Pneumatic Structural Deformation to Enhance Resonance Behavior for Broadband and Adaptive Radar Stealth.

Ideal radar absorbing materials (RAMs) require instantaneous, programmable, and spontaneous adaptability to cope with a complex electromagnetic (EM) environment across the full working frequency. Despite various material systems and adaptive mechanisms having been demonstrated, it remains a formidable challenge to integrate these benefits simultaneously. Here, we present a pneumatic matrix that couples morphable MXene/elastomer conductors with dielectric spacers, which leverages controllable airflow to reconfigure the spatial structure between a flat sheet and a hemispherical crown while maintaining resistance stability via wrinkle folding and unfolding. The interdimensional reconfigurations drastically induce multiple resonance behavior, enabling the matrix remarkable frequency tunability (144.5%), ultrawide bandwidth (15 GHz), weak angular dependence (45° incidence), ultrafast responsiveness (∼30 ms), and excellent reproducibility (1000 cycles). With multichannel fluidic and conceptual automated control systems, the final pneumatic device demonstrates a multiplexed, programmable, and autonomous transformable mode that builds a promising platform for smart radar cloaking.

Integrating carbonyl iron with sponge to enable lightweight and dual-frequency absorption.

In this work, sponge impregnated with iron pentacarbonyl was utilized to obtain a novel composite in which the carbonyl iron (CI) was embedded in a graphitized carbon matrix (CI-C). The CI that results from the thermal pyrolysis of iron pentacarbonyl can homogeneously disperse into the pore structures of the sponge skeleton, which not only improves the stability of the CI, but also modifies the impedance matching character. Moreover, the sponge bulk turns into graphitized carbon during the heat treatment (graphitized catalysis of magnetic metal on carbon at high temperature). Due to the respective strong dissipation ability of CI and the graphitized carbon matrix, the as-prepared CI-C sample exhibits a good microwave absorption performance, including expanding the effective absorption bandwidth and reduced weight, compared to pure CI. Moreover, the sample with 30 wt% paraffin loading not only shows strong reflection loss absorbing ability, but also possesses continuous dual-absorption peaks (9.96 GHz, -38.7 dB, and 13.8 GHz is -37.6 dB). This work not only extends the application of carbonyl iron as a lightweight microwave absorber with dual-absorption peaks but also initiates a new approach for artificially designed carbon-based composites via a simple sponge-impregnation method.

The flaky porous Fe3O4 with tunable dimensions for enhanced microwave absorption performance in X and C bands.

Special electric and magnetic characteristics make Fe3O4 widely applied in the electromagnetic (EM) wave absorption region. However, for pure Fe3O4, it is still a challenge to simultaneously obtain high absorption intensity and broadband absorption at a low thickness, owing to its low dielectric property. As we realized, flake configuration and the porous structure have obviously promote the EM wave absorption property. Because the former can lead to multi-reflection between flakes and the latter is conductive to interface polarization, flaky Fe3O4 with a porous and coarse surface was designed to overcome the deficiency of traditional Fe3O4 particles. The experimental results demonstrate that the flaky configuration is conductive to enhancing the dielectric coefficient and optimizing impedance matching. Moreover, the complex permittivity rises with the aspect ratio of the sheet. Under a suitable dimension, the flaky Fe3O4 could acquire targeted EM wave absorption capacity in the X band (8-12 GHz). In detail, the maximum reflection loss (RL) could reach a strong intensity of -49 dB at 2.05 mm. The effective absorption bandwidth (EAB) with RL below -10 dB is 4.32 (7.52-11.84) GHz, which is almost equivalent to the whole X band (8-12 GHz). Even more exciting, when regulating the thickness between 2.05 and 3.05 mm, the EAB could cover the entire C and X bands (4-12 GHz). This study provides a good reference for the future development of other ferromagnetic materials toward specific microwave bands.

Excellent microwave response derived from the construction of dielectric-loss 1D nanostructure.

Increasing efforts have recently been devoted to the artificial design and function of nanostructures for their application prospects in catalysis, drug delivery, energy storage, and microwave absorption. With the advantages of natural abundance, low cost, and environment friendliness, a one-dimensional (1D) MnO2 nanowire (MW) is the representative dielectric-loss absorber for its special morphology and crystalline structure. However, its low reflection loss (RL) value due to its thin thickness limits its wide development and application in the microwave absorption field. In this work, artificially designed MnO2@AIR@C (MCs), namely, 1D hollow carbon nanotubes filled with nano-MnO2, were designed and synthesized. It is found that the RL value of the MC is almost lower than -10 dB. Furthermore, the RL value was able to achieve -18.9 dB with an effective bandwidth (-10 dB) of 5.84 GHz at 2.25 mm. Simultaneously, the dielectric and interfacial polarization became stronger while the impedance matching was much better than in the single MWs. Hence, the rational design and fabrication of micro-architecture are essential and MC has great potential to be an outstanding microwave absorber.

A facile self-template strategy for synthesizing 1D porous Ni@C nanorods towards efficient microwave absorption.

Ni@C composites, which simultaneously possess porous, core-shell and 1D nanostructures have been synthesized with a facile self-template strategy. The precursors were obtained by a hydrothermal process using NiCl2 · 6H2O and nitrilotriacetic acid as the starting material and then annealed at 400 °C, 500 °C, and 600 °C. The Ni@C composites annealed at 500 °C display a nanorod feature with a length of ∼3 µm and diameter of 230-500 nm. In addition, about 3 nm carbon shells and 4 nm Ni cores can be found in Ni@C nanorods. Attributed to the interconnected mesoporous texture in nanorods, strengthened interfacial polarization from core-shell structure, and better impedance matching benefiting from a great deal of pores, Ni@C nanorod composites exhibit perfect microwave absorption performance. The minimum reflection loss (RL) value of -26.3 dB can be gained at 10.8 GHz with a thickness of 2.3 mm. Moreover, the effective bandwidth (RL ≤ -10 dB) can be achieved, 5.2 GHz (12.24-17.4 GHz) under an absorber thickness of 1.8 mm, indicating its great potential in the microwave absorption field. Considering this technique is facile and effective, our study may provide a good reference for the synthesis of 1D carbon-based microwave absorbers with core-shell nanostructure.

Facile Aluminum Reduction Synthesis of Blue TiO2 with Oxygen Deficiency for Lithium-Ion Batteries.

An ultrafacile aluminum reduction method is reported herein for the preparation of blue TiO2 nanoparticles (donated as Al-TiO2 , anatase phase) with abundant oxygen deficiency for lithium-ion batteries. Under aluminum reduction, the morphology of the TiO2 nanosheets changes from well-defined rectangular into uniform round or oval nanoparticles and the particle size also decreases from 60 to 31 nm, which can aggressively accelerate the lithium-ion diffusion. Electron paramagnetic resonance (EPR) and positron annihilation lifetime spectroscopy (PALS) results reveal that plentiful oxygen deficiencies relative to the Ti(3+) species were generated in blue Al-TiO2 ; this effectively enhances the electron conductivity of the TiO2 . X-ray photoelectron spectrometry (XPS) analysis indicates that a small peak is observed for the Al-O bond, which probably plays a very important role in the stabilization of the oxygen deficiencies/Ti(3+) species. As a result, the blue Al-TiO2 possesses significantly higher capacity, better rate performance, and a longer cycle life than the white pure TiO2 . Such improvements can be attributed to the decreased particle size, as well as the existence of the oxygen deficiencies/Ti(3+) species.

The role of Sn in enhancing the visible-light photocatalytic activity of hollow hierarchical microspheres of the Bi/BiOBr heterojunction.

Hollow hierarchical microspheres of Bi/BiOBr (SBB) with oxygen vacancies were prepared using a one step solvothermal method. It was found that the stannous chloride dihydrate played key roles in the formation of Bi, defects and the stacking mode of hierarchical construction units. Positron annihilation lifetime spectroscopy (PALS) was used to demonstrate the oxygen vacancies in Bi/BiOBr samples. The density of states (DOS) of the valence band of BiOBr can be modulated by the introduction of oxygen vacancies according to the valence band XPS and Density Functional Theory (DFT) calculations. Analyses of photoluminescence and BET demonstrated that SBB hollow hierarchical microspheres with higher specific surface area have a lower recombination rate of photo-generated electrons and holes. The photocatalytic and adsorptive performances showed that the samples exhibited stronger adsorption capacity toward rhodamine B (RhB) and highly efficient photocatalytic activity in the degradation of RhB, which were attributed to the higher adsorption ability and synergistic effect of oxygen vacancies and construction of the heterojunction structure (Bi/BiOBr).

Aerogel-Involved Triple-State Gels Resemble Natural Living Leaves in Structure and Multi-Functions.

Natural plant leaves with multiple functions, for example, spectral features, transpiration, photosynthesis, etc., have played a significant role in the ecosystem, and artificial synthesis of plant leaves with multiple functions of natural ones is still a great challenge. Herein, this work presents an aerogel-involved living leaf (AL), most similar to natural ones so far, by embedding super-hydrophobic SiO2 aerogel microparticles in polyvinyl alcohol hydrogel in the presence of hygroscopic salt and chlorophyllin copper sodium to form solid-liquid-vapor triple-state gel. The AL shows a high spectral similarity with all sampled 15 species of natural leaves and exhibits ≈4-7 times transpiration speed higher than natural leaves. More importantly, AL can achieve several times higher photosynthesis than natural leaves without the energy provided by the respiratory action of natural ones. This work demonstrates the feasibility of creating ALs with natural leaf-like triple-state gel structures and multiple functions, opening up new avenues for energy conversion, environmental engineering, and biomimetic applications.

Dendrimer-assisted defect and morphology regulation for improving optical, hyperthermia, and microwave-absorbing features.

Electromagnetic pollution and cancer are phenomena that essentially endanger the future of humanity. Herein, multiple approaches are being proposed to solve the aforementioned issues. Recent studies have demonstrated that by regulating the morphology, defect, and phase of materials, their microwave absorbing, optical, and hyperthermia properties are tunable. Calcium ferrite with proper dielectric, magnetic, and biocompatible characteristics was chosen as a substantial candidate to promote its microwave-absorbing properties by regulating its structure. Spinel CaFe2O4 was synthesized through sol-gel and solvothermal routes and its phase, defect, and morphology were manipulated using innovative procedures. Glucose was applied as conventional defecting and templating agent; interestingly, a dendrimer was designed to bear and form nanoparticles. More importantly, a novel reductive process was designed to fabricate one-put Ca/Fe3O4 using a solvothermal method. Particularly, polypropylene (PP) was employed as a practical polymeric matrix to fabricate the eventual product. Structures were molded at a low filling ratio to evaluate their optical and microwave-absorbing performance. As expected, defects, morphology, and phase play a pivotal role in tuning the optical and microwave-absorbing properties of calcium ferrite derivates. Interestingly, the dendrimer-assisted (D-A) formation of CaFe2O4 demonstrated a fascinating reflection loss (RL) of 70.11 dB and an efficient bandwidth (RL ≤ -20 dB) of 7.03 GHz with ultralow thickness (0.65 mm) and filling ratio (10 wt%), attaining proper shielding efficiency (SE) and hyperthermia desirable for its practical application as a material for shielding buildings and cancer therapy. The presented perspective develops new inspirations for architecting microwave absorbing/shielding materials with advanced applications in therapeutic issues.

MXene-Enabled Pneumatic Multiscale Shape Morphing for Adaptive, Programmable and Multimodal Radar-infrared Compatible Camouflage.

Achieving radar-infrared compatible camouflage with dynamic adaptability has been a long-sought goal, but faces significant challenges owing to the limited dispersion relations of conventional material systems operating in different wavelength ranges. Here, this work proposes the concept of pneumatic multiscale shape morphing and design a periodically arranged pneumatic unit consisting of MXene-based morphable conductors and intake platforms. During gas actuation, the morphable conductor transforms centimeter-scale 2D flat sheets into 3D balloon shapes to enhance microwave absorption behavior, and also reconfigures micrometer-scale MXene wrinkles into smooth planes in combination with cavity-induced low heat transfer to minimize infrared (IR) signatures. Through theory-guided reverse engineering, the final pneumatic matrix shows remarkable frequency tunability (2.64-18.0 GHz), moderate IR emissivity regulation (0.14 at 7-16.5 µm), rapid responsiveness (≈30 ms), wide-angle operation (>45°), and excellent environmental tolerance. Additionally, the multiplexed pneumatic matrix enables over 14 programmable coding sequences that independently alter thermal radiation without compromising radar stealth, and allows multimodal camouflage switching between three distinct compatible states. The approach may facilitate the evolution of camouflage techniques and electromagnetic functional materials toward multispectral, adaptability and intelligence.

Multi-interfacial bridging engineering of flexible MXene film for efficient electromagnetic shielding and energy conversion.

Accompanied by the progressive development of electronic equipment, excellent electromagnetic interference (EMI) shielding materials display a satisfying prospect in protecting electronic devices against electromagnetic pollution/radiation, while integrating energy conversion. Heretofore, it remains a conundrum to availably construct thin films with multi-interfacial bridging engineering as multifunctional shielding devices. To effectively achieve electromagnetic wave attenuation and integrate energy conversion, a co-mixed vacuum-assisted filtration strategy is designed to synthesize Au@MXene/cellulose nanocrystal/dodecylbenzenesulfonic acid-doped polyaniline (AMCP) films. Profited from the interfacial engineering, the total EMI shielding effectiveness (SE) can be increased by 27 % with the highest value of 67.9 dB. MXene with localized surface plasmon resonance characteristics gives the composite films good energy conversion performance, that is, the composite film can be rapidly heated up to 100 °C under the irradiation of an infrared lamp, and its surface temperature remains stable after continuous irradiation. Additionally, the infrared emissivity is as low as 0.173 within the 8-14 µm, which is necessary to adapt various application scenarios. Therefore, it is reliable that the AMCP films constructed by multicomponent offer a facile strategy for MXene-based EMI shielding devices with integration characteristics.

Achieving Ultra-Broad Microwave Absorption Bandwidth Around Millimeter-Wave Atmospheric Window Through an Intentional Manipulation on Multi-Magnetic Resonance Behavior.

The utilization of electromagnetic waves is rapidly advancing into the millimeter-wave frequency range, posing increasingly severe challenges in terms of electromagnetic pollution prevention and radar stealth. However, existing millimeter-wave absorbers are still inadequate in addressing these issues due to their monotonous magnetic resonance pattern. In this work, rare-earth La3+ and non-magnetic Zr4+ ions are simultaneously incorporated into M-type barium ferrite (BaM) to intentionally manipulate the multi-magnetic resonance behavior. By leveraging the contrary impact of La3+ and Zr4+ ions on magnetocrystalline anisotropy field, the restrictive relationship between intensity and frequency of the multi-magnetic resonance is successfully eliminated. The magnetic resonance peak-differentiating and imitating results confirm that significant multi-magnetic resonance phenomenon emerges around 35 GHz due to the reinforced exchange coupling effect between Fe3+ and Fe2+ ions. Additionally, Mössbauer spectra analysis, first-principle calculations, and least square fitting collectively identify that additional La3+ doping leads to a profound rearrangement of Zr4+ occupation and thus makes the portion of polarization/conduction loss increase gradually. As a consequence, the La3+-Zr4+ co-doped BaM achieves an ultra-broad bandwidth of 12.5 + GHz covering from 27.5 to 40 + GHz, which holds remarkable potential for millimeter-wave absorbers around the atmospheric window of 35 GHz.

Electronic Modulation Strategy for Mass-Producible Ultrastrong Multifunctional Biomass-Based Fiber Aerogel Devices: Interfacial Bridging.

The emergence of green flexible aerogel electronics based on natural materials is expected to solve part of the global environmental and energy crisis. However, it is still challenging to achieve large-scale production and multifunctional stable applications of natural biomass fiber aerogel (BFA) materials. Herein, we exploit the interfacial bridging between the flower-type titanium dioxide nanoarray (FTNA) and natural fiber substrates to modulate the electronic structure and loss mechanism to achieve multifunctional properties. Specifically, the fibrous substrate with wrinkled features induces lattice strain in titania through precise interfacial bridging, effectively improving the intrinsic properties of the BFA materials. This interfacial bridging regulation strategy is also confirmed by X-ray absorption fine structure spectroscopy (XAS). More importantly, the construction of BFA products for different macroscopic and multifunctional applications through simple processing methods will facilitate the transition from natural materials to multifunctional flexible electronics. Therefore, the as-prepared blanket-type BFA (TCBFA) has good mechanical properties, electromagnetic protection properties, thermal stealth properties, high-temperature flame retardancy, and UV resistance. Meanwhile, the membrane-type (TCBFAM) multifunctional wearable fiber aerogel device exhibits superior flexibility, efficient Joule heating performance, and a smart response. This regulation strategy provides another concept for the design and innovation of green multifunctional fiber-integrated aerogels.

"Three-in-One" Multi-Scale Structural Design of Carbon Fiber-Based Composites for Personal Electromagnetic Protection and Thermal Management.

Wearable devices with efficient thermal management and electromagnetic interference (EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers (CF) @ polyaniline (PANI) / silver nanowires (Ag NWs) composites with a "branch-trunk" interlocked micro/nanostructure were achieved through "three-in-one" multi-scale design. The reasonable assembly of the three kinds of one-dimensional (1D) materials can fully exert their excellent properties i.e., the superior flexibility of CF, the robustness of PANI, and the splendid conductivity of AgNWs. Consequently, the constructed flexible composite demonstrates enhanced mechanical properties with a tensile stress of 1.2 MPa, which was almost 6 times that of the original material. This is mainly attributed to the fact that the PNAI (branch) was firmly attached to the CF (trunk) through polydopamine (PDA), forming a robust interlocked structure. Meanwhile, the composite possesses excellent thermal insulation and heat preservation capacity owing to the synergistically low thermal conductivity and emissivity. More importantly, the conductive path of the composite established by the three 1D materials greatly improved its EMI shielding property and Joule heating performance at low applied voltage. This work paves the way for rational utilization of the intrinsic properties of 1D materials, as well as provides a promising strategy for designing wearable electromagnetic protection and thermal energy management devices.

Multi-interfacial engineering in the hierarchical self-assembled micro-nano dielectric aerogel for wide-band absorption and low infrared emissivity.

Radar-infrared (IR) compatible stealth can satisfy the characteristics of excellent electromagnetic wave attenuation property and low infrared emissivity. However, concurrently satisfying these demands is still a great challenge at present. Herein, multi-interfacial engineering strategy was proposed for the preparation of radar-IR compatible stealth materials. ZnO has a high electron binding energy and a large band gap at room temperature, and doping with sulphide can increase the concentration of unconstrained carriers. Therefore, bimetallic sulphide aerogels loaded with ZnO were prepared by means of carbonization and vulcanization, combined with freeze-drying method. When the filling ratio is 20 %, an absorption bandwidth (fe) of 6.62 GHz at a matching thickness of 2.0 mm and a reduction in IR emissivity from 0.920 to 0.539 in the 8-14 µm band are achieved. This work provides a guidance to design and synthesize high-performance absorbers by multi-interfacial engineering for IR-radar compatible stealth application.

An Adaptive Multispectral Mechano-Optical System for Multipurpose Applications.

Mechano-optical systems with on-demand adaptability and a broad spectrum from the visible to microwave are critical for complex multiband electromagnetic (EM) applications. Most existing material systems merely have dynamic optical or microwave tunability because their EM wave response is strongly wavelength-dependent. Inspired by cephalopod skin, we develop an adaptive multispectral mechano-optical system based on bilayer acrylic dielectric elastomer (ADE)/silver nanowire (AgNW) films, which reconfigures the surface morphology between wrinkles and cracks via mechanical contraction and stretching. Such morphological evolution regulates the direct transmission/reflection and scattering behavior of visible-infrared light and simultaneously alters the conductive network in a AgNW film to influence its microwave characteristics. The designed system features switching between visible-infrared-microwave transparency and opacity, continuous regulation, wide spectral window (0.38-15.5 µm and 24,200-36,600 µm), excellent recyclability (500 times), and rapid response time (<1 s). These grant the system great potential as platforms for various promising applications such as smart windows, switchable EM devices, dynamic thermal management, adaptive visual stealth, and human motion detection.

BiOCl-assisted photodegradation of Rhodamine B under white light and monochromatic green pulsed laser irradiation.

BiOCl-assisted photodegradation of Rhodamine B (Rh. B) molecules was investigated by using white light and green pulsed laser as sources of irradiation in the visible region for the first time. The dependences of removal efficiencies on catalyst dosage, incident pulsed laser energy were investigated and discussed. The dissolved oxygen was found to play an important role during the photochemical reaction. In addition the lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) levels of Rh. B molecular were calculated using a Gaussian 03 program. These calculations were valuable to identify the possible photo-catalytic excitation process involved in degradation of Rh.B.

Green, Sustainable Architectural Bamboo with High Light Transmission and Excellent Electromagnetic Shielding as a Candidate for Energy-Saving Buildings.

Currently, light-transmitting, energy-saving, and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment. Here, we developed a cellulose composite with excellent optical transmittance that retained the natural shape and fiber structure of bamboo. The modified whole bamboo possessed an impressive optical transmittance of approximately 60% at 6.23 mm, illuminance of 1000 luminance (lux), water absorption stability (mass change rate less than 4%), longitudinal tensile strength (46.40 MPa), and surface properties (80.2 HD). These were attributed to not only the retention of the natural circular hollow structure of the bamboo rod on the macro, but also the complete bamboo fiber skeleton template impregnated with UV resin on the micro. Moreover, a multilayered device consisting of translucent whole bamboo, transparent bamboo sheets, and electromagnetic shielding film exhibited remarkable heat insulation and heat preservation performance as well as an electromagnetic shielding performance of 46.3 dB. The impressive optical transmittance, mechanical properties, thermal performance, and electromagnetic shielding abilities combined with the renewable and sustainable nature, as well as the fast and efficient manufacturing process, make this bamboo composite material suitable for effective application in transparent, energy-saving, and electromagnetic shielding buildings.

Enhanced interfacial polarization of biomass-derived porous carbon with a low radar cross-section.

Ultra-thin microwave absorbers have been urgently demanded for electromagnetic applications in recent years. Herein, porous carbon with a "flower cluster" microstructure was synthesized from biomass waste (mango seeds) by a facile activation and carbonization method. The novel structure reduced the density and also improved the impedance matching, dipole polarization, and provided many carbon matrix-air interfaces for interfacial polarization, resulting in superior microwave absorption performance. At an ultra-thin thickness of 1.5 mm, extraordinary microwave absorption was achieved, with a reflection loss (RL) of -42 dB. The effective absorption bandwidth reached 4.2 GHz. The RL can be further improved to -68.4 dB by adjusting the amount of activator to manipulate the structure of porous carbon. In addition, from the simulated radar scattering results, the maximum reduction in the radar cross-section (RCS) reached 30.4 dBm2, which can greatly reduce the probability of equipment being detected by radar. This work provides a low-cost and high-performance microwave absorber for electromagnetic stealth technologies.

A breathable and flexible fiber cloth based on cellulose/polyaniline cellular membrane for microwave shielding and absorbing applications.

High-performance electromagnetic (EM) wave absorption and shielding materials integrating with flexibility, air permeability, and anti-fatigue characteristics are of great potential in portable and wearable electronics. These materials usually prepared by depositing metal or alloy coatings on fabrics. However, the shortcomings of heavy weight and easy corrosion hamper its application. In this work, the cellulose nanofiber (CF) fabric was prepared by electrospinning technology. Then, conductive polyaniline (PANI) was deposited on the CF surface via a facile in-situ polymerization process. The interweaving cellulose/polyaniline nanofiber (CPF) composite constructs a conductive network, and the electrical conductivity can be adjusted by polymerization time. Benefiting from optimal impedance matching, strong conductive loss, as well as interfacial polarization, the CPF possesses excellent EM absorption performance. The minimum reflection loss (RLmin) value is -49.24 dB, and the effective absorption bandwidth (RL < -10 dB, fe) reaches 6.90 GHz. Furthermore, the CPF also exhibits outstanding electromagnetic interference (EMI) shielding capability with shielding efficiency (SE) of 34.93 dB in the whole X band. Most importantly, the lightweight CPF fabrics have the merits of mechanical flexibility, breathability and wash resistance, which is highly applicable for wearable devices.