RESUMEN
This study was undertaken to investigate the long-term performance of hydroxyapatite (HAP) as reactive material for the removal of uranium in passive groundwater remediation systems. 237U used as a radioindicator enabled tracking the movement of the contamination front through a test column without taking samples or dismantling the apparatus. The stoichiometric ratio between uranium and HAP was found to be 1:(487 +/- 19). Uranium removal by HAP is of pseudo first-order kinetics and the rate constant was measured to be (1.1 +/- 0.1) x 10(-3) s(-1). HAP can sorb more than 2900 mg/kg uranium. Possible reaction pathways of uranium and HAP are discussed. The data obtained enable the calculation of ideal lifetime for permeable reactive barriers (PRB) using HAP for uranium removal neglecting hydrological factors that may impair the function of PRBs.
RESUMEN
Extremely acidic and saline groundwater occurs naturally in south-western Australia. Discharge of this water to surface waters has increased following extensive clearing of native vegetation for agriculture and is likely to have negative environmental impacts. The use of passive treatment systems to manage the acidic discharge and its impacts is complicated by the region's semi-arid climate with hot dry summers and resulting periods of no flow. This study evaluates the performance of a pilot-scale compost bioreactor treating extremely acidic and saline drainage under semi-arid climatic conditions over a period of 2.5 years. The bioreactor's substrate consisted of municipal waste organics (MWO) mixed with 10 wt% recycled limestone. After the start-up phase the compost bioreactor raised the pH from ≤3.7 to ≥7 and produced net alkaline outflow for 126 days. The bioreactor removed up to 28 g/m(2)/d CaCO3 equivalent of acidity and acidity removal was found to be load dependent during the first and third year. Extended drying over summer combined with high salinity caused the formation of a salt-clay surface layer on top of the substrate, which was both beneficial and detrimental for bioreactor performance. The surface layer prevented the dehydration of the substrate and ensured it remained waterlogged when the water level in the bioreactor fell below the substrate surface in summer. However, when flow resumed the salt-clay layer acted as a barrier between the water and substrate decreasing performance efficiency. Performance increased again when the surface layer was broken up indicating that the negative climatic impacts can be managed. Based on substrate analysis after 1.5 years of operation, limestone dissolution was found to be the dominant acidity removal process contributing up to 78-91% of alkalinity generation, while bacterial sulfate reduction produced at least 9-22% of the total alkalinity. The substrate might last up to five years before the limestone is exhausted and would need to be replenished. The MWO substrate was found to release metals (Zn, Cu, Pb, Ni and Cr) and cannot be recommended for use in passive treatment systems unless the risk of metal release is addressed.