ concentration (1 mM when SA concentration is 0.3 g·L-1 in this study), the formed TEP existed in the form of c-TEP (average particle size is 0.24 µm) and p-TEP (average particle size is 1.05 µm), respectively. Thermodynamic analysis showed that the adhesion ability of c-TEP (-249,989 and - 303,692 kT) was more than 19 times than that of p-TEP (-12,905 kT), which would accelerate foulant layer formation. In addition, below the critical value, the increased SFR with Ca2+ concentration could be explained by integrating Flory-Huggins lattice theory with the preferential intermolecular coordination. Above the critical value, the decreased SFR can be attributed to the formation of a "large-size crack structure" cake layer from the p-TEP. This study revealed fundamental mechanisms of membrane fouling caused by TEP, greatly deepening understanding of TEP fouling, and facilitating to development of effective fouling control strategies.
Assuntos
Matriz Extracelular de Substâncias Poliméricas , Purificação da Água , Filtração , Membranas Artificiais , TermodinâmicaRESUMO
While magnesium cation (Mg2+) universally coexists with natural organic matter (NOM) in the water environment, influence of Mg2+ on NOM fouling in membrane filtration process is still unclear. This work was therefore performed to investigate effects of Mg2+ on NOM (sodium alginate (SA) as a model substance) fouling and role of Ca2+ in mitigating fouling from Mg2+ in the ultrafiltration (UF) water treatment process. Filtration tests showed two interesting fouling phenomena: (1) membrane fouling caused by combination of Mg2+ and SA maintained at a high value with the increased Mg2+ concentration; (2) the high fouling property of Mg2+ can be significantly improved by the prominent addition of calcium cation (Ca2+). It was found that changes of foulant morphology played essential roles through thermodynamic mechanisms represented by the Flory-Huggins lattice theory. Density functional theory (DFT) calculation showed that the combination of SA and Mg2+ tends to coordinate two terminal carboxyl groups in SA, beneficial to stretching alginate chains and forming a stable gel network at low doses. In addition, intramolecular coordination is difficult to occur between SA and Mg2+ due to the high hydration repulsion radius of Mg2+. Therefore, a dense and thick gel network remained even under high Mg2+concentration. Furthermore, due to the higher binding affinity of Ca2+ over Mg2+, high doses of Ca2+ trigger a transition of the stable SA-Mg2+ gel network to other configurations where flocculation and aggregation occur, thereby reducing the specific filtration resistance. The proposed thermodynamic mechanism satisfactorily explained the above interesting fouling behaviors, facilitating to development of new solutions to control membrane fouling.
Assuntos
Ultrafiltração , Purificação da Água , Magnésio , Cálcio/química , Membranas Artificiais , Teoria da Densidade Funcional , Alginatos/química , Cálcio da Dieta , CátionsRESUMO
While ethylenediamine tetramethylenephosphonic acid (EDTMPA) has been emerged as a stronger chelating agent than ethylene diamine tetraacetic acid (EDTA) for fouling mitigation, and transparent exopolymer particles (TEP) is a major foulant in membrane-based water treatment process, effects of EDTMPA on TEP fouling and the underlying mechanism have been not yet studied. In this study, Flory-Huggins lattice theory was combined with density functional theory (DFT) technology to explore this subject at molecular level. Filtration experiments showed a unimodal pattern of specific filtration resistance (SFR) of TEP sample with Ca2+ concentration in range of 0-3 mM. For the TEP sample with the peak SFR value at 1.5 mM Ca2+, continuous addition of EDTMPA (from 0 to 100 mg·L-1) resulted in a sustained decrease in SFR. Energy dispersive spectroscopy (EDS) mapping characterization showed the continuing decline of calcium content in the TEP layer with increase of EDTMPA addition, indicating that EDTMPA successfully captured Ca2+ from alginatecalcium ligation (TEP), and then disintegrated the TEP structure. DFT simulation showed that Ca2+ preferentially coordinated with the terminal carboxyl groups of alginate chains to form a coordination configuration that is conducive to stretch the three-dimensional polymer network. Such a network corresponded to an extremely high SFR according to Flory-Huggins theory. EDTMPA addition caused disintegration of the coordination configuration of Ca2+ binding to terminal carboxyl groups, which further resulted in collapse and flocculation of TEP gel network structure, thus leading to a continuous SFR decrease. This work provided deep thermodynamic insights into effects of EDTMPA on TEP-associated fouling at molecular level, facilitating to better understanding and mitigation of membrane fouling.
Assuntos
Matriz Extracelular de Substâncias Poliméricas , Purificação da Água , Membranas Artificiais , Cálcio/química , Ácido Edético , Filtração , Alginatos/química , Polímeros/química , Etilenodiaminas , Quelantes , EtilenosRESUMO
While transparent exopolymer particles (TEP) is a major foulant, and ethylene diamine tetraacetic acid (EDTA) is a strong chelating agent frequently used for fouling mitigation in membrane-based water treatment processes, little has been known about TEP-associated membrane fouling affected by EDTA. This work was performed to investigate roles of EDTA addition in TEP (Ca-alginate gel was used as a TEP model) associated fouling. It was interestingly found that, TEP had rather high specific filtration resistance (SFR) of 2.49 × 1015 m-1·kg-1, and SFR of TEP solution firstly decreased and then increased rapidly with EDTA concentration increase (0-1 mM). A series of characterizations suggested that EDTA took roles in SFR of TEP solution by means of changing TEP microstructure. The rather high SFR of TEP layer can be attributed to the big chemical potential gap during filtration described by the extended Flory-Huggins lattice theory. Initial EDTA addition disintegrated TEP structure by EDTA chelating calcium in TEP, inducing reduced SFR. Continuous EDTA addition decreased solution pH, resulting into no effective chelating and accumulation of EDTA on membrane surface, increasing SFR. It was suggested that factors increasing homogeneity of TEP gel will increase SFR, and vice versa. This study revealed the thermodynamic mechanism of TEP fouling behaviors affected by EDTA, and also demonstrated the importance of EDTA dosage and pH adjustment for TEP-associated fouling control.
Assuntos
Alginatos , Purificação da Água , Alginatos/química , Ácido Edético , Etilenos , Filtração , Membranas ArtificiaisRESUMO
In this study, mechanisms of membrane fouling caused by polysaccharides with different molecular structures in polyaluminum chloride (PACl) coagulation-ultrafiltration (C-UF) process were explored. Carrageenan and xanthan gum were chosen for model foulants of straight chain and branched chain polysaccharides, respectively. Filtration experiments showed that, with PACl dosage of 0-5 mM, specific filtration resistance (SFR) of carrageenan and xanthan solution showed a unimodal pattern and a continuous decrease pattern, respectively. A series of experimental characterizations indicated that the different SFR pattern was closely related to structure of foulants layer. Density functional theory (DFT) calculation suggested that Al3+ preferentially coordinating with the terminal sulfonyl groups of carrageenan chains to promote gel layer formation at low PACl concentration (0.15 mM). There existed a chemical potential gap between bound water in gel layer and free water in the permeate, so that, filtration through gel layer corresponded to rather high SFR for overcoming this gap. In contrast, Al3+ coordinating with the non-terminal sulfonyl groups of carrageenan at high PACl concentration caused transition from gel layer to cake layer, leading to SFR decrease. However, xanthan gum itself can form a dense gel layer with a complex polymer network by virtue of the interlacing of main chains and branches. Al3+ coordinating with the carboxyl groups on branched chains of xanthan gum resulted in clusters of polymer chains and flocculation, corresponding to the reduced SFR. This proposed molecular-level mechanism well explained membrane fouling behaviors of polysaccharides with different molecular structure, and also facilitated to optimize C-UF process for water treatment.
Assuntos
Ultrafiltração , Purificação da Água , Hidróxido de Alumínio , Carragenina , Membranas Artificiais , Polímeros/química , Polissacarídeos , Ultrafiltração/métodos , Purificação da Água/métodosRESUMO
With the goal of zero-liquid discharge and green energy harvest, extraction of abundant green energy from saline water via pressure retarded osmosis (PRO) technology is a promising but challenging issue for water treatment technologies to achieve water and energy sustainability. Development of high performance PRO membranes has received increased concerns yet still under controversy in practical applications. In this review, a comprehensive and up-to-date discussion of some key historical developments is first introduced covering the major advances of PRO engineering applications and novel membranes especially made in recent years. Then the critical performance indicators of PRO membranes including water flux and power density are briefly discussed. Subsequently, sufficient discussion on four performance limiting factors in PRO membrane and process is presented including concentration polarization, reverse solute diffusion, membrane fouling and mechanical stability. To fully address these issues, an updated insight is provided into recent major progresses on advanced fabrication and modification techniques of novel PRO membranes featuring enhanced performance with different configurations and materials, which are also reviewed in detail based on the viewpoint of design rationales. Afterwards, antifouling strategies and engineering applications are critically introduced. Finally, conclusions and future perspective of PRO membrane for practical operation are briefly discussed.
Assuntos
Purificação da Água , Água , Membranas Artificiais , Osmose , Águas ResiduáriasRESUMO
Anaerobic forward osmosis membrane bioreactor (AnOMBR) is a potential wastewater treatment technology, due to its low energy consumption and high effluent quality. However, membrane fouling is still a considerable problem which causes dwindling of water flux and shortening the membrane lifetime. In this study, electro-assisted anaerobic forward osmosis membrane bioreactor (AnOMEBR) was developed to treat wastewater and mitigate membrane fouling, in which the conductive FO membrane was used both as the separation unit and cathode. The formation, development and alleviation of membrane fouling in AnOMEBR were investigated. The results showed that the soluble microbial products (SMP) content and the proteins/polysaccharides (PN/PS) value in AnOMEBR were 26% and 15% lower than that in AnOMBR, respectively. The absolute value of Zeta of sludge mixture in AnOMEBR was 1.2 times that of the AnOMBR. The increase in the interaction between the membrane surface and the negatively charged foulants could inhibit the adsorption of foulants on membrane surface in the initial stage of membrane fouling. The strong interaction among foulants further affected the composition, structure and thickness of the cake layer on the FO membrane surface. AnOMEBR with a shorter hydraulic retention time, a higher organic loading rate and a lower osmotic pressure difference, could still obtain a lower flux decline rate of 0.063 LMH/h, which was 35.7% lower than AnOMBR. The wastewater treatment capacity of AnOMEBR was nearly 1.5 times that of the AnOMBR. This work provides an efficient strategy for mitigating membrane fouling and improving wastewater treatment capacity.
Assuntos
Reatores Biológicos , Anaerobiose , Membranas Artificiais , Osmose , Águas Residuárias , Purificação da ÁguaRESUMO
Two parallel membrane bioreactors (MBRs) were operated under different calcium dosages (168.5, 27 mg/L) to gain a better understanding of the mechanism of retarding membrane fouling by adding calcium. The results showed that the particle size of sludge flocs increased and the particle size distribution tended to be narrow at the optimum dosage (168.5 mg/L). Calcium was effective in decreasing loosely bound extracellular polymeric substances (LB-EPS) in microbial flocs and soluble microbial products (SMP) in the supernatant at the dosage of 168.5 mg/L by strengthening the neutralization and bridging of EPS with flocs. Furthermore, the amount of CODs and CODc decreased in both the mixed liquor and the fouling cake layer on the membrane surface. In order to compare the filtration characteristics of cake layers from the MBRs with the two calcium dosages, the specific cake resistance and the compressibility coefficient were measured. The specific cake resistance from the MBR with optimum dosage (168.5 mg/L) was distinctly lower than that with low dosage (27 mg/L). The compressibility coefficient of the cake layers under two dosages were respectively attained as 0.65, 0.91. Scanning electron microscopy (SEM) and three-dimensional confocal scanning laser microscope analysis (CLSM) images were utilized to observe the gel layer directly.
Assuntos
Reatores Biológicos , Cálcio/química , Membranas Artificiais , Microscopia Confocal , Microscopia Eletrônica de Varredura , Modelos TeóricosRESUMO
This study investigated a seven month storage and the subsequent reactivation of aerobic granules. The granule size and structure integrity were remained during storage, whereas some cavities and pleats appeared on the surface and further deteriorated the settleability. Along with the reactivation, the physical characteristics and microbial activities of aerobic granules were gradually improved. Activities of heterotrophs and nitrifiers can be fully recovered within 16days and 11days, respectively. Nitrifiers decayed slower during storage and reinstated rapider during reactivation than heterotrophs. In fresh aerobic granules, the dominated ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) were Nitrosomonas and Nitrospira, respectively. During storage, the initially dominated populations decayed rapider than the initially less dominated ones. Extracellular polymeric substances (EPS) significantly decreased within the first month, and then gradually accumulated during the last six months storage. Accumulation of EPS was an effective strategy for maintaining structural integrity of aerobic granules during long-term storage.
Assuntos
Biopolímeros/química , Aerobiose , Amônia/metabolismo , Bactérias/genética , Processos Heterotróficos , Hibridização in Situ Fluorescente , Nitritos/metabolismo , Oxirredução , RNA Ribossômico 16S/análise , Fatores de TempoRESUMO
Much work has been conducted on the topic of forward osmosis (FO), but only a few studies have focused on mitigating external concentration polarization (ECP). This study introduced a simple structure, the corrugated wall channel, to the design of FO module, to induce vortex, and then mitigate ECP. In this study, the corrugated wall channel module (CWCM) was tested under given conditions, with a traditional flat membrane module (FMM) as control. CWCM could mitigate ECP and then enhance water flux. When deionized water was taken as feed solution (FS) and 2-M NaCl solution as draw solution (DS), the water flux enhancement was 16.49 and 18.51% in FO mode (active layer facing FS) and PRO mode (active layer facing DS), respectively. When 0.5-M NaCl solution was taken as FS, the corresponding values were 15.92 and 17.13%, respectively. Computational fluid dynamics (CFD) analysis showed that the CWCM could induce vortex, promote the mixing of the solution in the module, and further contribute to the increase of water flux. The specific shape of CWCM affected its performance on mitigating ECP. Also, the more tortuous CWCM exhibited higher water flux. In addition, CWCM could lessen membrane fouling.
Assuntos
Purificação da Água/métodos , Membranas Artificiais , Osmose , Cloreto de Sódio , ÁguaRESUMO
Reverse draw solute diffusion not only reduces the water flux in forward osmosis (FO), but also contaminates the feed solution and eventually increases the regeneration cost of draw solution. In the present study, a new polyelectrolyte was synthesized as FO draw solute to address this problem. Acrylic acid and sodium p-styrenesulfonate monomers with hydrophilic group were used to fabricate carboxylate polyelectrolyte through free radical polymerization reaction. Results demonstrated that the osmotic pressure of carboxylate polyelectrolyte solution had a good linear relationship with concentration, and the viscosity of 0.18 g/mL solution was less than 5.4 cP. Active layer facing draw solution produced the initial water flux of 11.77 LMH and active layer facing feed solution yielded the initial water flux of 6.68 LMH when the concentration of draw solution was 0.18 g/mL. The reverse solute flux was around 1 gMH, and specific reverse solute flux of 0.18 g/mL carboxylate polyelectrolyte draw solution was 0.11 g/L which was much lower than that of traditional inorganic salts. Finally, diluted draw solution was regenerated via ultrafiltration, and the recovery efficiency of 94.78% was achieved. So, carboxylate polyelectrolyte can be suitable draw solute for FO.
Assuntos
Ácidos Carboxílicos/química , Membranas Artificiais , Modelos Teóricos , Osmose , Polieletrólitos/química , Purificação da Água/métodos , Interações Hidrofóbicas e Hidrofílicas , Pressão Osmótica , Soluções , Viscosidade , Águas Residuárias/químicaRESUMO
During the rejection of trace pharmaceutical contaminants from wastewater by forward osmosis (FO), disposal of the FO concentrate was still an unsolved issue. In this study, by integrating the advantages of forward osmosis and electrochemical oxidation, a forward osmosis process with the function of electrochemical oxidation (FOwEO) was established for the first time to achieve the aim of rejection of trace antibiotics from wastewater and treatment of the concentrate at the same time. Results demonstrated that FOwEO (current density J=1 mA cm(-2)) exhibited excellent rejections of antibiotics (>98%) regardless of different operation conditions, and above all, antibiotics in the concentrate were well degraded (>99%) at the end of experiment (after 3h). A synergetic effect between forward osmosis and electrochemical oxidation was observed in FOwEO, which lies in that antibiotic rejections by FO were enhanced due to the degradation of antibiotics in the concentrate, while the electrochemical oxidation capacity was improved in the FOwEO channel, of which good mass transfer and the assist of indirect oxidation owing to the reverse NaCl from draw solution were supposed to be the mechanism. This study demonstrated that the FOwEO has the capability to thoroughly remove trace antibiotics from wastewater.
Assuntos
Antibacterianos/isolamento & purificação , Eletro-Osmose , Águas Residuárias/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Cromatografia Líquida de Alta Pressão , Desenho de Equipamento , Filtração , Membranas Artificiais , Oxirredução , Espectrometria de Massas em Tandem , Purificação da Água/instrumentaçãoRESUMO
Conductive materials with attached biofilms, were used as membrane filtration biocathodes to filter the effluent and supply electrons for denitrification. Stainless steel mesh and carbon felt were employed to fabricate membrane modules, and the two MFC systems were termed as M1 and M2, respectively. High effluent quality was obtained with M1 and M2 in terms of turbidity, COD and ammonium. In M1, no bioelectrochemical denitrification took place, while nitrate decreased from 35.88±4.15 to 27.33±5.32mg-N/L through the membrane in M2, causing a removal efficiency of 23.3±6.5% with respect to cathodic nitrate. The denitrification ceased without electricity. The maximum power densities of M1 and M2 were 121 and 1253mW/m(3), respectively. Micrococcus bacteria and rod-shaped bacteria covered the surface of carbon felt and fewer bacteria were found on stainless steel mesh. According to fluorescence in situ hybridization, the putative bacteria affiliated with Paracoccus genus and Pseudomonas spp. dominated in the interior biofilm on carbon felt for denitrification. Results demonstrate that the carbon felt system can perform bioelectrochemical denitrification to polish the effluent.
Assuntos
Fontes de Energia Bioelétrica/microbiologia , Nitrogênio/isolamento & purificação , Bactérias/genética , Bactérias/metabolismo , Biocatálise , Biofilmes , Carbono , Fibra de Carbono , Eletroquímica , Desenho de Equipamento , Filtração/instrumentação , Hibridização in Situ Fluorescente , Microscopia Eletrônica de Varredura , Nefelometria e Turbidimetria , Aço Inoxidável , Eliminação de Resíduos Líquidos/instrumentaçãoRESUMO
In order to obtain a better understanding of the cake layer formation mechanism in the flocculants added MBRs, a model was developed on the basis of particle packing model considering cake collapse effect and a frictional force balance equation to predict the porosity and permeability of the cake layers. The important characteristic parameters of the flocs (e.g., floc size, fractal dimensions) and operating parameters of MBRs (e.g., transmembrane pressure, cross-flow velocity) are considered in this model. With this new model, the calculated results of porosities and specific cake resistances under different MBR operational conditions agree fairly well with the experimental data.
Assuntos
Incrustação Biológica , Reatores Biológicos , Filtração/instrumentação , Filtração/métodos , Membranas Artificiais , Simulação por Computador , Floculação , Fractais , Modelos Químicos , Permeabilidade , Porosidade , Propriedades de SuperfícieRESUMO
The ability of simultaneous phosphorus and nitrogen removal of sequencing batch membrane bioreactor run in anaerobic/oxic/ anoxic mode (AOA MBR) was examined under three aeration intensities [2.5, 3.75 and 5.0 m3 x (m2 x h)(-10]. The results showed that the averaged removals of COD were over 90% at different aeration intensities. And the higher aeration intensity was, the more ammonia nitrogen removal rate achieved. The removal rates of NH4(+) under the three aeration intensities were 84.7%, 90.6% and 93.8%, respectively. Total nitrogen removal rate increased with the increasing aeration intensity. But excessive aeration intensity reduced TN removal. The removal rates of TN under the three aeration intensities were 83.4%, 87.4% and 80.6%, respectively. Aeration intensity affected the denitrifying phosphorus ability of the AOA MBR. The ratio of denitrification phosphorus removal under the three aeration intensities were 20%, 30.2% and 26.7%, respectively.
Assuntos
Reatores Biológicos , Nitrogênio/isolamento & purificação , Oxigênio/química , Fósforo/isolamento & purificação , Eliminação de Resíduos Líquidos/métodos , Desnitrificação , Membranas Artificiais , Nitrogênio/metabolismo , Oxirredução , Fósforo/metabolismo , Águas Residuárias/químicaRESUMO
To prepare a high flux and antifouling filtration membrane used for submerged membrane bioreactors, non-woven fabric (NWF) was modified by coating chitosan (CS) on both internal and outer surface. Chemical structural and morphological changes were characterized. The changes of surface free energy were monitored by dynamic contact angle, which showed an increase after modification. The CS/NWF composite membranes were found to be with high flux, high effluent quality and excellent antifouling property. The results of fouling resistance distribution indicated that irreversible fouling resistance was decreased by coating CS. Especially, there were fewer gel layers existing on the outer surface. The adsorption of EPS on the NWF membrane internal surface decreased after being coated with CS. Modification improved filtration performance, and made fouling less troublesome and membrane regeneration efficient.
Assuntos
Reatores Biológicos , Quitosana/química , Membranas Artificiais , Adsorção , Animais , Biotecnologia/métodos , Bovinos , Filtração , Permeabilidade , Polímeros/química , Proteínas/química , Propriedades de SuperfícieRESUMO
To alleviate membrane fouling and reduce the price of membrane module, polyvinyl alcohol microsphere pre-coated dynamic membranes (PVA-MS/PCDMs) were investigated detailedly. It was prepared when the polyvinyl alcohol microsphere of the pre-coated reagent deposited on the surface and entered the pores of porous substrate common filter cloth which was low-cost by means of circulatory filtration. The morphology and structure of PVA-MS/PCDMs were examined using scanning electron microscope (SEM), and approximate maximal separated aperture, water contact angle, pure water permeation resistance and relative Zeta potential of the membrance surface were also determined. The results showed that pure water permeation resistance of PVA-MS/PCDMs was between 0.64 x 10(10) m(-1) and 3.84 x 10(10) m(-1) and the approximate maximal separated aperture reached microfiltration level. The hydrophilicity of PVA-MS/PCDMs increased with increasing PVA-MS pre-coated mass. The relative Zeta potential of the PVA-MS/PCDMs, which were measured using 0.01 mol x L(-1) KCl solution, pH 8.0 +/- 0.2 and at 20 degrees C, reached a peak value of -36.4 mV with pre-coated mass of 15.7 g x m(-2) PVA-MS on the membrance surface. In addition, evolutions of PVA-MS/PCDMs flux versus time were investigated using a 4 hours short-term filtration experiment at 9.5 kPa in an SMBR and the permeability coefficient of PVA-MS/PCDMs were measured by the extracellular polymeric substances (EPS) diffusion experiments. Results indicated that the PVA-MS/PCDMs presented dramatically high anti-fouling characteristics when the pre-coated mass of PVA-MS was 23.9-61.9 g x m(-2).
Assuntos
Reatores Biológicos , Membranas Artificiais , Microesferas , Álcool de Polivinil/química , Eliminação de Resíduos Líquidos/instrumentação , Propriedades de Superfície , Eliminação de Resíduos Líquidos/métodosRESUMO
Biological nutrient removal was investigated in a combined modified University of Cape Town and membrane bioreactor system. When the influent nutrient mass ratio (COD/TN/TP) was 28.5/5.1/1 to 28.5/7.2/1, average removal efficiencies of COD, TN and TP were 90%, 81.6%, 75.2%. Obvious denitrifying phosphorus removal occurred with C/N ratio 3.98. When nitrite was the main electron acceptor, the ratio of denitrifying phosphate uptake to the total phosphate uptake were 99.8% and the sludge yield was 0.28kg VSS/kg COD; when nitrate was the main electron acceptor, the ratio was 92% and the yield was 0.32kg VSS/kg COD. In case of nitrite, the system not only kept TP and TN removal at 89.1% and 82.2%, but also ensured less sludge production. Batch tests showed that the proportion of denitrifying phosphorus-accumulating organisms in the total phosphorus-accumulating organisms in the system was higher than 80%.