RESUMO
Cellulose as the most abundant biopolymers on Earth, presents appealing performance in mechanical properties, thermal management, and versatile functionalization. Developing fabrication methods to design functional materials and open new application areas. However, cellulose is hard to be dissolved or melt due to its recalcitrant property. Herein, the recent progress of fabricating cellulose is summarized. First, the unique hierarchical structure of cellulose is fully investigated and the resulted processability is analysed in directions of down to nanocellulose, dissolution, and thermoplastic processing. Then, the reported fabrication methods are summarized in three aspects: (1) self-assembly from nano/micro cellulose suspensions, especially the formation of cellulose nanocrystals; (2) dissolution-regeneration-drying, covering spinning and solvent infusion processing; and (3) thermoplastic processing, focusing on the setup and the morphology changes of the prepared products. In each aspect, the flowchart of the fabrication method, the mechanism, fabricated products, and effects of processing parameters are explored. Finally, this review provides a perspective on the further direction of fabricating cellulose, especially the challenges toward mass production.
Assuntos
Celulose , Nanopartículas , Celulose/química , Nanopartículas/química , Solventes , SuspensõesRESUMO
The formation of optical products using the traditional molten processing methods is a direct and extensive application of optical fields, and it suffers from intrinsic birefringence and optical distortion due to polymer orientation and residual stress. Here, a unique concept is proposed by assembling photonic crystal nanospheres without orientation in a rubbery state to realize transparent optical devices with zero-birefringence and high transparency. By developing fabrication techniques for transparent zero-birefringence optical devices, certain outstanding performances are realized, including no optical distortion and excellent mechanical properties. Simultaneously, by controlling the particle size of the photonic crystal, one has successfully obtained transparent optical devices with the visible light selective transmission are successfully obtained. The transparent zero-birefringence optical devices are promising candidates for potential applications for fine optical devices. The work opens up an exciting new fabrication route for zero-birefringence and highly transparent polymer devices that have been difficult to create using traditional methods.
Assuntos
Dispositivos Ópticos , Polímeros , Birrefringência , Óptica e Fotônica , FótonsRESUMO
Magnetic levitation (MagLev) is a promising technology for density-based analysis and manipulation of diamagnetic objects of various physical forms. However, one major drawback is that MagLev can be performed only along the central axis (one-dimensional MagLev), thereby leading to (i) no knowledge about the magnetic field in regions other than the axial region, (ii) inability to handle objects of similar densities, because they are aggregated in the axial region, and (iii) objects that can be manipulated (e.g., separated or assembled) in only one single direction, that is, the axial direction. This work explores a novel approach called "axial-circular MagLev" to expand the operational space from one dimension to three dimensions, enabling substances to be stably levitated in both the axial and circular regions. Without noticeably sacrificing the total density measurement range, the highest sensitivity of the axial-circular MagLev device can be adjusted up to 1.5 × 104 mm/(g/cm3), approximately 115× better than that of the standard MagLev of two square magnets. Being able to fully utilize the operational space gives this approach greater maneuverability, as the three-dimensional self-assembly of controllable ring-shaped structures is demonstrated. Full space utilization extends the applicability of MagLev to bioengineering, pharmaceuticals, and advanced manufacturing.
Assuntos
Formaldeído/análise , Polímeros/análise , Polímeros/química , Vidro/análise , Campos MagnéticosRESUMO
In this study, we report the controllable structural transformation of block copolymer/homopolymer binary blends in cylindrical nanopores. Polystyrene-b-poly(4-vinylpyridine)/homopolystyrene (SVP/hPS) nanorods (NRs) can be fabricated by pouring the polymers into an anodic aluminum oxide (AAO) channel and isolated by selective removal of the AAO membrane. In this two-dimensional (2D) confinement, SVP self-assembles into NRs with concentric lamellar structure, and the internal structure can be tailored with the addition of hPS. We show that the weight fraction and molecular weight of hPS and the diameter of the channels can significantly affect the internal structure of the NRs. Moreover, mesoporous materials with tunable pore shape, size, and packing style can be prepared by selective solvent swelling of the structured NRs. In addition, these NRs can transform into spherical structures through solvent-absorption annealing, triggering the conversion from 2D to 3D confinement. More importantly, the transformation dynamics can be tuned by varying the preference property of surfactant to the polymers. It is proven that the shape and internal structure of the polymer particles are dominated by the interfacial interactions governed by the surfactants.
Assuntos
Óxido de Alumínio/química , Nanotubos , Poliestirenos/química , Polivinil/química , Piridinas/química , Cetrimônio , Compostos de Cetrimônio/química , Microscopia Eletrônica de Transmissão , Peso Molecular , Nanoporos/ultraestrutura , Nanotubos/química , Nanotubos/ultraestrutura , Álcool de Polivinil/química , Porosidade , Propriedades de Superfície , Tensoativos/químicaRESUMO
Constrained by the existing scaffold inability to mimic limbal niche, limbal bio-engineered tissue constructed in vitro is challenging to be widely used in clinical practice. Here, a 3D nanofiber-aerogel scaffold is fabricated by employing thermal cross-linking electrospinned film polycaprolactone (PCL) and gelatin (GEL) as the precursor. Benefiting from the cross-linked (160 °C, vacuum) structure, the homogenized and lyophilized 3D nanofiber-aerogel scaffold with preferable mechanical strength is capable of refraining the volume collapse in humid vitro. Intriguingly, compared with traditional electrospinning scaffolds, the authors' 3D nanofiber-aerogel scaffolds possess enhanced water absorption (1100-1300%), controllable aperture (50-100 µm), and excellent biocompatibility (optical density value, 0.953 ± 0.021). The well-matched aperture and nanostructure of the scaffolds with cells enable the construction of limbal bio-engineered tissue. It is foreseen that the proposed general method can be extended to various aerogels, providing new opportunities for the development of novel limbal bio-engineered tissue.
Assuntos
Nanofibras , Gelatina , Nanofibras/química , Poliésteres/química , Engenharia Tecidual/métodos , Alicerces Teciduais/químicaRESUMO
Today's widely used and rapidly updated electronic substrates are composed of petroleum-based polymers, but the resulting electronic waste (such as Dioxin, oxole, PCBs, etc.) will cause massive harm to the environment and human body. Therefore, we report an effective approach for fabricating recyclable and high-performance cellulose films as green electronic substrates by calendering. The crosslinking between CH and CHCH in cellulose modified by maleic anhydride led to the in-situ formation of a chemical crosslinking network, and hydrogen bonds acted as a sacrificial physical crosslinking network. The dual crosslinked cellulose film exhibits high strength (120.56 MPa), improved elongation (increased by 263%), and outstanding thermal stability (thermal decomposition temperature is 311 °C). Further, the film has been successfully used as a substrate for biomass sensor and realized apparent responses to changes. The scientific strategy paves the way for the large-scale fabrication of high-performance cellulose films and simultaneously promotes green electronic substrates' industrialization.
Assuntos
Celulose/química , Eletrônica , Anidridos Maleicos/química , Técnicas Biossensoriais , Química Verde/métodos , Humanos , Ligação de Hidrogênio , Microscopia Eletroquímica de Varredura/métodos , Polímeros/química , Temperatura , Resistência à Tração , Difração de Raios X/métodosRESUMO
Restricted by the difficulty in fabricating scaffolds suitable for cell proliferation, the use of ex vivo expanded limbal stem cell (LSC) for LSC transplantation, an effective treatment method for patients with limb stem cell deficiency (LSCD), is hard to be widely used in clinical practice. To tackle these challenges, a novel electrospun polycaprolactone (PCL)/gelatin nanocomposite is proposed to make 3D scaffolds for limbal niche cells (LNC) proliferation in vitro, which is a milestone in the treatment of diseases such as LSCD. PCL and gelatin in different weight ratios are dissolved in a mixed solvent, and then electrospinning and cross-linking are performed to prepare a scaffold for cell proliferation. The characterizations of the nanocomposites indicate that the gelatin content has a significant effect on its micro-morphology, thermal properties, crystallinity, degradation temperature, hydrophilicity, and mechanical properties. P8G2-C (PCL: gelatin = 80: 20, cross-linked), with smooth fibers and homogeneous pores, has better hydrophilicity, mechanical properties, and flexibility, so it can support LNC as cell proliferation assays revealed. This detailed investigation presented here demonstrates the feasibility of using PCL/gelatin nanocomposites electrospun fiber membranes as a limbus tissue engineering scaffold, which undoubtedly provide a new perspective for the development of tissue engineering field.
Assuntos
Gelatina/farmacologia , Limbo da Córnea/fisiologia , Nanocompostos/química , Poliésteres/farmacologia , Alicerces Teciduais/química , Varredura Diferencial de Calorimetria , Proliferação de Células , Humanos , Células-Tronco/citologiaRESUMO
Cellulose limited by fusibility and solubility is impossible to be directly thermoformed, of which the existing progress crucially relies on larger liquids, making it hard to achieve a direct all-green manufacture. Here, we propose an innovative strategy that the surface molecular chains of cellulose nanospheres are activated at 100 °C and intertwined under 500 MPa because of the high molecular activity on the surface of nanospheres and the reduction of activation energy after ball-milling. It is confirmed that only physical changes are involved, according to infrared spectrum. Results show that applicable mechanical properties (hardness and modulus reach 0.44 and 9.66 GPa, respectively) are successfully obtained. Simultaneously, the optimum optical performance of all-cellulose substrate reaches more than 80 % at visible light. Combined with their intrinsic properties, these cellulose-based products could be potentially utilized as biomass substrates. Therefore, our innovative strategy opens up a door for the direct thermoforming of cellulose.