Sub-Ocean: Subsea Dissolved Methane Measurements Using an Embedded Laser Spectrometer Technology.

We present a novel instrument, the Sub-Ocean probe, allowing in situ and continuous measurements of dissolved methane in seawater. It relies on an optical feedback cavity enhanced absorption technique designed for trace gas measurements and coupled to a patent-pending sample extraction method. The considerable advantage of the instrument compared with existing ones lies in its fast response time of the order of 30 s, that makes this probe ideal for fast and continuous 3D-mapping of dissolved methane in water. It could work up to 40 MPa of external pressure, and it provides a large dynamic range, from subnmol of CH4 per liter of seawater to mmol L-1. In this work, we present laboratory calibration of the instrument, intercomparison with standard method and field results on methane detection. The good agreement with the headspace equilibration technique followed by gas-chromatography analysis supports the utility and accuracy of the instrument. A continuous 620-m depth vertical profile in the Mediterranean Sea was obtained within only 10 min, and it indicates background dissolved CH4 values between 1 and 2 nmol L-1 below the pycnocline, similar to previous observations conducted in different ocean settings. It also reveals a methane maximum at around 6 m of depth, that may reflect local production from bacterial transformation of dissolved organic matter.

IAOOS microlidar-on-buoy development and first atmospheric observations obtained during 2014 and 2015 arctic drifts.

The in situ tests of first ever autonomous aerosol and cloud backscatter LIDAR (light detection and ranging) systems implemented on buoys for Arctic observations has been achieved in 2015 within the French EQUIPEX IAOOS project. The environmental and operational constraints were met by adopting a concept of a fibered microjoule lidar system using a laser diode. Two systems have been developed with and without polarization analysis capability. A specific optical design was used for polarization discrimination. These systems were integrated in buoys and tested in the Arctic in 2014 and 2015 at latitudes higher than 80°N. Data were transmitted through an Iridium space link. Measurements have been obtained 90% of the time from the non-polarized system in 2014 over 8 months as the first fully equipped buoy drifted from the Barneo Russian camp close to the North Pole toward Svalbard. A polarized system was then tested over a short period in winter 2015 north of Svalbard during the Norwegian campaign N-ICE. In April and May 2014, the unattended lidar measurements showed a large occurrence of aerosols and haze. The average attenuated scattering ratio for non-cloudy profiles during this period was about 2.2. Aerosols could reach an altitude of 5km on average, whereas over the rest of the period low level clouds (below 1000 m) were prevailing with an average attenuated scattering ratio of about 103. The main features of the developed lidar instruments and first results are presented here.