Facilitated glass separation by asymmetric Bessel-like beams.

The modification of transparent materials is enabled by focused ultrashort laser pulses. Single pass processing up to several millimeters can be achieved by the usage of elongated beam profiles. We studied the mechanical separability in dependence of the material thickness. As simulations show, asymmetric beam profiles can cause modifications with preferential direction reducing the necessary breaking force. Pump-probe microscopy is implemented to examine the laser-matter-interaction. We present a measured 3D-reconstruction of the transient interaction inside the material and elucidate the desired crack formation. We demonstrate beam shaping concepts to create a new, efficient and robust class of Bessel-like beams, which can be used to achieve a preferred crack direction. We verify the concept by modification and separation of silicate glasses.

Ultrafast thin-disk multi-pass amplifier system providing 1.9 kW of average output power and pulse energies in the 10 mJ range at 1 ps of pulse duration for glass-cleaving applications.

An ultrafast Yb-doped thin-disk multi-pass laser amplifier system with flexible parameters for material processing is reported. We can generate bursts consisting of four pulses at a distance of 20 ns and a total energy of 46.7 mJ at a repetition rate of 25 kHz. In single-pulse operation, 1.5 kW of average output is achieved at 400 kHz when optimizing for a beam quality of M2 = 1.5. Alignment for maximum output power provides 1.9 kW at the same repetition rate. All results are obtained without chirped-pulse amplification in the multi-pass set-up. The application potential of the system is demonstrated exploring its performance in materials processing of dielectrics. Cleaving of 3.8-mm-thick SCHOTT borofloat glass with a velocity of 1200 mm/s is demonstrated with 300 W of input power. Single-pass modification of 30 mm borosilicate glass is enabled with a Bessel beam at 1 kW of average power delivered by four-pulse bursts of an energy of 30 mJ.

Time-resolved tomography of ultrafast laser-matter interaction.

We demonstrate time-resolved tomography with 200 fs resolution for the three-dimensional analysis of the non-linear dynamics of ultrafast laser-matter interaction inside the volume of transparent materials. We reconstruct as an example the three-dimensional spatial distribution of the transient extinction coefficient induced by focusing higher-order Bessel-Gaussian-beams into Gorilla glass. This approach can be employed to gaseous, liquid and transparent solid state matter which interact with laser light.

High-quality tailored-edge cleaving using aberration-corrected Bessel-like beams.

We report on the usage of ultrashort laser pulses in the form of aberration-corrected Bessel-like beams for laser cutting of glass with bevels. Our approach foresees inclining the material's entrance surface with respect to the processing optics. The detailed analysis of phase distortions caused by the beam transition through the tilted glass surface allows precompensating for occurring aberrations using digital holography. We verify theoretical considerations by means of pump-probe microscopy and present high-quality edges in nonstrengthened silicate glass.

Rational In Silico Design of an Organic Semiconductor with Improved Electron Mobility.

Organic semiconductors find a wide range of applications, such as in organic light emitting diodes, organic solar cells, and organic field effect transistors. One of their most striking disadvantages in comparison to crystalline inorganic semiconductors is their low charge-carrier mobility, which manifests itself in major device constraints such as limited photoactive layer thicknesses. Trial-and-error attempts to increase charge-carrier mobility are impeded by the complex interplay of the molecular and electronic structure of the material with its morphology. Here, the viability of a multiscale simulation approach to rationally design materials with improved electron mobility is demonstrated. Starting from one of the most widely used electron conducting materials (Alq3 ), novel organic semiconductors with tailored electronic properties are designed for which an improvement of the electron mobility by three orders of magnitude is predicted and experimentally confirmed.

Random-cavity lasing from electrospun polymer fiber networks.

Lasing emission from random cavities formed in networks of electrospun Rhodamine-doped polymer fibers is presented. Spatially resolved spectroscopy and spectral analysis prove that the observed laser emission stems from individual ring resonators randomly distributed throughout the network. These electrospun fiber lasers represent a facile and straightforward configuration for developing novel photonic devices that may advantageously utilize the network morphology.