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Luminescent Rhenium(I)-Polypyridine Complexes Appended with a Perylene Diimide or Benzoperylene Monoimide Moiety: Photophysics, Intracellular Sensing, and Photocytotoxic Activity.

Yip, Alex Man-Hei; Shum, Justin; Liu, Hua-Wei; Zhou, Huipeng; Jia, Meiqi; Niu, Niu; Li, Yongxin; Yu, Cong; Lo, Kenneth Kam-Wing.
Chemistry; 25(38): 8970-8974, 2019 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-30901122
This communication reports novel luminescent rhenium(I)-polypyridine complexes appended with a perylene diimide (PDI) or benzoperylene monoimide (BPMI) moiety through a non-conjugated linker. The photophysical and photochemical properties originating from the interactions of the metal polypyridine and perylene units were exploited to afford new cellular reagents with thiol-sensing capability and excellent photocytotoxic activity.