RESUMEN
An alpha-proteobacterial strain JXJ CY 53 T was isolated from the cyanosphere of Microcystis sp. FACHB-905 (MF-905) collected from Lake Dianchi, China. JXJ CY 53 T was observed to be an aerobic, Gram-stain-negative, oval shaped, and mucus-secreting bacterium. It had C18:1ω7c and C16:0 as the major cellular fatty acids, Q-10 as the predominant ubiquinone, and sphingoglycolipid, diphosphatidylglycerol, phosphatidylcholine, and phosphatidylmethylethanolamine as the polar lipids. The G + C content of DNA was 65.85%. The bacterium had 16S rRNA gene sequence identities of 98.9% and 98.7% with Sphingomonas panni DSM 15761 T and Sphingomonas hankookensis KCTC 22579 T, respectively, while less than 97.4% identities with other members of the genus. Further taxonomic analysis indicated that JXJ CY 53 T represented a new member of Sphingomonas, and the species epithet was proposed as Sphingomonas lacusdianchii sp. nov. (type strain JXJ CY 53 T = KCTC 72813 T = CGMCC 1.17657 T). JXJ CY 53 T promoted the growth of MF-905 by providing bio-available phosphorus and nitrogen, plant hormones, vitamins, and carotenoids. It could modulate the relative abundances of nonculturable bacteria associated with MF-905 and influence the interactions of MF-905 and other bacteria isolated from the cyanobacterium, in addition to microcystin production characteristics. Meanwhile, MF-905 could provide JXJ CY 53 T dissolved organic carbon for growth, and control the growth of JXJ CY 53 T by secreting specific chemicals other than microcystins. Overall, these results suggest that the interactions between Microcystis and its attached bacteria are complex and dynamic, and may influence the growth characteristics of the cyanobacterium. This study provided new ideas to understand the interactions between Microcystis and its attached bacteria. KEY POINTS: ⢠A novel bacterium (JXJCY 53 T) was isolated from the cyanosphere of Microcystis sp. FACHB-905 (MF-905) ⢠JXJCY 53 T modulated the growth and microcystin production of MF-905 ⢠MF-905 could control the attached bacteria by specific chemicals other than microcystins (MCs).
Asunto(s)
Composición de Base , ADN Bacteriano , Ácidos Grasos , Filogenia , ARN Ribosómico 16S , Sphingomonas , Sphingomonas/metabolismo , Sphingomonas/genética , Sphingomonas/aislamiento & purificación , Sphingomonas/clasificación , ARN Ribosómico 16S/genética , China , Ácidos Grasos/metabolismo , ADN Bacteriano/genética , Fosfolípidos/análisis , Microcystis/genética , Microcystis/metabolismo , Microcystis/crecimiento & desarrollo , Lagos/microbiología , Análisis de Secuencia de ADN , Técnicas de Tipificación Bacteriana , Simbiosis , UbiquinonaRESUMEN
A novel alphaproteobacterial strain JXJ CY 41T was isolated from a culture mass of Microcystis, collected from Lake Dianchi, south-west, China. Strain JXJ CY 41T was gram-strain-negative, aerobic, motile, with rod-shaped cells (0.4-1.0 × 1.7-3.5 µm). It was positive for catalase and starch hydrolysis, negative for oxidase and hydrolysis of Tweens (20, 40, and 80). Growth occurred at 10-44 °C, pH 5.0-10.0, and 0-5.0% (w/v) NaCl. Major fatty acids included C16:0 (28.1%), 11-methyl C18:1 ω7c (36.7%) and C18:1 ω7c (20.8%). Q10 was the sole ubiquinone. The polar lipids were diphosphatidylglycerol, phosphatidylglycerol, glycolipid, and an unidentified lipid. The DNA G + C content was 63.1%. Its 16S rRNA gene sequence showed high similarities with Devosia oryziradicis G19T (99.5%; not validly published), D. yakushimensis Yak96BT (98.3%) and D. ginsengisoli Gsoil 520T (98.1%), and less than 98.1% similarities with other members of the genus Devosia. The digital DNA-DNA hybridization (dDDH) and average nucleotide identity (ANI) values between strain JXJ CY 41T and its 5 closest similar strains were 19.9-24.1% and 75.7-80.5%, respectively. Based on the data above, strain JXJ CY 41T was identified as a novel species of the genus Devosia, for which the epithet Devosia lacusdianchii sp. nov. was proposed. The type strain is JXJ CY 41T (= KCTC 72812T = CGMCC 1.17502T). Strain JXJ CY 41T exhibited different interactions with Microcystis aeruginosa FACHB-905 (Maf) under different conditions, and Maf could control the bacterial cellular density by secreting unknown specific chemical compounds according to its nutritional requirements.
Asunto(s)
Microcystis , Adolescente , Niño , Humanos , Microcystis/genética , ARN Ribosómico 16S/genética , ADN Bacteriano/genética , Filogenia , Ácidos Grasos/química , Análisis de Secuencia de ADN , Técnicas de Tipificación Bacteriana , Fosfolípidos/químicaRESUMEN
Niobium-based oxides including Nb2 O5 , TiNbx O2+2.5x compounds, M-Nb-O (M = Cr, Ga, Fe, Zr, Mg, etc.) family, etc., as the unique structural merit (e.g., quasi-2D network for Li-ion incorporation, open and stable Wadsley- Roth shear crystal structure), are of great interest for applications in energy storage systems such as Li/Na-ion batteries and hybrid supercapacitors. Most of these Nb-based oxides show high operating voltage (>1.0 V vs Li+ /Li) that can suppress the formation of solid electrolyte interface film and lithium dendrites, ensuring the safety of working batteries. Outstanding rate capability is impressive, which can be derived from their fast intercalation pseudocapacitive kinetics. However, the intrinsic poor electrical conductivity hinders their energy storage applications. Various strategies including structure optimization, surface engineering, and carbon modification are effectively used to overcome the issues. This review provides a comprehensive summary on the latest progress of Nb-based oxides for advanced electrochemical energy storage applications. Major impactful work is outlined, promising research directions, and various performance-optimizing strategies, as well as the energy storage mechanisms investigated by combining theoretical calculations and various electrochemical characterization techniques. In addition, challenges and perspectives for future research and commercial applications are also presented.
RESUMEN
Developing high power-high energy electrochemical energy storage systems is an ultimate goal in the energy storage field, which is even more difficult but significant for low-cost sodium ion batteries. Here, fluoride is successfully prepared by the electrostatic spray deposition (ESD) technique, which greatly expands the application scope of ESD. A two-step strategy (solvothermal plus ESD method) is proposed to construct a bicontinuous ordered network of 3D porous Na3 (VO)2 (PO4 )2 F/reduced graphene oxide (NVOPF/rGO). This two-step strategy makes sure that NVOPF can be prepared by ESD, since it avoids the loss of F element during synthesis. The obtained NVOPF particles are as small as 15 nm, and the carbon content is only 3.5% in the final nanocomposite. Such a bicontinuous ordered network and small size of electroactive particles lead to the significant contribution of the pseudocapacitance effect to sodium storage, resulting in real high power-high energy sodium cathodes. The cathode exhibits excellent rate capability and cycling stability, whose rate performance is one of the best ever reported in both half cells and full cells. Moreover, this work provides a general and promising strategy for developing high power-high energy electrode materials for various electrochemical energy storage systems.
RESUMEN
Due to the intrinsic low electrical conductivity and large volume expansion of the CoFe2O4 based active materials, designing more novel structures is still one of the most important challenges for its lithium ion battery application. In this work, the CoFe2O4/reduced graphene oxide/carbon (CFO/rGO/C) composite with integrated multi-layer structure has been synthesized through a facial two-step hydrothermal method. Benefiting from the introduction of the graphene network and amorphous carbon coating layer, as well as the accompanying synergistic effect, this composite can exhibit fast and reversible lithium intercalation/deintercalation reactions. With the aid of a surface-induced capacitive process, the CFO/rGO/C composite delivers a superior specific capacity (945 mA h g-1 at 0.1 A g-1) and excellent long-term cyclic stability (421 mA h g-1 at 4 A g-1 with closely 100% Coulombic efficiency after 2000 cycles). Significantly, at a high current density of 1 A g-1, the reversible capacity exhibits a rapid increasing after 100 cycles and finally shows an ultra-high-capacity of 1430 mA h g-1 over 500 cycles. This method could be generalized to the preparation of other similar transition metal oxide-based materials for the development of high-performance energy storage systems.
RESUMEN
To overcome inferior rate capability and cycle stability of MnO-based anode materials for lithium-ion batteries (LIBs), we reported a novel 3D porous MnO@GS/CNT composite, consisting of MnO nanoparticles homogeneously distributed on the conductive interconnected framework based on 2D graphene sheets (GS) and 1D carbon nanotubes (CNTs). The distinctive architecture offers highly interpenetrated network along with efficient porous channels for fast electron transfer and ionic diffusion as well as abundant stress buffer space to accommodate the volume expansion of the MnO nanoparticles. The MnO@GS/CNT anode exhibits an ultrahigh capacity of 1115 mAh g-1 at 0.2 A g-1 after 150 cycles and outstanding rate capacity of 306 mAh g-1 at 10.0 A g-1. Moreover, a stable capacity of 405 mAh g-1 after 3200 cycles can still be achieved, even at a large current density of 5.0 A g-1. When coupled with LiMn2O4 (LMO) cathode, the LMO [Formula: see text] MnO@GS/CNT full cell characterizes an excellent cycling stability and rate capability, indicating the promising application of MnO@GS/CNT anode in the next-generation LIBs.
RESUMEN
Orthorhombic Nb2O5 (T-Nb2O5) has structural merit but poor electrical conductivity, limiting their applications in energy storage. Although graphene is frequently adopted to effectively improve its electrochemical properties, the ordinary modified methods cannot meet the growing demands for high-performance. Here, we demonstrate that different graphene modified routes play a vital role in affecting the electrochemical performances of T-Nb2O5. By only manual shaking within one minute, Nb2O5 nano-particles can be rapidly adsorbed onto graphene, then the free-anchored T-Nb2O5@graphene three-dimensional networks can be successfully prepared based on hydrogel method. As for the application in lithium-ion batteries, it performs outstanding rate character (129 mA h g-1 (25C rate), 110 mA h g-1 (50C rate) and 90 mA h g-1 (100C rate), correspond to 79%, 67% and 55% capacity of 0.5C rate, respectively) and excellent long-term cycling feature (â¼70% capacity retention after 20000 cycles). Moreover, it still maintains similar ultrafast-stable lithium storage performances when Cu foil is substituted by Al foil as current collector. In addition, relevant kinetics mechanisms are also expounded. This work provides a versatile strategy for the preparation of graphene modified Nb2O5 or other types of nanoparticles.
RESUMEN
The metal-insulator transition (MIT) is of key importance for understanding the fundamental electronic interaction that determines the physical properties of vanadium dioxide (VO2) film. Here, the spectral slopes of transmittance and reflectance in the infrared absorption region (about 0.62-1.63 eV) and the interband electronic transitions for VO2 films with thicknesses of 27, 40 and 63 nm have been investigated. The potential applications of the spectral slopes were presented in detail. It is found that the variation of resistivity and transmittance increases with the spectral slopes of transmittance and reflectance. It is surprising that the resistivity of the VO2 film with a thickness of 27 nm is larger than that of the VO2 film with a thickness of 40 nm in the metal state. In addition, an anomalous counterclockwise thermal hysteresis with higher energy from the interband electronic transition was also found during the MIT process for the thinnest film. It is believed that this remarkable phenomenon could be related to the correlation effects in the rutile phase, which could lead to the splitting of the a1g band into Hubbard bands. The lower Hubbard band would result in an electronic transition blue-shift with the empty e band, which can explain the origin of the counterclockwise thermal hysteresis and the abnormal resistivity in the metal state.
RESUMEN
Post-annealing has been approved to effectively relax the out-of-plane strain in thin films. Epitaxial EuTiO3 (ETO) thin films, with and without strain, have been fabricated on (001) LaAlO3 substrates by pulsed laser deposition. The absorption and electronic transitions of the ETO thin films are investigated by means of temperature dependent transmittance spectra. The antiferrodistortive phase transition can be found at about 260-280 K. The first-principles calculations indicate there are two interband electronic transitions in ETO films. Remarkably, the direct optical band gap and higher interband transition for ETO films show variation in trends with different strains and temperatures. The strain leads to a band gap shrinkage of about 240 meV while the higher interband transition an expansion of about 140 meV. The hardening of the interband transition energies in ETO films with increasing temperature can be attributed to the Fröhlich electron-phonon interaction. The behavior can be linked to the strain and low temperature modified valence electronic structure, which is associated with rotations of the TiO6 octahedra.
RESUMEN
Sodium-ion batteries (SIBs) have demonstrated remarkable development potential and commercial prospects. However, in the current state of research, the development of high-energy-density, long-cycle-life, high-rate-performance anode materials for SIBs remains a huge challenge. Free-standing flexible electrodes, owing to their ability to achieve higher energy density without the need for current collectors, binders, and conductive additives, have garnered significant attention across various fields. In this work, we designed and fabricated a free-standing three-dimensional flexible Nb2O5@WS2@C carbon nanofiber (CNF) anode based on a hybrid adsorption-intercalation-conversion mechanism of sodium storage, using electrospinning and hydrothermal synthesis processes. The hybrid structure, aided by synergistic effects, releases the advantages of all materials, demonstrating a superior rate performance (288, 248, 211, 158, 90, and 48 mA h g-1 at the current density of 0.2, 0.5, 1, 2, 5, and 10 A g-1, respectively) and good cycling stability (160 mA h g-1 after 200 cycles at 1 A g-1). This work provides certain guiding significance for future research on hybrid and flexible anodes of SIBs.
RESUMEN
Cervical cancer is a significant global health concern, and novel therapeutic strategies are continually being sought to combat this disease. In recent years, selenadiazole found latent therapeutic effects on tumors. Herein, investigating the mechanism of selenadiazole in Hela cells holds promise for advancing cervical cancer treatment. Hela cells, a widely utilized model for studying cervical cancer, were treated with selenadiazole, and cell viability was assessed by using the cell counting kit-8 (CCK-8) assay. Changes in mitochondrial membrane potential were evaluated using JC-1 staining, while apoptosis induction was examined using AnnexinV-PI double staining. Intracellular ROS levels were measured by using specific fluorescent probes and the ELIASA system. Additionally, Western blotting was performed to assess the activation of related proteins in response to selenadiazole. Data analysis was performed using GraphPad. Exposure to selenadiazole led to a substantial increase in intracellular redox oxygen species (ROS) levels in Hela cells. Importantly, the induction of ROS by selenadiazole was associated with a marked increase in mitochondrial apoptosis, as evidenced by elevated levels of AnnexinV-positive cells, the JC-1 monomer, caspase-9, and Bcl-2. Furthermore, activation of the JAK2/STAT3 pathway was observed following the selenadiazole treatment. Selenadiazole holds the potential to suppress tumor growth in cervical cancer cells by increasing reactive oxygen species (ROS) levels and inducing mitochondrial apoptosis via the JAK2/STAT3 pathway. This study offers valuable insights into potential cervical cancer therapies and underscores the need for further research into the specific mechanisms of selenadiazole.
RESUMEN
Harmful algal blooms (HABs) in natural waters are of escalating global concern due to their detrimental impact on environmental health. Emerging evidence indicates that algae-bacteria symbionts can affect HAB features, though much about this interplay remains largely unexplored. The current study isolated a new species of Mucilaginibacter (type strain JXJ CY 39T) from culture biomass of the bloom-causing Microcystis aeruginosa FACHB-905 (Maf) from Lake Dianchi, China. Strain JXJ CY 39T was an aerobic, Gram-stain-negative rod bacterium that grew at 5-38°C, pH 4.0-11.0, and 0-3.0% NaCl. Taxonomic evaluation proposed a new species, with Mucilaginibacter lacusdianchii sp. nov., as the species epithet. Experimental results revealed that strain JXJ CY 39T spurred the growth of Maf by supplying soluble phosphorus and nitrogen during cultivation, despite the unavailability of soluble phosphorus and nitrogen. Additionally, by producing the plant hormone indole-3-acetate, strain JXJ CY 39T possibly impacted Maf's functionality. Results from co-culture experiments with other strains from Maf biomass showed possible effects of strain JXJ CY 39T on the relationship between Maf and other cohabiting bacteria, as well as microcystin toxin production characteristics. Although Maf could foster the growth of strain JXJ CY 39T by supplying organic carbon, the strain's growth could be regulated via specific chemical compounds based on antibiotic assays. Community composition analysis disclosed that this Mucilaginibacter strain positively affected Maf's growth and modified densities and types of bacteria linked to Maf. Overall, these results suggest that the interactions between important HAB-causing organisms and their attached bacteria are complex, dynamic, and may influence the growth characteristics of algae.
RESUMEN
Compared to SnTe and PbTe base materials, the GeTe matrix exhibits a relatively high Seebeck coefficient and power factor but has garnered significant attention due to its poor thermal transport performance and environmental characteristics. As a typical p-type IV-VI group thermoelectric material, W-doped GeTe material can bring additional enhancement to thermoelectric performance. In this study, the introduction of W, Ge1-xWxTe (x = 0, 0.002, 0.005, 0.007, 0.01, 0.03) resulted in the presence of high-valence state atoms, providing additional charge carriers, thereby elevating the material's power factor to a maximum PFpeak of approximately 43 µW cm-1 K-2, while slightly optimizing the Seebeck coefficient of the solid solution. Moreover, W doping can induce defects and promote slight rhombohedral distortion in the crystal structure of GeTe, further reducing the lattice thermal conductivity κlat to as low as approximately 0.14 W m-1 K-1 (x = 0.002 at 673 K), optimizing it to approximately 85% compared to the GeTe matrix. This led to the formation of a p-type multicomponent composite thermoelectric material with ultra-low thermal conductivity. Ultimately, W doping achieves the comprehensive enhancement of the thermoelectric performance of GeTe base materials, with the peak ZT value of sample Ge0.995W0.005Te reaching approximately 0.99 at 673 K, and the average ZT optimized to 0.76 in the high-temperature range of 573-723 K, representing an increase of approximately 17% compared to pristine GeTe within the same temperature range.
RESUMEN
Tree-type hydraulic fracturing (TTHF) is a new technology that can enhance the permeability of coal seams in a balanced manner and increase the coalbed methane production rate. However, the heterogeneity of coal seams is a major challenge in achieving balanced permeability enhancement by TTHF. Traditional methods based on digital image processing are difficult to apply in practice. To address these challenges, we proposed a 2D numerical model of coal seams based on the combined finite-discrete element method (FDEM). The elastic modulus of the coal seams obeys a Weibull distribution, and the coal heterogeneity was quantified by an index m. The effects on the fracture initiation pressure, the fracturing influence range, and displacements of TTHF were analyzed from four aspects, including the homogeneity index of coal, the arrangement angle of branch boreholes, the horizontal stress difference, and the injection rate of the fracturing fluid. The results show that TTHF has a significant effect on the balanced permeability enhancement in coal reservoirs, particularly with strong heterogeneity, and the best permeability enhancement for TTHF is achieved when the branch boreholes are arranged at 45°. The branch boreholes are prefabricated in advance to create a pressure relief area around the injection point, and the hydraulic fracture propagation is affected by the horizontal stress difference only when the fracturing influence range exceeds this area. When the horizontal stress difference increases from 0 to 4 MPa, its fracture initiation pressure increases from 8.93 to 10.86 MPa, with an increase of 21.61%. In addition, the initial stage of fluid injection was found to be crucial for achieving balanced permeability enhancement in TTHF, and a higher injection rate can expand the fracturing influence range. The numerical model has profound implications for the field application of TTHF technology.
RESUMEN
Aqueous zinc ion batteries (AZIBs) have attracted sustained attention owing to their intrinsic safety and low cost. Unfortunately, the dendrite growth and parasitic side reactions of metallic zinc anodes severely degrade the cycling stability of the batteries and limit the practical application of AZIBs. In this work, calcium gluconate (CG), a chelating agent, as a novel electrolyte additive was introduced to tackle the thorny issue of zinc anodes in a 2 M ZnSO4 electrolyte by the synergistic effects of gluconate (GA-) anions and Ca2+ cations. Experimental characterization and computational simulations confirmed that the incorporation of GA- can not only mitigate the precipitation of Ca2+ ions, but also affect the primary solvation shell (PSS) of Zn2+ and modulate the electrode/electrolyte interfacial reaction, thereby inhibiting side reactions. Besides, trace amounts of Ca2+ cations can preferentially adsorb on the surface of the zinc anode tip, forming an electrostatic shielding shell that guides the uniform deposition of zinc ions. The Zn//Zn symmetric cells achieved a remarkably prolonged cycling lifespan ranging from 174 h to 3745 h at 6.37 mA cm-2 and 2.88 mA h cm-2 with an ultrahigh cumulative plating capacity (CPC) of about 11 900 mA h cm-2. Even at a higher current density of 5 mA cm-2 and an areal specific capacity of 5 mA h cm-2, Zn//Zn cells with the CG additive cycled for 248 h, about 5 times better than that without the CG additive. These results pave the way for the exploitation of new electrolyte additives with synergistic effects in AZIBs.
RESUMEN
Polymer dielectrics play an irreplaceable role in electronic power systems because of their high power density and fast charge-discharge capability, but it is limited by their low stability in the temperature range of 25-200 °C. Rather than the introduction of one-dimensional fillers in polymers, we used a kind of multidimensional synergistic design to prepare Al2O3-TiO2-Al2O3/PI composites with layered structures by introducing multi-dimensional materials in polyimide (PI). In fact, the composite achieves much higher temperature stability than the pure PI film. The optimally proportioned composite has an energy density of 3.41 J cm-3 (vs. 1.48 J cm-3 for pure PI) even at 200 °C. Additionally, it reaches an impressive energy density retention of up to 90% and maintains an energy efficiency as high as 86% at 400 MV m-1 in the temperature range of 25-200 °C. The multidimensional coordination design is proposed to obtain composite films, and provides a feasible strategy in the study of polymer-based composites with high-temperature performance.
RESUMEN
A novel actinobacterial strain, designated as JXJ CY 30 T, was isolated from the phycosphere of Microcystis aeruginosa FACHB-905 (Maf) collected from Lake Dianchi, China. The strain was a Gram-stain-positive, aerobic and coccus-shaped actinobacterium. It had alanine, glutamic acid, aspartic acid, and lysine in the peptidoglycan, and mannose, ribose and arabinose in its cell wall sugars, anteiso-C15:0 and iso-C15:0 as the main cellular fatty acids, MK-7 and MK-8 as the major respiratory quinones, and phosphatidylglycerol, diphosphatidylglycerol, phosphatidylinositol, glycolipid, and an unidentified phospholipid as the polar lipids. The DNA G + C content was 73.08%. Its 16 S rRNA gene sequence shared 99.14%, and 98.75% similarities with Micrococcus flavus DSM 19079 T and M. porci KD337-16T, respectively, and ≤98.41% similarities with other type strains of the genus Micrococcus. It formed independent clade with M. flavus DSM 19079 T on the phylogenetic trees. The digital DNA-DNA hybridization and average nucleotide identity values between strain JXJ CY 30 T and M. flavus DSM 19079 T and M. porci KD337-16T were 48.0% and 92.1%, 25.5% and 83.2%, respectively. These data above indicated that strain JXJ CY 30 T represented a new species of the genus Micrococcus, and the species epithet is proposed as Micrococcus lacusdianchii sp. nov. (type strain JXJ CY 30 T = KCTC 49378 T = CGMCC 1.17508 T). Strain JXJ CY 30 T can potentially provide Maf with various nutrients such as available phosphorus and nitrogen, plant hormones, various vitamins and carotenoids for growth, while it was inhibited by metabolites from its symbiotic algae Maf.
Asunto(s)
Micrococcus , Fosfolípidos , Filogenia , Micrococcus/genética , Ácidos Grasos , ADN , ARN Ribosómico 16S/genética , ADN Bacteriano/genética , Análisis de Secuencia de ADN , Técnicas de Tipificación Bacteriana , Vitamina K 2RESUMEN
Hydrogen production with higher efficiency and lower cost is of great significance for the sustainable development of energy. Zinc cadmium sulfide (CZS) is gaining more attention owing to its excellent photocatalytic properties. However, its development is greatly limited due to photogenerated charge recombination. In this work, an innovative design with a unique 3D morphology was introduced by integrating 3DTiO2 into CZS to form a novel 3DTiO2/CZS heterojunction photocatalyst. As a result, the optimized composite achieved a very high hydrogen production rate of 75.38 mmol h-1 g-1 under visible light, which is 2.4 times higher than that of the original CZS. It can also be greatly demonstrated through photoelectrochemical tests that this unique 3D morphology contributes to the effective separation of electrons and holes, thus dramatically improving the photocatalytic activity of 3DTiO2/CZS composites. The 3DTiO2/CZS composite has a rational energy band structure, which makes it more favorable for the hydrogen precipitation reaction. It is believed that such a modification strategy based on 3DTiO2 can be applied to other similar photocatalysts as well for boosting hydrogen evolution.
RESUMEN
Developing high-performance anodes is one of the most effective ways to improve the energy storage performances of potassium-ion batteries (PIBs). Among them, Ti-based oxides, including TiO2, K2Ti6O13, K2Ti4O9, K2Ti8O17, Li4Ti5O12, etc., as the intrinsic structural advantages, are of great interest for applications in PIBs. Despite numerous merits of Ti-based oxide anodes, such as fantastic chemical and thermal stability, a rich reserve of raw materials, non-toxic and environmentally friendly properties, etc., their poor electrical conductivity limits the energy storage applications in PIBs, which is the key challenge for these anodes. Although various modification projects are effectively used to improve their energy storage performances, there are still some related issues and problems that need to be addressed and solved. This review provides a comprehensive summary on the latest research progress of Ti-based oxide anodes for the application in PIBs. Besides the major impactful work and various performance improvement strategies, such as structural regulation, carbon modification, element doping, etc., some promising research directions, including effects of electrolytes and binders, MXene-derived TiO2-based anodes and application as a modifier, are outlined in this review. In addition, noteworthy research perspectives and future development challenges for Ti-based oxide anodes in PIBs are also proposed.
RESUMEN
Using natural light energy to convert water into hydrogen is of great significance to solving energy shortages and environmental pollution. Due to the rapid recombination of photogenerated carriers after separation, the efficiency of photocatalytic hydrogen production using photocatalysts is usually very low. Here, efficient CdZnS nanoparticles@Ti3C2Tx MXene nanosheet heterojunction photocatalysts have been successfully prepared by a facile in situ growth strategy. Since the CdZnS nanoparticles uniformly covered the Ti3C2Tx Mxene nanosheets, the agglomeration phenomenon of CdZnS nanoparticles could be effectively inhibited, accompanied by increased Schottky barrier sites and an enhanced migration rate of photogenerated carriers. The utilization efficiency of light energy can be improved by inhibiting the recombination of photogenerated electron-hole pairs. As a result, under the visible-light-driven photocatalytic experiments, this composite achieved a high hydrogen evolution rate of 47.1 mmol h-1 g-1, which is much higher than pristine CdZnS and Mxene. The boosted photocatalytic performances can be attributed to the formed heterojunction of CdZnS nanoparticles and Ti3C2Tx MXene nanosheets, as well as the weakened agglomeration effects.