Ultra-Small 2D PbS Nanoplatelets: Liquid-Phase Exfoliation and Emerging Applications for Photo-Electrochemical Photodetectors.

2D PbS nanoplatelets (NPLs) form an emerging class of photoactive materials and have been proposed as robust materials for high-performance optoelectronic devices. However, the main drawback of PbS NPLs is the large lateral size, which inhibits their further investigations and practical applications. In this work, ultra-small 2D PbS NPLs with uniform lateral size (11.2 ± 1.7 nm) and thickness (3.7 ± 0.9 nm, ≈6 layers) have been successfully fabricated by a facile liquid-phase exfoliation approach. Their transient optical response and photo-response behavior are evaluated by femtosecond-resolved transient absorption and photo-electrochemical (PEC) measurements. It is shown that the NPLs-based photodetectors (PDs) exhibit excellent photo-response performance from UV to the visible range, showing extremely high photo-responsivity (27.81 mA W-1 ) and remarkable detectivity (3.96 × 1010 Jones), which are figures of merit outperforming currently reported PEC-type PDs. The outstanding properties are further analyzed based on the results of first-principle calculations, including electronic band structure and free energies for the oxygen evolution reaction process. This work highlights promising applications of ultra-small 2D PbS NPLs with the potential for breakthrough developments also in other fields of optoelectronic devices.

Tailored negative/positive photoresponse of BP via doping.

Black phosphorus (BP) is a promising material for photodetectors due to its excellent and broadband photoresponse. To realize a wide application of BP in photodetection, there is a continuous eagerness for new approaches to tailor photoresponse of BP for a specific purpose, such as high sensitivity and switching of negative/positive responses. Here, we demonstrate that the ion irradiation with controllable conditions can enhance the photoresponsivity of BP for two orders compared to the pristine one, and can select the positive/negative photoresponse of the BP. The range of the tailored photoresponse covers the whole optical spectrum, ranging from the visible (532 nm) to the mid-infrared (10 µm). This work shows a pathway to modulate the photoresponse of BP, which opens new possibilities for potential photonic applications.

Low-Complexity and Hardware-Friendly H.265/HEVC Encoder for Vehicular Ad-Hoc Networks.

Real-time video streaming over vehicular ad-hoc networks (VANETs) has been considered as a critical challenge for road safety applications. The purpose of this paper is to reduce the computation complexity of high efficiency video coding (HEVC) encoder for VANETs. Based on a novel spatiotemporal neighborhood set, firstly the coding tree unit depth decision algorithm is presented by controlling the depth search range. Secondly, a Bayesian classifier is used for the prediction unit decision for inter-prediction, and prior probability value is calculated by Gibbs Random Field model. Simulation results show that the overall algorithm can significantly reduce encoding time with a reasonably low loss in encoding efficiency. Compared to HEVC reference software HM16.0, the encoding time is reduced by up to 63.96%, while the Bjontegaard delta bit-rate is increased by only 0.76-0.80% on average. Moreover, the proposed HEVC encoder is low-complexity and hardware-friendly for video codecs that reside on mobile vehicles for VANETs.

Quality-Oriented Perceptual HEVC Based on the Spatiotemporal Saliency Detection Model.

Perceptual video coding (PVC) can provide a lower bitrate with the same visual quality compared with traditional H.265/high efficiency video coding (HEVC). In this work, a novel H.265/HEVC-compliant PVC framework is proposed based on the video saliency model. Firstly, both an effective and efficient spatiotemporal saliency model is used to generate a video saliency map. Secondly, a perceptual coding scheme is developed based on the saliency map. A saliency-based quantization control algorithm is proposed to reduce the bitrate. Finally, the simulation results demonstrate that the proposed perceptual coding scheme shows its superiority in objective and subjective tests, achieving up to a 9.46% bitrate reduction with negligible subjective and objective quality loss. The advantage of the proposed method is the high quality adapted for a high-definition video application.

Polypyrrole pre-intercalation engineering-induced NH4+ removal in tunnel ammonium vanadate toward high-performance zinc ion batteries.

Ammonium vanadate with stable bi-layered structure and superior mass-specific capacity have emerged as competitive cathode materials for aqueous rechargeable zinc-ion batteries (AZIBs). Nevertheless, fragile NH…O bonds and too strong electrostatic interaction by virtue of excessive NH4+ will lead to sluggish Zn2+ ion mobility, further largely affects the electro-chemical performance of ammonium vanadate in AZIBs. The present work incorporates polypyrrole (PPy) to partially replace NH4+ in NH4V4O10 (NVO), resulting in the significantly enlarged interlayers (from 10.1 to 11.9 Å), remarkable electronic conductivity, increased oxygen vacancies and reinforced layered structure. The partial removal of NH4+ will alleviate the irreversible deammoniation to protect the laminate structures from collapse during ion insertion/extraction. The expanded interlayer spacing and the increased oxygen vacancies by the virtue of the introduction of polypyrrole improve the ionic diffusion, enabling exceptional rate performance of NH4V4O10. As expected, the resulting polypyrrole intercalated ammonium vanadate (NVOY) presents a superior discharge capacity of 431.9 mAh g-1 at 0.5 A g-1 and remarkable cycling stability of 219.1 mAh g-1 at 20 A g-1 with 78 % capacity retention after 1500 cycles. The in-situ electrochemical impedance spectroscopy (EIS), in-situ X-ray diffraction (XRD), ex-situ X-ray photoelectron spectroscopy (XPS) and ex-situ high resolution transmission electron microscopy (HR-TEM) analysis investigate a highly reversible intercalation Zn-storage mechanism, and the enhanced the redox kinetics are related to the combined effect of interlayer regulation, high electronic conductivity and oxygen defect engineering by partial substitution NH4+ of PPy incorporation.

Photothermal-driven disassembly of naphthalocyanine nano-photosensitizers for photothermal and photodynamic therapy.

The disassembly of nanomaterials is of particular interest for high-quality imaging and targeted therapies in the field of nanomedicine. In this study, we developed a novel strategy for fabricating self-assembled naphthalocyanine photosensitizers (SiNc@CEL) with intrinsically unique photochemical and photophysical properties. SiNc@CEL could be disassembled under the photothermal effect, and its photoactivity could be enhanced by 780 nm laser irradiation. Moreover, SiNc@CEL generates reactive oxygen species, including superoxide radicals (O2•-) and singlet oxygen (1O2), as well as good photothermal properties, facilitating the application of multifunctional phototherapy. In vitro evaluation indicated that SiNc@CEL possesses an excellent bactericidal effect under a combination of photodynamic (PDT) and photothermal therapy (PTT). The in vivo treatment of a full-layer skin defect model of Escherichia coli (E. coli) infection showed that SiNc@CEL had superior antibacterial and wound-healing abilities. These results provide the basis for a feasible strategy to enhance the phototherapeutic effect of photosensitizer (PS) systems.

Near-infrared to mid-infrared photoluminescence of Bi2O3-GeO2 binary glasses.

Near-infrared and mid-infrared (MIR) ultrabroad emission bands were observed in as-grown and annealed Bi(2)O(3)-GeO(2) binary glasses, in the wavelength ranges of 1000-1800 nm and 1800-3020 nm, respectively. The MIR emission band could appear through high doping ratio of Bi(2)O(3) or annealing process in air atmosphere. The structure of these glasses, the transformation of emission centers, and the effect of Al ions doping have been discussed, with the conclusion that the Bi(2)O(3)-GeO(2) binary glasses could be a promising laser material.

Orange-red to NIR emissive carbon dots for antimicrobial, bioimaging and bacteria diagnosis.

Antimicrobial photodynamic therapy (aPDT) has become a popular technology for the treatment of bacterial infections. The development of antimicrobial agents combining diagnosis and treatment remains a major challenge. Herein, curcumin carbon quantum dots (Cur-NRCQDs) with antibacterial and imaging effects were synthesized using a hydrothermal method. The fluorescence absorption range of the Cur-NRCQDs in aqueous solution was 555 to 850 nm, showing orange-red to near infrared (NIR) fluorescence, and its maximum emission wavelength was 635 nm. At the same time, Cur-NRCQDs improved the efficiency of Cur as the photosensitizer (PS), showed good storage and light stability, and enhanced the efficiency of reactive oxygen (ROS) generation and antibacterial activity. Under the irradiation of a xenon lamp, Cur-NRCQDs inactivated 100% Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) at concentrations of 10 and 15 µM, respectively. The possible reason for this was that under PDT, the ROS produced by the Cur-NRCQDs destroyed the integrity of the cell membrane, resulting in leakage of the contents. In addition, the Cur-NRCQDs showed good cell compatibility, as they can also enter bacteria and cells for imaging, so they can be employed for the detection of bacteria and cell tissues. Therefore, Cur-NRCQDs are an ideal candidate material for aPDT treatment and fluorescent bioimaging.

Preparation of graphene oxide/polydopamine-curcumin composite nanomaterials and its antibacterial effect against Staphylococcus aureus induced by white light.

Curcumin (Cur) plays a key role in photodynamic antibacterial activity as a photosensitizer. On the other hand, the antimicrobial potential of graphene oxide (GO) has been reported controversially, and how to improve its antimicrobial ability has become an meaningful study. In this study, we prepared polydopamine-curcumin (PDA-Cur) by pi-pi stacking and loaded it onto the GO surface to obtain GO/PDA-Cur composite nanomaterials. GO/PDA-Cur was characterized by physical and optical means, and GO/PDA-Cur possessed good dispersion and stability in water. In vitro antibacterial results showed that GO/PDA-Cur mediated photodynamic therapy significantly reduced Gram-positive Staphylococcus aureus (S. aureus) by 4 orders of magnitude with a bactericidal rate of 99.99 %. The antibacterial mechanism stems from the fact that GO/PDA-Cur can generate reactive oxygen species (ROS) under white light irradiation (405-780 nm), which causes bacterial outer membrane breakage and cellular deformation. In addition, GO/PDA-Cur has good biocompatibility. The antibacterial ability of graphene oxide was significantly improved by combining it with PDA-Cur, which allows it to be used as a photodynamic antibacterial material.

Rose bengal-modified gold nanorods for PTT/PDT antibacterial synergistic therapy.

In this study, Rose Bengal (RB) was loaded onto mesoporous silica coated gold nanorods (AuNR@SiO2-NH2) to form a novel multifunctional platform for antimicrobial therapy (AuNR@SiO2-NH2-RB). The platform combines the photothermal functions of AuNR and the photodynamic functions of RB to effectively inactivate bacteria under irradiation. Moreover, AuNR@SiO2-NH2-RB showed negligible cytotoxicity and good blood compatibility. Therefore, this work has potential significance for the development of new antibacterial agents.

Photodynamic and Photothermal Ce6-Modified Gold Nanorod as a Potent Alternative Candidate for Improved Photoinactivation of Bacteria.

The global rise of antibiotic resistance of pathogenic bacteria has become an increasing medical and public concern, which is further urging the development of antimicrobial channels for treating infectious diseases. The combination of photodynamic therapy (PDT) with photothermal therapy (PTT) has been considered as a promising alternative way for the replacement of traditional antibiotic therapy. In this research, the newly fabricated Chlorin-e6 (Ce6) conjugated mesoporous silica-coated AuNRs, designated AuNR@SiO2-NH2-Ce6, exhibited synergistic photothermal effects and single oxygen localized generation property, and showed stronger photoinactivation for bacteria compared with Ce6. AuNR@SiO2-NH2-Ce6 can anchor to the cell membrane and accumulate in the interior of cells. Furthermore, the unique porous structure of AuNR@SiO2NH2 enabled Ce6 encapsulation in the mesopores and was subsequently released and activated by photothermic effect, allowing the generated single oxygen to penetrate into the cytoplasmic membrane or directly enter the interior of bacteria cells, thus overcoming the inherent defects of single oxygen. AuNR@SiO2-NH2-Ce6 not only damaged the integrity of the cell membrane of bacteria but also facilitated the cellular permeation and accumulation of external nanoagents in the bacteria upon light irradiation. In addition, AuNR@SiO2-NH2-Ce6 exhibited negligible cytotoxicity toward mammalian cells and hemolytic activity. Therefore, AuNR@SiO2-NH2-Ce6 may be highly promising candidates as topical antibacterial agents, and this study has wide implications on the design of next-generation antimicrobial agents.

2D Material Optoelectronics for Information Functional Device Applications: Status and Challenges.

Graphene and the following derivative 2D materials have been demonstrated to exhibit rich distinct optoelectronic properties, such as broadband optical response, strong and tunable light-mater interactions, and fast relaxations in the flexible nanoscale. Combining with optical platforms like fibers, waveguides, grating, and resonators, these materials has spurred a variety of active and passive applications recently. Herein, the optical and electrical properties of graphene, transition metal dichalcogenides, black phosphorus, MXene, and their derivative van der Waals heterostructures are comprehensively reviewed, followed by the design and fabrication of these 2D material-based optical structures in implementation. Next, distinct devices, ranging from lasers to light emitters, frequency convertors, modulators, detectors, plasmonic generators, and sensors, are introduced. Finally, the state-of-art investigation progress of 2D material-based optoelectronics offers a promising way to realize new conceptual and high-performance applications for information science and nanotechnology. The outlook on the development trends and important research directions are also put forward.

Wideband saturable absorption in metal-organic frameworks (MOFs) for mode-locking Er- and Tm-doped fiber lasers.

We fabricate a metal-organic framework (MOF) saturable absorber (SA) based on a microfiber. Nonlinear optical absorption of the MOF SA is characterized systematically. The modulation depth is found to be 6.57% and 14.25% at 1.5 and 2 µm spectral ranges, respectively. We report ultrashort pulse generation in both Er- and Tm-doped fiber lasers by using the same microfiber-based MOF SA, operating at 384 fs and 1.3 ps pulse duration at 1563 nm and 1882 nm, respectively. To the best of our knowledge, this is the first report of a MOF-based fiber laser at near infrared spectral ranges. Our findings validate the applicability of MOFs as a broadband SA in ultrafast photonics.

Photocarrier relaxation pathways in selenium quantum dots and their application in UV-Vis photodetection.

Recently, chain-like materials have attracted significant attention due to their unique structure and outstanding electro-optical properties. However, the photocarrier dynamics and pathways in these materials that determine the electro-optical performances of the prepared devices have barely been touched. Herein, selenium quantum dots (Se QDs), one typical chain-like material, were prepared via a facile liquid phase exfoliation approach. The photocarrier dynamics in selenium quantum dots were systematically investigated by ultrafast transient absorption spectroscopy in the ultraviolet-visible regime. Four photocarrier decay pathways with different lifetimes were firstly detected, and they assist in the elucidation and reconstruction of the energy schematic diagram of Se QDs. Owing to the broadband photo-response and fast recovery time of Se QDs, a photoelectrochemical (PEC)-type photodetector was proposed for the first time to our knowledge, demonstrating its excellent photodetection properties. Considering the feasible fabrication method and clear photocarrier pathways, the excellent photocurrent density and stability of this photodetector undoubtedly guarantee that selenium is a promising candidate for advanced photonic devices.

Zero-Dimensional MXene-Based Optical Devices for Ultrafast and Ultranarrow Photonics Applications.

In recent years, MXene has become a hotspot because of its good conductivity, strong broadband absorption, and tunable band gap. In this contribution, 0D MXene Ti3C2Tx quantum dots are synthesized by a liquid exfoliation method and a wideband nonlinear optical response from 800 to 1550 nm is studied, which have a larger nonlinear absorption coefficient ß of -(11.24 ± 0.14) × 10-2 cm GW-1. The carrier dynamic processes of 0D MXene are explored with ultrahigh time resolution nondegenerate transient absorption (TA) spectroscopy, which indicates that the TA signal reaches its maximum in 1.28 ps. Furthermore, 0D MXene is used to generate ultrashort pulses in erbium or ytterbium-doped fiber laser cavity. High signal-to-noise (72 dB) femtosecond lasers with pulse durations as short as 170 fs with spectrum bandwidth of 14.8 nm are obtained. Finally, an ultranarrow fiber laser based on 0D MXene is also investigated and has a full width at half maximum of only 5 kHz, and the power fluctuation is less than 0.75% of the average power. The experimental works prove that 0D MXene is an excellent SA and has a promising application in ultrafast and ultranarrow photonics.

A self-powered photodetector based on two-dimensional boron nanosheets.

Owing to their intriguing characteristics, the ongoing pursuit of emerging mono-elemental two-dimensional (2D) nanosheets beyond graphene is an exciting research area for next-generation applications. Herein, we demonstrate that highly crystalline 2D boron (B) nanosheets can be efficiently synthesized by employing a modified liquid phase exfoliation method. Moreover, carrier dynamics has been systematically investigated by using femtosecond time-resolved transient absorption spectroscopy, demonstrating an ultrafast recovery speed during carrier transfer. Based on these results, the optoelectronic performance of the as-synthesized 2D B nanosheets has been investigated by applying them in photoelectrochemical (PEC)-type and field effect transistor (FET)-type photodetectors. The experimental results revealed that the as-fabricated PEC device not only exhibited a favourable self-powered capability, but also a high photoresponsivity of 2.9-91.7 µA W-1 in the UV region. Besides, the FET device also exhibited a tunable photoresponsivity in the range of 174-281.3 µA W-1 under the irradiation of excited light at 405 nm. We strongly believe that the current work shall pave the path for successful utilization of 2D B nanosheets in electronic and optoelectronic devices. Moreover, the proposed method can be utilized to explore other mono-elemental 2D nanomaterials.

Simultaneous voltammetric determination of acetaminophen and isoniazid using MXene modified screen-printed electrode.

Determination of hepatotoxic drugs is critical for both clinical diagnosis and quantity control of their pharmaceutical formulations. In this work, a facile and sensitive sensor based on MXene modified screen-printed electrode (MXene/SPE) has been developed for detection of acetaminophen (ACOP) and isoniazid (INZ), which are two commonly used drugs but might induce liver damage in certain circumstances. MXene showed excellent electrocatalytic activity toward the oxidation of ACOP and INZ compared with bare SPE in 0.1 M H2SO4, and the separated oxidation peak potentials ensured simultaneous detection of the targets with wide linear ranges from 0.25 to 2000 µM for ACOP and 0.1-4.6 mM for INZ. The detection limits of ACOP and INZ were 0.048 µM and 0.064 mM, respectively. (S/N = 3). MXene/SPE exhibits good stability, reproducibility and repeatability, and the method has been successfully applied for detection of ACOP and INZ in their pharmaceutical and biological samples with satisfactory recovery.

Lead monoxide: a promising two-dimensional layered material for applications in nonlinear photonics in the infrared band.

Lead monoxide (PbO), a novel few-layer two-dimensional (2D) material, was theoretically predicted to have an excellent optical response. Herein, the nonlinear optical response of PbO in the infrared region was experimentally investigated. The feasibility of PbO nanosheets as an effective optical saturable absorber was experimentally verified for the first time. Based on the excellent nonlinear optical characteristics, 2D PbO was fabricated as a passive mode locker by depositing onto a fiber patch cord and by decorating on a microfiber, both of which were successfully applied in fiber lasers for the passive mode locking operation. The mode locking pulses of the fiber laser were as short as 650 fs at 1.5 µm. A pulse duration of 5.47 ps with a 1 µm fiber laser was also experimentally verified. Finally, a PbO-decorated microfiber was fabricated as an optical thresholder that can enhance the SNR of a 1 GHz signal up to 6 dB. This finding might facilitate the development of nonlinear photonic devices with high stability and their practical applications in the future.

Broadband Nonlinear Optical Response of InSe Nanosheets for the Pulse Generation From 1 to 2 µm.

Few-layered InSe nanosheets were fabricated by the simple liquid-phase exfoliation method. The morphology and crystal structure features of InSe nanosheet sample were characterized comprehensively. The photoluminescence (PL) spectrum indicated that the liquid-phase exfoliated InSe nanosheets contained variously layered nanoflakes, where eight layers nanosheets dominate. In addition, the first-principle simulation was carried out to describe the electron density of states (DOS) and the electronic band structures. Moreover, the few-layered InSe nanosheets performed excellent nonlinear absorption properties in a broad spectral band. As an application, the stable passively Q-switched (PQS) lasers with few-layered InSe nanosheets saturable absorbers (SAs) were realized with the operating wavelengths at 1.06, 1.34, and 1.91 µm. The shortest pulse durations were 599, 520, and 210 ns, respectively. Our results confirmed that the few-layered InSe nanosheets could be an excellent candidate for pulsed lasers in wide spectral bands.

Green/red pulsed vortex-beam oscillations in all-fiber lasers with visible-resonance gold nanorods.

Optical vortex beams are of tremendous interest in diverse applications for optical tweezers, high-resolution imaging, quantum information and optical communications. So far, these vortex laser sources largely rely on extra-cavity mode conversion by bulk optical elements (e.g. spatial light modulators, phase plates, etc.), resulting in a relatively poor purity, low conversion efficiency, non-compact structure and expensive package. Vortex beams generated directly from cavity-mode lasers is naturally an ideal solution, but almost all of them are not extended into the important visible spectral region. Here, we address the challenge through demonstrating, for the first time, visible-wavelength all-fiber pulsed vortex lasers. By using the fiber offset splicing technique and all-fiber visible resonators, 543.6 nm (green) and 634.7 nm (red) vortex beams are generated directly from Er3+: ZBLAN and Pr3+/Yb3+: ZBLAN fiber lasers with topological charges of ±1 and ±2, respectively. In particular, by exploiting an excellent visible-wavelength saturable absorber, visible-resonance-controlled gold nanorods, we further realize stable short-pulse operation of the 543.6 nm/634.7 nm vortex beams in the miniaturized visible fiber lasers. The green/red vortex laser pulses are ∼500 ns in duration, have a 40-400 kHz tunable repetition rate, and a >45 dB RF signal-to-noise ratio. This work may pave a path towards compact visible-wavelength pulsed vortex lasers for specific applications in STED microscopy and visible-light communications.