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Cellulose is the most abundant biopolymer on Earth, found in trees, waste from agricultural crops and other biomass. The fibres that comprise cellulose can be broken down into building blocks, known as fibrillated cellulose, of varying, controllable dimensions that extend to the nanoscale. Fibrillated cellulose is harvested from renewable resources, so its sustainability potential combined with its other functional properties (mechanical, optical, thermal and fluidic, for example) gives this nanomaterial unique technological appeal. Here we explore the use of fibrillated cellulose in the fabrication of materials ranging from composites and macrofibres, to thin films, porous membranes and gels. We discuss research directions for the practical exploitation of these structures and the remaining challenges to overcome before fibrillated cellulose materials can reach their full potential. Finally, we highlight some key issues towards successful manufacturing scale-up of this family of materials.
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Biotecnología/métodos , Biotecnología/tendencias , Celulosa/química , Nanoestructuras/química , Desarrollo Sostenible/tendencias , Materiales Biocompatibles/química , Geles/química , Humanos , PorosidadRESUMEN
Ionic conductors (ICs) find widespread applications across different fields, such as smart electronic, ionotronic, sensor, biomedical, and energy harvesting/storage devices, and largely determine the function and performance of these devices. In the pursuit of developing ICs required for better performing and sustainable devices, cellulose appears as an attractive and promising building block due to its high abundance, renewability, striking mechanical strength, and other functional features. In this review, we provide a comprehensive summary regarding ICs fabricated from cellulose and cellulose-derived materials in terms of fundamental structural features of cellulose, the materials design and fabrication techniques for engineering, main properties and characterization, and diverse applications. Next, the potential of cellulose-based ICs to relieve the increasing concern about electronic waste within the frame of circularity and environmental sustainability and the future directions to be explored for advancing this field are discussed. Overall, we hope this review can provide a comprehensive summary and unique perspectives on the design and application of advanced cellulose-based ICs and thereby encourage the utilization of cellulosic materials toward sustainable devices.
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Rechargeable batteries, typically represented by lithium-ion batteries, have taken a huge leap in energy density over the last two decades. However, they still face material/chemical challenges in ensuring safety and long service life at temperatures beyond the optimum range, primarily due to the chemical/electrochemical instabilities of conventional liquid electrolytes against aggressive electrode reactions and temperature variation. In this regard, a gel polymer electrolyte (GPE) with its liquid components immobilized and stabilized by a solid matrix, capable of retaining almost all the advantageous natures of the liquid electrolytes and circumventing the interfacial issues that exist in the all-solid-state electrolytes, is of great significance to realize rechargeable batteries with extended working temperature range. We begin this review with the main challenges faced in the development of GPEs, based on extensive literature research and our practical experience. Then, a significant section is dedicated to the requirements and design principles of GPEs for wide-temperature applications, with special attention paid to the feasibility, cost, and environmental impact. Next, the research progress of GPEs is thoroughly reviewed according to the strategies applied. In the end, we outline some prospects of GPEs related to innovations in material sciences, advanced characterizations, artificial intelligence, and environmental impact analysis, hoping to spark new research activities that ultimately bring us a step closer to realizing wide-temperature rechargeable batteries.
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Food safety is vital to human health, necessitating the development of nondestructive, convenient, and highly sensitive methods for detecting harmful substances. This study integrates cellulose dissolution, aligned regeneration, in situ nanoparticle synthesis, and structural reconstitution to create flexible, transparent, customizable, and nanowrinkled cellulose/Ag nanoparticle membranes (NWCM-Ag). These three-dimensional nanowrinkled structures considerably improve the spatial-electromagnetic-coupling effect of metal nanoparticles on the membrane surface, providing a 2.3 × 108 enhancement factor for the surface-enhanced Raman scattering (SERS) effect for trace detection of pesticides in foods. Notably, the distribution of pesticides in the apple peel and pulp layers is visualized through Raman imaging, confirming that the pesticides penetrate the peel layer into the pulp layer (â¼30 µm depth). Thus, the risk of pesticide ingestion from fruits cannot be avoided by simple washing other than peeling. This study provides a new idea for designing nanowrinkled structures and broadening cellulose utilization in food safety.
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Inert inorganic nano-building blocks, such as carbon nanotubes (CNTs) and boron nitride (BN) nanosheets, possess excellent physicochemical properties. However, it remains challenging to build aerogels with these inert nanomaterials unless they are chemically modified or compounded with petrochemical polymers, which affects their intrinsic properties and is usually not environmentally friendly. Here, a universal biomacromolecule-enabled assembly strategy is proposed to construct aerogels with 90 wt% ultrahigh inorganic loading. The super-high inorganic content is beneficial for exploiting the inherent properties of inert nanomaterials in multifunctional applications. Taking chitosan-CNTs aerogel as a proof-of-concept demonstration, it delivers sensitive pressure response as a pressure sensor, an ultrahigh sunlight absorption (94.5%) raising temperature under light (from 25 to 71 °C within 1 min) for clean-up of crude oil spills, and superior electromagnetic interference shielding performance of up to 68.9 dB. This strategy paves the way for the multifunctional application of inert nanomaterials by constructing aerogels with ultrahigh inorganic loading.
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Synthetic structural materials with exceptional mechanical performance suffer from either large weight and adverse environmental impact (for example, steels and alloys) or complex manufacturing processes and thus high cost (for example, polymer-based and biomimetic composites). Natural wood is a low-cost and abundant material and has been used for millennia as a structural material for building and furniture construction. However, the mechanical performance of natural wood (its strength and toughness) is unsatisfactory for many advanced engineering structures and applications. Pre-treatment with steam, heat, ammonia or cold rolling followed by densification has led to the enhanced mechanical performance of natural wood. However, the existing methods result in incomplete densification and lack dimensional stability, particularly in response to humid environments, and wood treated in these ways can expand and weaken. Here we report a simple and effective strategy to transform bulk natural wood directly into a high-performance structural material with a more than tenfold increase in strength, toughness and ballistic resistance and with greater dimensional stability. Our two-step process involves the partial removal of lignin and hemicellulose from the natural wood via a boiling process in an aqueous mixture of NaOH and Na2SO3 followed by hot-pressing, leading to the total collapse of cell walls and the complete densification of the natural wood with highly aligned cellulose nanofibres. This strategy is shown to be universally effective for various species of wood. Our processed wood has a specific strength higher than that of most structural metals and alloys, making it a low-cost, high-performance, lightweight alternative.
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Madera/química , Aleaciones/química , Pared Celular/química , Celulosa/química , Calor , Lignina/química , Lignina/aislamiento & purificación , Metales/química , Peso Molecular , Polisacáridos/química , Polisacáridos/aislamiento & purificación , Hidróxido de Sodio/química , Sulfitos/química , Resistencia a la Tracción , Madera/clasificaciónRESUMEN
Conventional plastic foams are usually produced by fossil-fuel-derived polymers, which are difficult to degrade in nature. As an alternative, cellulose is a promising biodegradable polymer that can be used to fabricate greener foams, yet such a process typically relies on methods (e.g., freeze-drying and supercritical-drying) that are hardly scalable and time-consuming. Here, we develop a fast and scalable approach to prepare cellulose-graphite foams via rapidly cross-linking the cellulose fibrils in metal ions-containing solution followed by ambient drying. The prepared foams exhibit low density, high compressive strength, and excellent water stability. Moreover, the cross-linking of the cellulose fibrils can be triggered by various metal ions, indicating good universality. We further use density functional theory to reveal the cross-linking effect of different ions, which shows good agreement with our experimental observation. Our approach presents a sustainable route toward low-cost, environmentally friendly, and scalable foam production for a range of applications.
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Celulosa , Grafito , Iones , Polímeros , AguaRESUMEN
Solar desalination has been recognized as an emerging strategy for solving the pressing global freshwater crisis. However, salt crystallization at the photothermal interface frequently causes evaporator failure. In addition, arbitrary discharge of concentrated brine produced during desalination results in potential ecological impacts as well as wastage of valuable minerals. In the present work, a suspended-type evaporator (STEs) constructed using Janus fibrous mats is reported. The fibrous structure wicks brine to the evaporation layer and the salt gets confined in the evaporation layer until crystallization for zero liquid discharge due to the suspended design. Enhanced evaporation is observed because STEs have an additional low-resistance vapor escape path directly from the evaporation layer to the atmosphere compared to traditional floating Janus evaporators. Moreover, owing to the drastically different wettability on both sides, the evaporator allows salt crystallization only on the hydrophilic bottom layer, thus eliminating salt accumulation at the hydrophobic photothermal interface. With this unique structural design, the proposed evaporator not only maintains a high evaporation rate of 1.94 kg m-2 h-1 , but also demonstrates zero liquid discharged salt resistance and ideal recovery of the mineral in brine.
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Purificación del Agua , Interacciones Hidrofóbicas e Hidrofílicas , Cloruro de Sodio , Luz SolarRESUMEN
The conventional thermal treatment systems typically feature low ramping/cooling rates, which lead to steep thermal gradients that generate inefficient, nonuniform reaction conditions and result in nanoparticle aggregation. Herein, we demonstrate a continuous fly-through material synthesis approach using a novel high-temperature reactor design based on the emerging thermal-shock technology. By facing two sheets of carbon paper with a small distance apart (1-3 mm), uniform and ultrahigh temperatures can be reached up to 3200 K within 50 ms by simply applying a voltage of 15 V. The raw materials can be continuously fed through the device, allowing the final products to be rapidly collected. As a proof-of-concept demonstration, we synthesized Pt nanocatalysts (â¼4 nm) anchored on carbon black via this reactor at â¼1400 K. Furthermore, we find it features excellent electrocatalytic activities toward methanol oxidation reaction. This work offers a highly efficient platform for nanomaterials synthesis at high temperatures.
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The combination of good stability, biocompatibility, and high mechanical strength is attractive for bio-related material applications, but it remains challenging to simultaneously achieve these properties in a single, ionically conductive material. Here a "wood" ionic cable, made of aligned wood nanofibrils, demonstrating a combination of biocompatibility, high mechanical strength, high ionic conductivity, and excellent stability is reported. The wood ionic cable possesses excellent flexibility and exhibits high tensile strength up to 260 MPa (in the dry state) and ≈80 MPa (in the wet state). The nanochannels within the highly aligned cellulose nanofibrils and the presence of negative charges on the surfaces of these nanochannels, originating from the cellulose hydroxyl groups, provide new opportunities for ion regulation at low salt concentrations. Ion regulation in turn enables the wood ionic cable to have unique nanofluidic ionic behaviors. The Na+ ion conductivity of the wood ionic cable can reach up to ≈1.5 × 10-4 S cm-1 at low Na+ ion concentration (1.0 × 10-5 mol L-1 ), which is an order of magnitude higher than that of bulk NaCl solution at the same concentration. The scalable, biocompatible wood ionic cable enables novel ionic device designs for potential ion-regulation applications.
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Celulosa , Madera , Hidrogeles , Iones , Resistencia a la TracciónRESUMEN
High temperature synthesis and treatments are ubiquitous in chemical reactions and material manufacturing. However, conventional sintering furnaces are bulky and inefficient with a narrow temperature range (<1500 K) and slow heating rates (<100 K min-1 ), which are undesirable for many applications that require transient heating to produce ideal nanostructures. Herein, a 3D-printed, miniaturized reactor featuring a dense micro-grid design is developed to maximize the material contact and therefore acheive highly efficient and controllable heating. By 3D printing, a versatile, miniaturized reactor with microscale features can be constructed, which can reach a much wider temperature range (up to ≈3000 K) with ultrafast heating/cooling rates of ≈104 K s-1 . To demonstrate the utility of the design, rapid and batch synthesis of Ru nanoparticles supported in ordered mesoporous carbon is performed by transient heating (1500 K, 500 ms). The resulting ultrafine and uniform Ru nanoparticles (≈2 nm) can serve as a cathode in Li-CO2 batteries with good cycling stability. The miniaturized reactor, with versatile shape design and highly controllable heating capabilities, provides a platform for nanocatalyst synthesis with localized and ultrafast heating toward high temperatures that is otherwise challenging to achieve.
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Lithium metal anode with the highest capacity and lowest anode potential is extremely attractive to battery technologies, but infinite volume change during the Li stripping/plating process results in cracks and fractures of the solid electrolyte interphase, low Coulombic efficiency, and dendritic growth of Li. Here, we use a carbonized wood (C-wood) as a 3D, highly porous (73% porosity) conductive framework with well-aligned channels as Li host material. We discovered that molten Li metal can infuse into the straight channels of C-wood to form a Li/C-wood electrode after surface treatment. The C-wood channels function as excellent guides in which the Li stripping/plating process can take place and effectively confine the volume change that occurs. Moreover, the local current density can be minimized due to the 3D C-wood framework. Therefore, in symmetric cells, the as-prepared Li/C-wood electrode presents a lower overpotential (90 mV at 3 mAâ cm-2), more-stable stripping/plating profiles, and better cycling performance (â¼150 h at 3 mAâ cm-2) compared with bare Li metal electrode. Our findings may open up a solution for fabricating stable Li metal anode, which further facilitates future application of high-energy-density Li metal batteries.
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The construction of two-dimensional (2D) layered compounds for nanofluidic ion transport has recently attracted increasing interest due to the facile fabrication, tunable channel size, and high flux of these materials. Here we design a nacre-mimetic graphite-based nanofluidic structure in which the nanometer-thick graphite flakes are wrapped by negatively charged nanofibrillated cellulose (NFC) fibers to form multiple 2D confined spacings as nanochannels for rapid cation transport. At the same time, the graphite-NFC structure exhibits an ultralow electrical conductivity (σe ≤ 10-9 S/cm), even when the graphite concentration is up to 50 wt %, well above the percolation threshold (â¼1 wt %). By tuning the hydration degree of graphite-NFC composites, the surface-charge-governed ion transport in the confined â¼1 nm spacings exhibits nearly 12 times higher ionic conductivity (1 × 10-3 S/cm) than that of a fully swollen structure (â¼1.5 nm, 8.5 × 10-5 S/cm) at salt concentrations up to 0.1 M. The resulting charge selective conductor shows intriguing features of both high ionic conductivity and low electrical conductivity. Moreover, the inherent stability of the graphite and NFC components contributes to the strong functionality of the nanofluidic ion conductors in both acidic and basic environments. Our work demonstrates this 1D-2D material hybrid system as a suitable platform to study nanofluidic ion transport and provides a promising strategy to decouple ionic and electronic pathways, which is attractive for applications in new nanofluidic device designs.
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Cellulose is the most abundant biopolymer on Earth and has long been used as a sustainable building block of conventional paper. Note that nanocellulose accounts for nearly 40% of wood's weight and can be extracted using well-developed methods. Due to its appealing mechanical and electrochemical properties, including high specific modulus (â¼100 GPa/(g/cm3)), excellent stability in most solvents, and stability over a wide electrochemical window, nanocellulose has been widely used as a separator, electrolyte, binder, and substrate material for energy storage. Additionally, nanocellulose-derived carbon materials have also drawn increasing scientific interest in sustainable energy storage due to their low-cost and raw-material abundance, high conductivity, and rational electrochemical performance. The inexpensive and environmentally friendly nature of nanocellulose and its derivatives as well as simple fabrication techniques make nanocellulose-based energy storage devices promising candidates for the future of "green" and renewable electronics. For nanocellulose-based energy storage, structure engineering and design play a vital role in achieving desired electrochemical properties and performances. Thus, it is important to identify suitable structure and design engineering strategies and to better understand their relationship. In this Account, we review recent developments in nanocellulose-based energy storage. Due to the limited space, we will mainly focus on structure design and engineering strategies in macrofiber, paper, and three-dimensional (3D) structured electrochemical energy storage (EES) devices and highlight progress made in our group. We first present the structure and properties of nanocellulose, with a particular discussion of nanocellulose from wood materials. We then go on to discuss studies on nanocellulose-based macrofiber, paper, and 3D wood- and other aerogel-based EES devices. Within this discussion, we highlight the use of natural nanocellulose as a flexible substrate for a macrofiber supercapacitor and an excellent electrolyte reservoir for a breathable textile lithium-oxygen battery. Paper batteries and supercapacitors using nanocellulose as a green dispersant, nanocellulose-based paper as a flexible substrate, and nanocellulose as separator and electrolyte are also examined. We highlight recent progress on wood-based batteries and supercapacitors, focusing on the advantages of wood materials for energy storage, the structure design and engineering strategies, and their microstructure and electrochemical properties. We discuss the influence of structure (particularly pores) on the electrochemical performance of the energy storage devices. By taking advantage of the straight, nature-made channels in wood materials, ultrathick, highly loaded, and low-tortuosity energy storage devices are demonstrated. Finally, we offer concluding remarks on the challenges and directions of future research in the field of nanocellulose-based energy storage devices.
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Solid-state electrolytes (SSEs) have been widely considered as enabling materials for the practical application of lithium metal anodes. However, many problems inhibit the widespread application of solid state batteries, including the growth of lithium dendrites, high interfacial resistance, and the inability to operate at high current density. In this study, we report a three-dimensional (3D) mixed electron/ion conducting framework (3D-MCF) based on a porous-dense-porous trilayer garnet electrolyte structure created via tape casting to facilitate the use of a 3D solid state lithium metal anode. The 3D-MCF was achieved by a conformal coating of carbon nanotubes (CNTs) on the porous garnet structure, creating a composite mixed electron/ion conductor that acts as a 3D host for the lithium metal. The lithium metal was introduced into the 3D-MCF via slow electrochemical deposition, forming a 3D lithium metal anode. The slow lithiation leads to improved contact between the lithium metal anode and garnet electrolyte, resulting in a low resistance of 25 Ω cm2. Additionally, due to the continuous CNT coating and its seamless contact with the garnet we observed highly uniform lithium deposition behavior in the porous garnet structure. With the same local current density, the high surface area of the porous garnet framework leads to a higher overall areal current density for stable lithium deposition. An elevated current density of 1 mA/cm2 based on the geometric area of the cell was demonstrated for continuous lithium cycling in symmetric lithium cells. For battery operation of the trilayer structure, the lithium can be cycled between the 3D-MCF on one side and the cathode infused into the porous structure on the opposite side. The 3D-MCF created by the porous garnet structure and conformal CNT coating provides a promising direction toward new designs in solid-state lithium metal batteries.
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Room-temperature Na ion batteries (NIBs) have attracted great attention because of the widely available, abundant sodium resources and potentially low cost. Currently, the challenge of the NIB development is due primarily to the lack of a high-performance anode, while the Na metal anode holds great promise considering its highest specific capacity of 1165 mA h/g and lowest anodic potential. However, an uneven deposit, relatively infinite volume change, and dendritic growth upon plating/stripping cycles cause a low Coulombic efficiency, poor cycling performance, and severe safety concerns. Here, a stable Na carbonized wood (Na-wood) composite anode was fabricated via a rapid melt infusion (about 5 s) into channels of carbonized wood by capillary action. The channels function as a high-surface-area, conductive, mechanically stable skeleton, which lowers the effective current density, ensures a uniform Na nucleation, and restricts the volume change over cycles. As a result, the Na-wood composite anode exhibited flat plating/stripping profiles with smaller overpotentials and stable cycling performance over 500 h at 1.0 mA/cm2 in a common carbonate electrolyte system. In sharp comparison, the planar Na metal electrode showed a much shorter cycle life of 100 h under the same test conditions.
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For the first time, hierarchically porous carbon materials with a sandwich-like structure are synthesized through a facile and efficient tri-template approach. The hierarchically porous microstructures consist of abundant macropores and numerous micropores embedded into the crosslinked mesoporous walls. As a result, the obtained carbon material with a unique sandwich-like structure has a relatively high specific surface (1235â m2 g-1 ), large pore volume (1.30â cm3 g-1 ), and appropriate pore size distribution. These merits lead to a comparably high specific capacitance of 274.8â F g-1 at 0.2â A g-1 and satisfying rate performance (87.7 % retention from 1 to 20â A g-1 ). More importantly, the symmetric supercapacitor with two identical as-prepared carbon samples shows a superior energy density of 18.47â Wh kg-1 at a power density of 179.9â W kg-1 . The asymmetric supercapacitor based on as-obtained carbon sample and its composite with manganese dioxide (MnO2 ) can reach up to an energy density of 25.93â Wh kg-1 at a power density of 199.9â W kg-1 . Therefore, these unique carbon material open a promising prospect for future development and utilization in the field of energy storage.
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Flexible power sources have shown great promise in next-generation bendable, implantable, and wearable electronic systems. Here, flexible and binder-free electrodes of Na3V2(PO4)3/reduced graphene oxide (NVP/rGO) and Sb/rGO nanocomposites for sodium-ion batteries are reported. The Sb/rGO and NVP/rGO paper electrodes with high flexibility and tailorability can be easily fabricated. Sb and NVP nanoparticles are embedded homogenously in the interconnected framework of rGO nanosheets, which provides structurally stable hosts for Na-ion intercalation and deintercalation. The NVP/rGO paper-like cathode delivers a reversible capacity of 113 mAh g(-1) at 100 mA g(-1) and high capacity retention of ≈96.6% after 120 cycles. The Sb/rGO paper-like anode gives a highly reversible capacity of 612 mAh g(-1) at 100 mA g(-1) , an excellent rate capacity up to 30 C, and a good cycle performance. Moreover, the sodium-ion full cell of NVP/rGO//Sb/rGO has been fabricated, delivering a highly reversible capacity of ≈400 mAh g(-1) at a current density of 100 mA g(-1) after 100 charge/discharge cycles. This work may provide promising electrode candidates for developing next-generation energy-storage devices with high capacity and long cycle life.
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A unique hybrid, TiO2-B nanosheets/anatase nanocrystals co-anchored on nanoporous graphene sheets, can be synthesized by a facile microwave-induced in situ reduction-hydrolysis route. The as-formed nanohybrid has a hierarchically porous structure, involving both mesopores of approximately 4â nm and meso-/macropores of 30-60â nm in the graphene sheets, and a large surface area. Importantly, electrodes composed of the nanohybrid exhibit superior rate capability (160â mA h g(-1) at ca. 36 C; 154â mA h g(-1) at ca. 72 C) and excellent cyclability. The synergistic effects of conductive graphene with numerous nanopores and the pseudocapacitive effect of ultrafine TiO2-B nanosheets and anatase nanocrystals endow the hybrid a superior rate capability.
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Hepatectomy, a surgical procedure for liver cancer, is often plagued by high recurrence rates worldwide. The recurrence of liver cancer is primarily attributed to microlesions in the liver, changes in the immune microenvironment, and circulating tumor cells in the bloodstream. To address this issue, a novel intervention method that combines intraoperative hemostasis with mild photothermal therapy is proposed, which has the potential to ablate microlesions and improve the immune microenvironment simultaneously. Specifically, the integrated strategy is realized based on the fibrous chitosan/polydopamine sponge (CPDS), which is constructed from shearing-flow-induced oriented hybrid chitosan fibers and subsequent self-assembly of polydopamine. The CPDS demonstrates high elasticity, excellent water absorption, and photothermal conversion performance. The results confirm the efficient hemostatic properties of the fibrous CPDS in various bleeding models. Notably, in subcutaneous and orthotopic postoperative recurrence and metastasis models of hepatocellular carcinoma, the fibrous CPDS significantly inhibits local tumor recurrence and distant metastasis. Moreover, the combination with lenvatinib can substantially enhance the antitumor effect. This comprehensive treatment strategy offers new insights into hepatectomy of liver cancer, representing a promising approach for clinical management.