Low-Temperature Growth of Carbon Nanotubes Catalyzed by Sodium-Based Ingredients.

Synthesis of low-dimensional carbon nanomaterials such as carbon nanotubes (CNTs) is a key driver for achieving advances in energy storage, computing, and multifunctional composites, among other applications. Here, we report high-yield thermal chemical vapor deposition (CVD) synthesis of CNTs catalyzed by reagent-grade common sodium-containing compounds, including NaCl, NaHCO3 , Na2 CO3 , and NaOH, found in table salt, baking soda, and detergents, respectively. Coupled with an oxidative dehydrogenation reaction to crack acetylene at reduced temperatures, Na-based nanoparticles have been observed to catalyze CNT growth at temperatures below 400 °C. Ex situ and in situ transmission electron microscopy (TEM) reveal unique CNT morphologies and growth characteristics, including a vaporizing Na catalyst phenomenon that we leverage to create CNTs without residual catalyst particles for applications that require metal-free CNTs. Na is shown to synthesize CNTs on numerous substrates, and as the first alkali group metal catalyst demonstrated for CNT growth, holds great promise for expanding the understanding of nanocarbon synthesis.

Superconductor-superconductor bilayers for enhancing single-photon detection.

Here, we optimized ultrathin films of granular NbN on SiO2 and of amorphous αW5Si3. We showed that hybrid superconducting nanowire single-photon detectors (SNSPDs) made of 2 nm thick αW5Si3 films over 2 nm thick NbN films exhibit advantageous coexistence of timing (<5 ns reset time and 52 ps timing jitter) and efficiency (>96% quantum efficiency) performance. We discuss the governing mechanism of this hybridization via the proximity effect. Our results demonstrate saturated SNSPDs performance at 1550 nm optical wavelength and suggest that such hybridization can significantly expand the range of available superconducting properties, impacting other nano-superconducting technologies. Lastly, this hybridization may be used to tune properties, such as the amorphous character of superconducting films.

J-Integral Experimental Reduction Reveals Fracture Toughness Improvements in Thin-Ply Carbon Fiber Laminates with Aligned Carbon Nanotube Interlaminar Reinforcement.

The Mode I, Mode II, and mixed-mode interlaminar failure behavior of a thin-ply (54 gsm) carbon fiber-epoxy laminated composite reinforced by 20 µm tall z-direction-aligned carbon nanotubes (CNTs), comprising ∼50 billion CNT fibers per cm2, is analyzed following J-integral-based data reduction methods. The inclusion of aligned CNTs in the ply interfaces provides enhanced crack resistance, resulting in sustained crack deflection from the reinforced interlaminar region to the intralaminar region of the adjacent plies, i.e., the CNTs drive the crack from the interlaminar region into the plies. The CNTs do not appreciably increase the interlaminar thickness or laminate weight and preserve the intralaminar microfiber morphology. Improvements of 34 and 62% on the Mode I and Mode II initiation fracture toughness, respectively, are observed. This type of interlaminar nanoreinforcement effectively drives crack propagation from the interface to within the ply where the crack propagates parallel to the interlaminar region, providing new insight into previously reported strength and fatigue performance increases. These findings extend to industries where lightweight and durable materials are critical for improving the structural efficiency.

Manufacturing Autoclave-Grade Thermoset Carbon Fiber-Reinforced Polymer Aerospace Composites without an Autoclave Using Nanoporous Materials.

Composite laminates utilizing autoclave-grade carbon fiber-reinforced plastic (CFRP) prepreg were manufactured using a polymer nanoporous network (NPN) interlayer that generates capillary pressure in lieu of pressure from an autoclave. The polymer nanofiber NPN film is integrated into the interlaminar region and is shown to eliminate voids in a vacuum-bag-only (VBO) curing process. After a preliminary investigation of the effect of NPN thickness on the interlaminar region and performance, an 8 µm thick polymer NPN was selected for a scaled manufacturing demonstration. Combining the polymer NPN with "out-of-oven" (OoO) electrothermal heating of a carbon nanotube (CNT)-heated tool, a 0.6 × 0.6 m void-free plate is successfully manufactured. OoO cure enables an accelerated cure cycle, which reduces the cure time by 35% compared to the manufacturer-recommended cure cycle (MRCC). X-ray microcomputed tomography (µ-CT) reveals that the laminates are void-free and of identical quality to autoclave-cured specimens. An array of mechanical tests including tension, compression, open-hole compression (OHC), tension-bearing (bolt-bearing), and compression after impact, reveal that the accelerated NPN-cured composites were broadly equivalent, with some instances of improved properties, relative to the autoclave-cured parts, e.g., OHC strength increased by 5%. With reduced capital costs, energy consumption, and increased throughput, the facile polymer NPN-enabled out-of-autoclave (OoA) fabrication method is shown to be a practical and attractive alternative to conventional autoclave fabrication.

Multifunctional nanocomposite structural separators for energy storage.

Separators in energy storage devices such as batteries and supercapacitors are critical elements between the much-researched anodes and cathodes. Here we present a new "structural separator" comprised of electrically-insulating aligned alumina nanotubes, which realizes a structural, or mechanically robust, function in addition to allowing charge transfer. The polymer nanocomposite structural separator is demonstrated in a supercapacitor cell and also as an interface reinforcement in an aerospace-grade structural carbon fiber composite. Relative to a polymeric commercial separator, the structural separator shows advantages both electrically and structurally: ionic conductivity in the supercapacitor cell is doubled due to the nanotubes disrupting the semi-crystallinity in the polymer electrolyte, and the structural separator creates an interface that is 50% stronger in the advanced composite. In addition to providing direct benefits to existing energy storage devices, the structural separator is best suited to multifunctional structural energy storage applications.

Ultrahigh-Areal-Capacitance Flexible Supercapacitor Electrodes Enabled by Conformal P3MT on Horizontally Aligned Carbon-Nanotube Arrays.

Nanocarbon electronic conductors combined with pseudocapacitive materials, such as conducting polymers, display outstanding electrochemical properties and mechanical flexibility. These characteristics enable the fabrication of flexible electrodes for energy-storage devices; that is, supercapacitors that are wearable or can be formed into shapes that are easily integrated into vehicle parts. To date, most nanocarbon materials such as nanofibers are randomly dispersed as a network in a flexible matrix. This morphology inhibits ion transport, particularly under the high current density necessary for devices requiring high power density. Novel flexible densified horizontally aligned carbon nanotube arrays (HACNTs) with controlled nanomorphology for improved ion transport are introduced and combined with conformally coated poly(3-methylthiophene) (P3MT) conducting polymer to impart pseudocapacitance. The resulting P3MT/HACNT nanocomposite electrodes exhibit high areal capacitance of 3.1 F cm-2 at 5 mA cm-2 , with areal capacitance remaining at 1.8 F cm-2 even at a current density of 200 mA cm-2 . The asymmetric supercapacitor cell also delivers more than 1-2 orders of magnitude improvement in both areal energy and power density over state-of-the-art cells. Furthermore, little change in cell performance is observed under high strain, demonstrating the mechanical and electrochemical stability of the electrodes.

Dynamic nanoindentation by instrumented nanoindentation and force microscopy: a comparative review.

Viscoelasticity is a complex yet important phenomenon that drives material response at different scales of time and space. Burgeoning interest in nanoscale dynamic material mechanics has driven, and been driven by two key techniques: instrumented nanoindentation and atomic force microscopy. This review provides an overview of fundamental principles in nanoindentation, and compares and contrasts these two techniques as they are used for characterization of viscoelastic processes at the nanoscale.