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A Four-Armed Unsymmetrical Cryptand: From Two Different Host-Guest Interactions to Responsive Supramolecular Polymer.
Yao, Chenhao; Zhang, Jing; Cheng, Ming; Sun, Qiang; Pan, Yi; Jiang, Juli; Wang, Leyong.
Afiliação
  • Yao C; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Zhang J; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Cheng M; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Sun Q; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Pan Y; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Jiang J; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Wang L; Institute for Natural & Synthetic Organic Chemistry, Changzhou University, Changzhou, 213164, China.
Macromol Rapid Commun ; 39(1)2018 Jan.
Article em En | MEDLINE | ID: mdl-28759133
ABSTRACT
By linking BMP32C10 and DB24C8 motifs together, a four-armed cryptand 1 is synthesized successfully, in which BMP32C10 motif can bind paraquat 2 while DB24C8 motif can complex dibenzylammonium salt 3 in spite of the electrostatic repulsion between guests 2 and 3. The base/acid-responsive supramolecular polymer is constructed further via two kinds of host-guest interactions between cryptand 1 and two homoditopic paraquat 4 and dibenzylammonium salt 5 similar to guests 2 and 3.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros Idioma: En Revista: Macromol Rapid Commun Ano de publicação: 2018 Tipo de documento: Article País de afiliação: China
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros Idioma: En Revista: Macromol Rapid Commun Ano de publicação: 2018 Tipo de documento: Article País de afiliação: China